Citation: XIONG Wei, DING Ming-yue, TU Jun-ling, CHEN Lun-gang, WANG Tie-jun, ZHANG Qi, MA Long-long. Methanation of biomass pyrolysis gas over Ni catalyst with different supports[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(8): 958-964. shu

Methanation of biomass pyrolysis gas over Ni catalyst with different supports

1.
1. Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: WANG Tie-jun,
Received Date: 4 March 2014
Available Online: 27 May 2014
Fund Project: 国家自然科学基金(U1362109,51206172) (U1362109,51206172)国家重点基础研究发展规划(973计划,2013CB228105) (973计划,2013CB228105)国家重大科学仪器设备开发专项(2012YQ16000704)。 (2012YQ16000704)

The supported Ni-based catalysts were prepared by impregnation method. Effects of different supports (SiO₂, ZrO₂, CeO₂, Al₂O₃ and Al₂O₃-CeO₂) and water vapour on catalyst microstructure and their performance in biomass pyrolysis gas methanation were investigated. The results indicated that CO conversion increased gradually, and the CH₄ selectivity increased firstly, and then decreased with the increase of adding water vapor amount. Compared to SiO₂, ZrO₂ and CeO₂, Al₂O₃ presented higher BET surface area and Ni metal dispersion, which promoted the activity and selectivity for biomass pyrolysis gas methanation. Furthermore, the Al₂O₃-CeO₂ modified Ni-based catalyst showed more nickel metal loading and active metal dispersion comparing to the Ni-Al₂O₃ catalyst, exhibiting more excellent methanation performances at lower temperature. CO conversion reached 97%, and CH₄ growth rate reached 110% over the Ni-Al₂O₃-CeO₂ catalyst at 300 ℃.
- biomass pyrolysis gas,
- Ni-based catalyst,
- composite supporters,
- methanation
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