Citation: XIONG Wei, DING Ming-yue, TU Jun-ling, CHEN Lun-gang, WANG Tie-jun, ZHANG Qi, MA Long-long. Methanation of biomass pyrolysis gas over Ni catalyst with different supports[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(8): 958-964. shu

Methanation of biomass pyrolysis gas over Ni catalyst with different supports

1.
1. Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: WANG Tie-jun,
Received Date: 4 March 2014
Available Online: 27 May 2014
Fund Project: 国家自然科学基金(U1362109,51206172) (U1362109,51206172)国家重点基础研究发展规划(973计划,2013CB228105) (973计划,2013CB228105)国家重大科学仪器设备开发专项(2012YQ16000704)。 (2012YQ16000704)

The supported Ni-based catalysts were prepared by impregnation method. Effects of different supports (SiO₂, ZrO₂, CeO₂, Al₂O₃ and Al₂O₃-CeO₂) and water vapour on catalyst microstructure and their performance in biomass pyrolysis gas methanation were investigated. The results indicated that CO conversion increased gradually, and the CH₄ selectivity increased firstly, and then decreased with the increase of adding water vapor amount. Compared to SiO₂, ZrO₂ and CeO₂, Al₂O₃ presented higher BET surface area and Ni metal dispersion, which promoted the activity and selectivity for biomass pyrolysis gas methanation. Furthermore, the Al₂O₃-CeO₂ modified Ni-based catalyst showed more nickel metal loading and active metal dispersion comparing to the Ni-Al₂O₃ catalyst, exhibiting more excellent methanation performances at lower temperature. CO conversion reached 97%, and CH₄ growth rate reached 110% over the Ni-Al₂O₃-CeO₂ catalyst at 300 ℃.
- biomass pyrolysis gas,
- Ni-based catalyst,
- composite supporters,
- methanation
1. [1]
  [1] DEMIRBAS M F, BALAT M, BALAT H. Potential contribution of biomass to the sustainable energy development[J]. Energy Convers Manage, 2009, 50(7): 1746-1760.
2. [2]
  [2] ZHANG J, FATAH N, CAPELA S. Kinetic investigation of carbon monoxide hydrogenation under realistic conditions of methanation of biomass derived syngas[J]. Fuel, 2013, 111: 845-854.
3. [3]
  [3] KOPYSCINSKI J, SCHILDHAUER T J, BIOLLAZ S. Production of synthetic natural gas (SNG) from coal and dry biomass-A technology review from 1950 to 2009[J]. Fuel, 2010, 89(8): 1763-1783.
4. [4]
  [4] BAKAR W A W A, ALI R, TOEMEN S. Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas[J]. J Nat Gas Chem, 2011, 20(6): 585-594.
5. [5]
  [5] PANAGIOTOPOULOU P, KONDARIDES D I, VERYKIOS X E. Selective methanation of CO over supported Ru catalysts[J]. Appl Catal B: Environ, 2009, 88(3): 470-478.
6. [6]
  [6] PANAGIOTOPOULOU P, KONDARIDES D I, VERYKIOS X E. Selective methanation of CO over supported noble metal catalysts: Effects of the nature of the metallic phase on catalytic performance[J]. Appl Catal A: Gen, 2008, 344(1): 45-54.
7. [7]
  [7] LIU Z, CHU B, ZHAI X. Total methanation of syngas to synthetic natural gas over Ni catalyst in a micro-channel reactor[J]. Fuel, 2012, 95: 599-605.
8. [8]
  [8] CHITPONG N, PRASERTHDAM P, JONGSOMJIT B. A study on characteristics and catalytic properties of Co/ZrO2-B catalysts towards methanation[J]. Catal Lett, 2009, 128(1/2): 119-126.
9. [9]
  [9] KANG S H, RYU J H, KIM J H. Co-methanation of CO and CO₂ on the NiX-Fe1-X/Al₂O₃ catalysts: Effect of Fe contents[J]. Korean J Chem Eng, 2011, 28(12): 2282-2286.
10. [10]
  [10] STRUIS R P W J, SCHILDHAUER T J, CZEKAJ I. Sulphur poisoning of Ni catalysts in the SNG production from biomass: A TPO/XPS/XAS study[J]. Appl Catal A: Gen, 2009, 362(1): 121-128.
11. [11]
  [11] LIU J, SHEN W, CUI D. Syngas methanation for substitute natural gas over Ni-Mg/Al₂O₃ catalyst in fixed and fluidized bed reactors[J]. Catal Commun, 2013, 38: 35-39.
12. [12]
  [12] HU D, GAO J, PING Y. Enhanced investigation of CO methanation over Ni/Al₂O₃ catalysts for synthetic natural gas production[J]. Ind Eng Chem Res, 2012, 51(13): 4875-4886.
13. [13]
  [13] WANG Y, WU R, ZHAO Y. Effect of ZrO₂ promoter on structure and catalytic activity of the Ni/SiO₂ catalyst for CO methanation in hydrogen-rich gases[J]. Catal Today, 2010, 158(3): 470-474.
14. [14]
  [14] 刘文燕, 赵安民, 张海涛, 应卫勇, 房鼎业. 制备条件对 Ni/ZrO₂-SiO₂催化剂煤气甲烷化的影响[J]. 燃料化学学报, 2012, 40(1): 86-92. (LIU Wen-yan, ZHAO An-min, ZHANG Hai-tao, YING Wei-yong, FANG Ding-ye. Effect of preparation condition on catalytic performance of Ni/ZrO₂-SiO₂ for methanation of coal gas[J]. Journal of Fuel Chemistry and Technology, 2012, 40(1): 86-92.)
15. [15]
  [15] LIU H, ZOU X, WANG X. Effect of CeO₂ addition on Ni/Al₂O₃ catalysts for methanation of carbon dioxide with hydrogen[J]. J Nat Gas Chem, 2012, 21(6): 703-707.
16. [16]
  [16] 徐莹, 孙锐, 栾积毅, 吴少华. 生物质热解气及其成分气再燃还原NO的数值模拟与机制分析[J]. 中国电机工程学报, 2009, (35): 7-14. (XU Ying, SUN Rui, LUAN Ji-yi, WU Shao-hua. Numerical simulation and mechanism analysis on NO reduction by biomass pyrolysis gas and its contented species[J]. Proceedings of the CSEE, 2009, (35): 7-14.)
17. [17]
  [17] TAKENAKA S, SHIMIZU T, OTSUKA K. Complete removal of carbon monoxide in hydrogen-rich gas stream through methanation over supported metal catalysts[J]. Int J Hydrogen Energy, 2004, 29(10): 1065-1073.
18. [18]
  [18] RAZZAQ R, ZHU H, JIANG L. Catalytic methanation of CO and CO₂ in coke oven gas over Ni-Co/ZrO₂-CeO₂[J]. Ind Eng Chem Res, 2013, 52(6): 2247-2256.
19. [19]
  [19] 赵亮, 陈允捷. 国外甲烷化技术发展现状[J]. 化工进展, 2012, 31(S1): 176-178. (Zhao Liang, Chen Yun-jie. Developement phenomina of foreign methanation process[J]. Chemical Industry and Engineering Progress, 2012, 31(S1): 176-178.)
1. [1]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
2. [2]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
5. [5]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
6. [6]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
7. [7]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
8. [8]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
11. [11]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
12. [12]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
13. [13]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
14. [14]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
15. [15]
  Yushan Cai , Fang-Xing Xiao . Revisiting MXenes-based Photocatalysis Landscape: Progress, Challenges, and Future Perspectives. Acta Physico-Chimica Sinica, 2024, 40(8): 2306048-0. doi: 10.3866/PKU.WHXB202306048
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
18. [18]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
19. [19]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
20. [20]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(599)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142