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Citation: LI Qu, QIN Wu, ZHANG Jun-jiao, CHENG Wei-liang, DONG Chang-qing. Characteristics and kinetics of chemical looping combustion of Mn-doped Fe2O3 oxygen carrier with CO[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(8): 932-937. shu

Characteristics and kinetics of chemical looping combustion of Mn-doped Fe2O3 oxygen carrier with CO

  • 1.

    1. National Engineering Laboratory for Biomass Power Generation Equipment, School of Renewable Energy Engineering, North China Electric Power University, Beijing 102206, China;

  • Corresponding author: QIN Wu, 
  • Received Date: 15 April 2014
    Available Online: 10 June 2014

    Fund Project: 国家自然科学基金(51206044)。 (51206044)

  • Mn-doped Fe2O3 oxygen carriers with different molar ratios of Fe to Mn were prepared by co-precipitation method, which were characterized by XRD, BET and TEM. Chemical looping combustion tests between Mn-Fe2O3 and CO at different temperatures were performed to investigate the reaction characteristics, and to determine the optimized Mn doping amount and reaction temperature. The results reveal that a rational Mn doping could enhance the reactivity of iron-base oxygen carrier, and the optimal Fe/Mn molar ratio is 50. Multi-cycle experiments confirm the high stability of the optimized oxygen carrier. Furthermore, the reaction kinetic analysis at heating rates of 30, 40, 50 ℃/min shows that the Avrami-Erofeev model is suitable for the reactions, and the activation energy and pre-exponential factor can be calculated according to the kinetic model.
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