Citation: HUA De-run, CHEN Sheng-li, ZHOU Zheng, CHEN Ai-cheng, LIU Hong-bo, HUANG Qing, LU Xin-ning. Effect of support on catalytic performance for metathesis of butene to propene[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(7): 865-869. shu

Effect of support on catalytic performance for metathesis of butene to propene

1.
1. Gannan Normal University, Chemical Institute of Chemical Industry, Ganzhou 341000, China;

Corresponding author: CHEN Sheng-li,
Received Date: 27 November 2013
Available Online: 11 March 2014

The catalysts with SBA-15, MCM-48, SiO₂, and MTS-9 as supports were synthesized with 8% WO₃, and their catalytic performance for metathesis of butene to propene were carried out. The conversion of butene is 30%~37% on the catalysts with SBA-15, MCM-48, and SiO₂ as supports, and that of butene is 37%~42% on WO₃/MTS-9 catalyst. The catalyst characterization results show that the catalytic activities depend on the acidic numbers of catalysts prepared and the distribution of tungstens on the supports used. As a result, the performance of 8% WO₃/MTS-9 catalyst for the titled reaction is best.
- propene,
- metathesis,
- support,
- WO₃
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