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Citation: WANG Lei, NUERMAIMAITI Abudukelimu, MA Yu-bo, QING Shao-jun, GAO Zhi-xian, WUMANJIANG Eli. Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(7): 839-844. shu

Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate

  • 1.

    1. Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Ulumqi 830011, China;

  • Corresponding author: GAO Zhi-xian, 
  • Received Date: 30 December 2013
    Available Online: 27 March 2014

  • Fe-modified Ru/Al2O3 (Ru-Fe/Al2O3) catalysts were prepared by adsorption-precipitation (AP) method with alumina as the support and characterized by H2-TPR, XRD and XPS; the effect of Fe modification on the catalytic performance of Ru-Fe/Al2O3 was investigated in the selective hydrogenation of dimethyl meleate (DMM) to dimethyl succinate (DMS). The results indicated that through the modification with a Fe/Ru atomic ratio above 2, the catalytic performance of Ru-Fe/Al2O3 and its stability towards high temperature oxidation-reduction treatment is obviously enhanced. Under 70℃, 1.0 MPa and with a stirring speed of 600 r/min, the conversion of DMM and the selectivity to DMS were both nearly 100%. The XPS and H2-TPR results suggest that the promoting effect of Fe on Ru-Fe/Al2O3 may be ascribed to an increase of Ru dispersion as well as a change in Ru electronic state through the modification with Fe.
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