Citation: FENG Jun-peng, ZHANG Ye, LÜ Zhan-jun, LI Xue-kuan. Study of poisoning effect of dimethyl disulfide on Ni/Al₂O₃ catalyst for hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(7): 833-838. shu

Study of poisoning effect of dimethyl disulfide on Ni/Al₂O₃ catalyst for hydrogenation

FENG Jun-peng ^1,2 ,
ZHANG Ye ^1,, ,
LÜ Zhan-jun ¹ ,
LI Xue-kuan ^1,,

1.
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: ZHANG Ye, LI Xue-kuan,
Received Date: 28 January 2014
Available Online: 31 March 2014
Fund Project: 中国科学院战略性先导科技专项(A类)(XDA07020400) (A类)(XDA07020400)中国科学院山西煤炭化学研究所知识创新工程(ylsc5c1581)。 (ylsc5c1581)

Poisoning effect of dimethyl disulfide (CH₃SSCH₃) on Ni/Al₂O₃ catalysts for hydrogenation of benzene, cyclohexene and styrene was studied. The structures and properties of the catalysts were investigated by means of BET, XRD, H₂-TPR, XPS, SEM and EA. Results indicated that with the existence of CH₃SSCH₃, Ni/Al₂O₃ catalysts quickly deactivated for benzene and cyclohexene hydrogenation, while the activity for styrene hydrogenation remained well. The sulfur tolerance of Ni/Al₂O₃ catalysts for cyclohexene hydrogenation was little better than that of benzene hydrogenation. The conversion of conjugated double bond of styrene can keep 100% for a long time. For hydrogenation reactions, the poisoning effects of CH₃SSCH₃ over Ni/Al₂O₃ were in the order of aromatic nucleus>monoene>conjugated alkene. In addition, poisoning mechanism of CH₃SSCH₃ for Ni/Al₂O₃ catalyst was also discussed. CH₃SSCH₃ molecules were firstly adsorbed on the surface of catalyst and then dissociated to CH₄ under the function of hydrogen and catalyst. It is concluded that the toxicity of carbon in CH₃SSCH₃ for catalysts is neglectful and remaining sulfur is the dominant poisoning factor by the interaction with active component.
- dimethyl disulfide,
- Ni/Al₂O₃,
- hydrogenation,
- poison
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Study of poisoning effect of dimethyl disulfide on Ni/Al2O3 catalyst for hydrogenation

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Study of poisoning effect of dimethyl disulfide on Ni/Al₂O₃ catalyst for hydrogenation