Citation: WANG Xu-hong, ZHU Hui, Huang Jin-shan, JI Wang-jin, LUO Xiu-qi. Performance of carbon fiber supported Pt-SnO2 anode catalyst for direct ethanol fuel cell[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 763-768. shu

Performance of carbon fiber supported Pt-SnO2 anode catalyst for direct ethanol fuel cell

  • Corresponding author: ZHU Hui, 
  • Received Date: 19 December 2013
    Available Online: 23 February 2014

    Fund Project: 江苏省自然科学基金(BK2007704)。 (BK2007704)

  • Nano Pt-SnO2 anode catalyst (with a Pt/Sn atomic ratio of 3) supported on carbon fiber was synthesized via electrospinning technology. The catalyst was characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and scanning electron microscopy (SEM); its activity for ethanol oxidation as an anode in direct ethanol fuel cell was evaluated through cyclic voltammogram (CV). The results showed that nano Pt-SnO2 catalyst is uniformly scattered around the skeleton of vesicular carbon fiber. The carbon fiber exhibits higher density, better conductive performance with the increase of sintering temperature. The electrocatalytic test results indicated that at a sintering temperature of 800 ℃, the catalyst exhibits the best peak current density (0.11 A/cm2) and the strongest tolerance to CO. Single cell power performance test suggests that highest power generation efficiency can be achieved with an injection velocity of 1.0 mL/min with proper ethanol concentration.
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    1. [1]

      [1] NI H J, LV C C, WANG X H. Study on Pt-SnO2/C electrode prepared by different content of Nafion for new direct ethanol fuel cells[J]. J Adv Mater Res, 2011, 399(4): 1408-1411.

    2. [2]

      [2] CASTROLUNA A M, BONESI A, TRAICA W E. Investigation of a Pt-Fe/C catalyst for oxygen reductionreaction in direct ethanol fuel cells[J]. J Nanopart Res, 2010, 10(12): 357-365.

    3. [3]

      [3] 徐明丽, 张正富, 杨显万. 纳米材料及其在电催化领域的研究进展[J]. 材料导报, 2006, 20(7): 2-6. (XU Ming-li, ZHANG Zheng-fu, YANG Xian-wan. Progress of research on nanomaterial used in electro-catalysis[J]. Materials Review, 2006, 20(7): 2-6.)

    4. [4]

      [4] 罗彬, 周德璧, 赵大鹏, 刘军, 王珏, 王俊杰. 直接乙醇燃料电池阳极催化材料的研究进展[J]. 材料导报, 2007, 21(9): 288-291. (LUO Bin, ZHOU De-bi, ZHAO Da-peng, LIU Jun, WANG Jue, WANG Jun-jie. Research on anode catalysts for direct ethanol fuel cell[J]. Materials Review, 2007, 21(9): 288-291.)

    5. [5]

      [5] 黄明宇, 倪红军, 周一丹, 朱昱, 骆兵. 质子交换膜燃料电池的研究与应用[J]. 南通大学学报(自然科学版), 2005, 4(4): 10-13. (HUANG Ming-yu, NI Hong-jun, ZHOU Yi-dan, ZHU Yu, LUO Bing. The research on PEMFC and its application[J]. Journal of Nantong University(Natural Sciences Edition), 2005, 4(4): 10-13.)

    6. [6]

      [6] APPLEBY A J. Fuel cell technology: Status and future prospects[J]. Energy, 1996, 21(7/8): 521-653.

    7. [7]

      [7] LAMY C, ROUSSEAU S, BELGSIR E M. Recent progress in the direct ethanol fuel cell: development of new platinum-tin electrocatalysts[J]. Electrochimica Acta, 2004, 49(22/23): 3901-3908.

    8. [8]

      [8] ZHENG H T, LI Y L, CHEN S X, SHEN P K. Effect of support on the activity of Pd electrocatalyst for ethanol oxidation[J]. J Power Sources, 2006, 163(1): 371-375.

    9. [9]

      [9] 袁善美, 朱昱, 倪红军, 黄明宇. 直接乙醇燃料电池研究进展[J]. 化工新型材料, 2011, 1(4): 15-18. (YUAN Shan-mei, ZHU Yu, NI Hong-jun, HUANG Ming-yu. Research progress on direct ethanol fuel cell[J]. Journal of New Chemical Materials, 2011, 1(4): 15-18.)

    10. [10]

      [10] 张朝群. 聚丙烯腈基复合纳米材料的制备及性能研究[D]. 吉林:吉林大学化学学院, 2011. (ZHANG Chao-qun. Preparation and applied studied of PAN-based nanocomposite[D]. Ji Lin: College of Chemistry, Jilin University, 2011.)

    11. [11]

      [11] ZHANG X W, ZHU H, GUO Z J. Sulfated SnO2 modified multi-walled carbon nanotubes-A mixed proton-electron conducting support for Pt catalysts in direct ethanol fuel cells[J]. J Power Sources, 2011, 196(6): 3048-3053.

    12. [12]

      [12] YU L H, XI J Y. CeO2 nanoparticles improved Pt-based catalysts for direct alcohol fuel cells[J]. Int J Hydrogen Energy, 2012, 37(10): 5938-5947.

    13. [13]

      [13] YONGPRAPAT S, THERDTHIANWONG A, THERDTHIANWONG S. Au/C catalyst prepared by polyvinyl alcohol protection method for direct alcohol alkaline exchange membrane fuel cell application[J]. J Appl Electrochem, 2012, 42(8): 483-490.

    14. [14]

      [14] NETO A O, TUSI M M, DE OLIVEIRA POLANCO N S, DA SILVAA S G, SANTOSB M C D, SPINACÉ E V. PdBi/C electrocatalysts for ethanol electro-oxidation in alkaline medium[J]. Int J Hydrogen Energy, 2011, 36(17): 10522-10526.

    15. [15]

      [15] THEPKAEW J, THERDTHIANWONG A. Effect of pre-treatment approach of a carbon support on activity of PtSn/C electrocatalysts for direct ethanol fuel cells[J]. J Appl Electrochem, 2011, 41(9): 435-444.

    16. [16]

      [16] MINORU U, HIROMASAS, ISAMU U. Alcohol electrooxidation at Pt and Pt-Ru sputtered electrodes under elevated temperature and pressurized conditions[J]. J Power Sources, 2008, 179(2): 489-496.

    17. [17]

      [17] 王旭红, 袁善美, 朱昱, 倪红军. 碳纤维基PtSn催化剂直接乙醇燃料电池制备及性能研究[J]. 燃料化学学报, 2012, 40(12): 1454-1458. (WANG Xu-hong, YUAN Shan-mei, ZHU Yu, NI Hong-jun. Preparation and performance research of PtSn catalystsupported on carbon fiber for direct ethanol fuel cells[J]. Journal of Fuel Chemistry and Technology, 2012, 40(12): 1454-1458.)

    18. [18]

      [18] DEIVARAJ T C, LEE J Y. Preparation of carbon-supported PtRu nanoparticles for direct methanol fuel cell applications-A comparative study[J]. J Power Sources, 2005, 142(1/2): 43-49.

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