Citation: ZHAO Zhao-hui, ZOU Han-bo, LIN Wei-ming. Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 758-762. shu

Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst

1.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Corresponding author: ZHAO Zhao-hui,
Received Date: 3 December 2013
Available Online: 27 March 2014
Fund Project: 国家自然科学基金(20806017) (20806017)广东省自然科学基金(10151009101000009)。 (10151009101000009)

The reaction kinetics of ammoniade composition over La-CoMoN_x/CNTs catalyst were studied. The effect of N₂ concentration, H₂ concentration, NH₃ concentration and reaction temperature on the rate of ammonia decomposition were investigated. According to the experimental data, the correlative kinetic parameters were determined based on an exponential equation. The intrinsic kinetic equation was obtained. The activation energy of the reaction was 93.948 kJ/mol. The reaction mechanism was also discussed. The reaction rate of ammonia decomposition over La-CoMoN_x/CNTs was controlled by the combination desorption of nitrogen on the surface of the catalyst.
- supported metallic nitride,
- catalysis,
- ammonia decomposition,
- hydrogen production,
- reaction kinetic
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Reaction kinetics of ammonia decomposition over La-CoMoNx/CNTs catalyst

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通讯作者: 陈斌, bchen63@163.com

Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst