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Citation: SONG Hua, WANG Zi-Dong, DAI Min, SONG Hua-Lin, WAN Xia, LI Feng. Preparation of Ni2P catalyst at low reduction temperature and its HDS performance[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 733-737. shu

Preparation of Ni2P catalyst at low reduction temperature and its HDS performance

  • 1.

    1. Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China;

  • Corresponding author: SONG Hua,  SONG Hua-Lin, 
  • Received Date: 8 December 2013
    Available Online: 26 March 2014

    Fund Project: 国家自然科学基金(21276048) (21276048)黑龙江省自然科学基金(ZD201201)。 (ZD201201)

  • The Ni2P/MCM-41 catalysts was prepared at low reduction temperature by temperature programmed reduction. The catalyst was characterized by H2-TPR, TG-DTG, XRD, BET, and XPS. The effects of reduction temperature on formation of the active Ni2P phase and HDS performance of the catalysts were studied. The results showed that a pure Ni2P phase can be obtained with samples reduced at low reduction temperature range of 210~390 ℃. The catalyst obtained at reduction temperature of 390 ℃ exhibited the highest HDS activity. At a reaction temperature of 340 ℃, pressure of 3.0 MPa, H2/oil volume ratio of 500, and weight hourly space velocity (WHSV) of 2.0 h-1, the DBT HDS conversion reached to 99.0%.
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