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Citation: SONG Hua, WANG Zi-Dong, DAI Min, SONG Hua-Lin, WAN Xia, LI Feng. Preparation of Ni2P catalyst at low reduction temperature and its HDS performance[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 733-737. shu

Preparation of Ni2P catalyst at low reduction temperature and its HDS performance

  • 1.

    1. Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China;

  • Corresponding author: SONG Hua,  SONG Hua-Lin, 
  • Received Date: 8 December 2013
    Available Online: 26 March 2014

    Fund Project: 国家自然科学基金(21276048) (21276048)黑龙江省自然科学基金(ZD201201)。 (ZD201201)

  • The Ni2P/MCM-41 catalysts was prepared at low reduction temperature by temperature programmed reduction. The catalyst was characterized by H2-TPR, TG-DTG, XRD, BET, and XPS. The effects of reduction temperature on formation of the active Ni2P phase and HDS performance of the catalysts were studied. The results showed that a pure Ni2P phase can be obtained with samples reduced at low reduction temperature range of 210~390 ℃. The catalyst obtained at reduction temperature of 390 ℃ exhibited the highest HDS activity. At a reaction temperature of 340 ℃, pressure of 3.0 MPa, H2/oil volume ratio of 500, and weight hourly space velocity (WHSV) of 2.0 h-1, the DBT HDS conversion reached to 99.0%.
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    1. [1]

      [1] 宋华, 代敏, 宋华林. Ni2P加氢脱硫催化剂[J]. 化学进展, 2012, 24(5): 43-47. (SONG Hua, DAI Min, SONG Hua-lin. Ni2P catalyst for hydrodesulfurization[J]. Progress in Chemistry, 2012, 24(5): 43-47.)

    2. [2]

      [2] KORANYI T I. Phosphorus promotion of Ni(Co)-containing Mo-free catalysts in thiophene hydrodesulfurization[J]. Appl Catal A: Gen, 2003, 239(1/2): 253-267.

    3. [3]

      [3] 余夕志, 王远强, 陈长林, 徐南平, 王延儒. Ni2P/TiO2的制备及其对苯加氢反应的催化性能[J]. 燃料化学学报, 2006, 34(1): 100-104. (YU Xi-zhi, WANG Yuan-qiang, CHEN Chang-lin, XU Nan-ping, WANG Yan-ru. Preparation of Ni2P/TiO2 catalyst and its reactivity for benzene hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2006, 34(1): 100-104.)

    4. [4]

      [4] SEO H R, CHO K S, LEE Y K. Formation mechanisms of Ni2P nanocrystals using XANES and EXAFS spectroscopy[J]. Mater Sci Eng: B, 2011, 176(2): 132-140.

    5. [5]

      [5] SONG L M, ZHANG S J, WEI Q W. A new route for synthesizing nickel phosphide catalysts with high hydrodesulfurization activity based on sodium dihydrogenphosphite[J]. Catal Commun, 2011, 12(12): 1157-1160.

    6. [6]

      [6] 刘理华, 刘书群, 柴永明, 刘晨光. 磷化镍催化剂的制备机理及其加氢脱氮性能[J]. 燃料化学学报, 2013, 41(3): 335-340. (LIU Li-hua, LIU Shu-qun, CHAI Yong-ming, LIU Chen-guang. Preparation mechanism and hydrodenitrogenation performance of nickel phosphide catalyst[J]. Journal of Fuel Chemistry and Technology, 2013, 41(3): 335-340.)

    7. [7]

      [7] SONG L M, ZHANG S J. A versatile route to synthesizing bulk and supported nickel phosphides by thermal treatment of a mechanical mixing of nickel chloride and sodium hypophosphite[J]. Powder Technol, 2011, 208(3): 713-716.

    8. [8]

      [8] GUAN Q X, LI W, ZHANG M H, TAO K Y. Alternative synthesis of bulk and supported nickel phosphide from the thermal decomposition of hypophosphites[J]. J Catal, 2009, 263(1): 1-3.

    9. [9]

      [9] CECILIA J A, INFANTES-MOLINA A, RODRIGUEZ-CASTELLON E, JIMENEZ-LOPEZ A. A novel method for preparing an active nickel phosphide catalyst for HDS of dibenzothiophene[J]. J Catal, 2009, 263(1): 4-15.

    10. [10]

      [10] MELENDEZ-ORTIZ H I, GARCIA-CERDA L A, OLIVARES-MALDONADO Y, CASTRUITA G, MERCADO-SILVA J A, PERERA-MERCADO Y A. Preparation of spherical MCM-41 molecular sieve at room temperature: Influence of the synthesis conditions in the structural properties[J]. Ceram Int, 2012, 38(8): 6353-6358.

    11. [11]

      [11] GUAN J, WANG Y, QIN M L, YANG Y, LI X, WANG A J. Synthesis of transition-metal phosphides from oxidic precursors by reduction in hydrogen plasma[J]. J Solid State Chem, 2009, 182(6): 1550-1555.

    12. [12]

      [12] CHO K S, SEO H R, LEE Y K. A new synthesis of highly active Ni2P/Al2O3 catalyst by liquid phase phosphidation for deep hydrodesulfurization[J]. Catal Commun, 2011, 12(6): 470-474.

    13. [13]

      [13] SONG H, DAI M, GUO Y T, ZHANG Y J. Preparation of composite TiO2-Al2O3 supported nickel phosphide hydrotreating catalysts and catalytic activity for hydrodesulfurization of dibenzothiophene[J]. Fuel Process Technol, 2012, 96: 228-236.

    14. [14]

      [14] BERHAULT G, AFANASIEV P, LOBOUE H, GEANTET C, CSERI T, PICHON C, GUILLOT-DEUDON C, LAFOND A. In situ XRD, XAS, and magnetic susceptibility study of the reduction of ammonium nickel phosphate NiNH4PO4·H2O into nickel phosphide[J]. Inorg Chem, 2009, 48(7): 2985-2992.

    15. [15]

      [15] ELICHE-QUESADA D, MERIDA-ROBLES J, MAIRELES-TORRES P, RODRIGUEZ-CASTELLON E, BUSCA G, FINOCCHIO E, JIMENEZ-LOPEZ A. Effects of preparation method and sulfur poisoning on the hydrogenation and ring opening of tetralin on NiW/zirconium-doped mesoporous silica catalysts[J]. J Catal, 2003, 220(2): 457-467.

    16. [16]

      [16] KUHN J N, LAKSHMINARAYANAN N, OZKAN U S. Effect of hydrogen sulfide on the catalytic activity of Ni-YSZ cermets[J]. J Mol Catal A: Chem, 2008, 282(1/2): 9-21.

    17. [17]

      [17] KANAMA D, OYAMA S T, OTANI S, COX D F. Ni2P (0001) by XPS[J]. Surf Sci Spectra, 2001, 8(3): 220-224.

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