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Citation: LI Yu-ping, CHEN Lun-gang, WANG Tie-jun, MA Long-long, WU Chuang-zhi, QIU Song-bai. Ru modified Co/SiO2/HZSM-5 catalysts for jet fuel-range hydrocarbons synthesis[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 727-732. shu

Ru modified Co/SiO2/HZSM-5 catalysts for jet fuel-range hydrocarbons synthesis

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    CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Guangzhou 510640, China

  • Corresponding author: WANG Tie-jun,  MA Long-long, 
  • Received Date: 10 October 2013
    Available Online: 13 February 2014

    Fund Project: 国家自然科学基金(51276183,51036006) (51276183,51036006)国家自然科学基金中日国际合作项目(51161140331) (51161140331)国家重点基础研究发展规划(973计划,2013CB228105)。 (973计划,2013CB228105)

  • Selective synthesis of jet fuel-range hydrocarbons (C8~18) was investigated in a fixed-bed reactor over Ru modified cobalt-based catalysts, supported on mesoporous SiO2 and microporous HZSM-5. The effect of Ru adding amount (1%~4%) and the textual and structural properties of the catalysts on Fischer-Tropsch synthesis(FTS) performance were studied. The results showed that the tailor-made Ru-Co/SiO2/HZSM-5 catalysts maintained both meso-and micro-pores. Co dispersion and reducibility at 150~750 ℃ were enhanced with the increase of Ru amount, which resulted in the increase of CO conversion. In the same time, the yield of iso-paraffins was enhanced due to the existence of microporous structure of HZSM-5. Thus CO conversion of 62.8% and yield of jet fuel-range hydrocarbons (C8~18) of 37.7%, including 10.9% of iso-paraffins, were achieved over 1% Ru modified Co/SiO2/HZSM-5. The FTS product distribution shifted to low-carbon hydrocarbons when Ru amount was higher than 2% due to the increased CO hydrogenation rate and CH4 selectivity.
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    1. [1]

      [1] GARDEZI S A, WOLAN J T, JOSEPH B. Effect of catalyst preparation conditions on the performance of eggshell cobalt/SiO2 catalysts for Fischer-Tropsch synthesis[J]. Appl Catal A: Gen, 2012, 447-448: 151-163.

    2. [2]

      [2] 闫朋辉, 陶智超, 郝坤, 王煜丹, 杨勇, 李永旺. 金属载体结合方式对镍钨催化剂费托合成蜡加氢裂化性能的影响[J]. 燃料化学学报, 2013, 41(6): 691-697. (YAN Peng-hui, TAO Zhi-chao, HAO Kun, WANG Yu-dan, YANG Yong, LI Yong-wang. Effect of impregnation methods on nickel-tungsten catalysts and its performance on hydrocracking Fischer-Tropsch wax[J]. Journal of Fuel Chemistry and Technology, 2013, 41(6): 691-697.)

    3. [3]

      [3] BRUNO T J, BAIBOURINE E, LOVESTEAD T M. Comparison of synthetic isoparaffinic kerosene turbine fuels with the composition-explicit distillation curve method[J]. Energy Fuels, 2010, 24(5): 3049-3059.

    4. [4]

      [4] YAN Q, YU F, LIU J, STREET J, GAO J, CAI Z, ZHANG J. Catalytic conversion wood syngas to synthetic aviation turbine fuels over a multifunctional catalyst[J]. Bioresour Technol, 2013, 127: 281-290.

    5. [5]

      [5] KHODAKOV A Y, CHU W, FONGARLAND P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels[J]. Chem Rev, 2007, 107(5): 1692-1744.

    6. [6]

      [6] QIU X, TSUBAKI N, SUN S, FUJIMOTO K. Promoting effect of noble metals to Co/SiO2 catalysts for hydroformylation of 1-hexene[J]. Catal Commun, 2001, 2(2): 75-80.

    7. [7]

      [7] TSUBAKI N, SUN S, FUJIMOTO K. Different functions of the noble metals added to cobalt catalysts for Fischer-Tropsch synthesis[J]. J Catal, 2001, 199(2): 236-246.

    8. [8]

      [8] TEISEH E A, CAPAREDA S, REZENOM Y H. Cobalt based hybrid Fischer-Tropsch synthesis catalyst for improved selectivity of hydrocarbons in the JP-8 carbon number range from a synthesis gas obtained from the pyrolysis of the MixAlco process derived sludge[J]. Appl Catal A:Gen, 2012, 437-438: 63-71.

    9. [9]

      [9] LI Y P, WANG T J, WU C Z, QIN X X, TSUBAKI N. Effect of Ru addition to Co/SiO2/HZSM-5 catalysts on Fischer-Tropsch synthesis of gasoline-range hydrocarbons[J]. Catal Commun, 2009, 10(14): 1868-1874.

    10. [10]

      [10] NGAMCHARUSSRIVICHAI C, LIU X, LI X, VITIDSANT T, FUJIMOTO K. An active and selective production of gasoline-range hydrocarbons over bifunctional Co-based catalysts[J]. Fuel, 2007, 86(1/2): 50-59.

    11. [11]

      [11] KOGELBAUER A, GOODWIN J J G, OUKACI R. Ruthenium promotion of Co/Al2O3 Fischer-Tropsch catalysts[J]. J Catal, 1996, 160(1): 125-133.

    12. [12]

      [12] NURUNNABI M, MURATA K, OKABE K, INABA M, TAKAHARA I. Effect of Mn addition on activity and resistance to catalyst deactivation for Fischer-Tropsch synthesis over Ru/Al2O3 and Ru/SiO2 catalysts[J]. Catal Commun, 2007, 8(10): 1531-1537.

    13. [13]

      [13] IGLESIA E, SOLED S L, FIATO R A, VIA G H. Bimetallic synergy in cobalt ruthenium Fischer-Tropsch synthesis catalysts[J]. J Catal, 1993, 143(2): 345-368.

    14. [14]

      [14] 徐东彦, 李文钊, 段洪敏, 葛庆杰, 徐恒泳. Pt, Ru和Pd助剂对F-T合成中Co/γ-Al2O3催化剂性能的影响[J]. 催化学报, 2005, 26(9): 780-784. (XU Dong-yan, LI Wen-zhao, DUAN Hong-min, GE Qing-jie, XU Heng-yong. Effect of Pt, Ru and Pd promoters on the performance of Co/γ-Al2O3 Catalysts for Fischer-Tropsch synthesis[J]. Chinese Journal of Catalysis, 2005, 26(9): 780-784.)

    15. [15]

      [15] CHUDEK J A, MCQUIRE M W, ROCHESTER C H. Comparative FT-IR and MAS NMR spectroscopic studies of Rh/SiO2 catalysts exposed to CO/H2 at high temperature and pressure[J]. J Catal, 1992, 135(2): 358-366.

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