Citation: NIU Sheng-li, LIU Meng-qi, LU Chun-mei, LI Hui, HUO Meng-jia. Catalytic performance of carbide slag loaded with potassium fluoride in transesterification[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 690-696. shu

Catalytic performance of carbide slag loaded with potassium fluoride in transesterification

1.
School of Energy and Power Engineering, Shandong University, Jinan 250061, China

Corresponding author: NIU Sheng-li,
Received Date: 29 November 2013
Available Online: 19 January 2014
Fund Project: 国家自然科学基金(51206098) (51206098)山东省优秀中青年科学家科研奖励基金(BS2012NJ005)。 (BS2012NJ005)

Using the potassium fluoride as the active site and the carbide slag as the carrier, a calcium-based loaded catalyst for the transesterification was prepared through the impregnation method. The catalyst was characterized by X-ray fluorescence, thermogravimetric analysis, X-ray diffraction, nitrogen adsorption and desorption, scanning electron microscope and Hammett indicator. Also, the composition of peanut oil was analyzed by gas chromatograph. Then, the performance of prepared catalyst in the transesterification of peanut oil with methanol was examined with a batchwise experimental system. After being loaded with potassium fluoride, the new textural phases of KCaF₃, CaF₂ and KF emerge. Under the condition of the catalyst addition of 5%, the transesterification temperature of 62 ℃, the transesterification time of 2 h and the molar ratio of methanol to oil of 15, the glycerol yield of 91.58% can be achieved. Compared with calcium hydroxide and unloaded carbide slag, this loaded catalyst has a better performance.
- transesterification,
- catalyst,
- carbide slag,
- potassium fluoride,
- load
1. [1]
  [1] 郑华艳, 李茜茜, 崔丽萍, 李忠. Ca/Al固体碱催化菜籽油制备生物柴油[J]. 燃料化学学报, 2012, 40(3): 331-336. (ZHENG Hua-yan, LI Qian-qian, CUI Li-ping, LI Zhong. Synthesis of biodiesel from rapeseed oil catalyzed by Ca/Al solid base[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 331-336.)
2. [2]
  [2] 梁金花, 任晓乾, 王锦堂, 姜岷, 李振江. 双核碱性离子液体催化棉籽油酯交换制备生物柴油[J]. 燃料化学学报, 2010, 38(3): 275-280. (LIANG Jin-hua, REN Xiao-qian, WANG Jin-tang, JIANG Min, LI Zhen-jiang. Preparation of biodiesel by transesterification from cottonseed oil using the basic dication ionic liquids as catalysts[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 275-280.)
3. [3]
  [3] 侯凯丽, 赵华, 田薇薇, 李会鹏. 固体催化剂催化酯交换反应制备生物柴油研究进展[J]. 工业催化, 2010, 18(8): 7-11. (HOU Kai-li, ZHAO Hua, TIAN Wei-wei, LI Hui-peng. Latest researches in synthesis of biodiesel biodiesel via transesterification catalyzed by solid catalysts[J]. Industrial Catalysis, 2010, 18(8): 7-11.)
4. [4]
  [4] KOUZU M, HIDAKA J. Transesterification of vegetable oil into biodiesel catalyzed by CaO: A review[J]. Fuel, 2012, 93: 1-12.
5. [5]
  [5] WEI Z K, XU C L, LI B X. Application of waste eggshell as low-cost solid catalyst for biodiesel production[J]. Bioresour Technol, 2009, 100(11): 2883-2885.
6. [6]
  [6] BOEY P L, MANIAM G P, HAMID S A, ALI D M H. Crab and cockle shells as catalyst for the preparation of methyl esters from low FFA chicken fat[J]. J Am Oil Chem Soc, 2011, 88(2): 283-288.
7. [7]
  [7] NAKATANI N, TAKAMORI H, TAKEDA K, SAKUGAWA H. Transesterification of soybean oil using combusted oyster shell waste as a catalyst[J]. Bioresour Technol, 2009, 100(3): 1510-1513.
8. [8]
  [8] LI Y J, LIU H L, SUN R Y, WU S M, LU C M. Thermal analysis of cyclic carbonation behavior of CaO derived from carbide slag at high temperature[J]. J Therm Anal Calorim, 2012, 110(2): 685-694.
9. [9]
  [9] 谭亚, 李彩亭, 曾光明, 翟云波, 李珊红, 邓久华. 添加剂对燃煤电石渣固硫的促进作用[J]. 燃料化学学报, 2005, 33(6): 767-770. (TAN Ya, LI Cai-ting, ZENG Guang-ming, ZHAI Yun-bo, LI Shan-hong, DENG Jiu-hua. Promotion effect of additives on sulfur capture during coal combustion with carbide slag[J]. Journal of Fuel Chemistry and Technology, 2005, 33(6): 767-770.)
10. [10]
  [10] NIU S L, LIU M Q, LU C M, LI H, HUO M J. Thermogravimetric analysis of carbide slag: A potential transesterification catalyst validation[J]. J Therm Anal Calorim, 2014, 115(1): 73-79.
11. [11]
  [11] 牛胜利, 李辉, 路春美, 刘梦琪, 霍梦佳. 造纸白泥催化花生油与甲醇酯交换的特性研究[J]. 燃料化学学报, 2013, 41(7): 856-861. (NIU Sheng-li, LI Hui, LU Chun-mei, LIU Meng-qi, HUO Meng-jia. Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7): 856-861.)
12. [12]
  [12] GAO L, TENG G, XIAO G, WEI R. Biodiesel from palm oil via loading KF/Ca-Al hydrotalcite catalyst[J]. Biomass Bioenergy, 2010, 34(9): 1283-1288.
13. [13]
  [13] 钱卫卫, 韩萍芳, 吕效平. 超声作用下KF/CaO催化酯交换反应制备生物柴油[J]. 燃料化学学报, 2010, 38(1): 52-56. (QIAN Wei-wei, HAN Ping-fang, LV XIAO-ping. KF/CaO as solid base catalyst for transesterification to biodiesel by ultrasound[J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 52-56.)
14. [14]
  [14] 刘云, 陈文, 邓利. 生物柴油工艺技术[M]. 北京: 化学工业出版社, 2011: 12-13. (LIU Yun, CHEN Wen, DENG Li. Process technology of biodiesel[M]. Beijing: Chemical Industry Press, 2011: 12-13.)
15. [15]
  [15] YIN J Z, MA Z, SHANG Z Y, HU D P, XIU Z L. Biodiesel production from soybean oil transesterification in subcritical methanol with K₃PO₄ as catalyst[J]. Fuel, 2012, 93: 284-287.
16. [16]
  [16] FREEDMAN B, PRYDE E H, MOUNTS T L. Variables affecting the yields of fatty esters from transesterified vegetable oil[J]. J Am Oil Chem Soc, 1984, 61(10): 1638-1643.
17. [17]
  [17] 李亚娥. 非负载型固体碱催化剂制备生物柴油的研究[D]. 西安: 西北大学, 2010. (LI Ya-e. Study on non-carrier solid base catalysts for synthsis of biodiesel[D]. Xi'an: Xibei University, 2010.)
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
6. [6]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
7. [7]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
8. [8]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
9. [9]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
10. [10]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
11. [11]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
12. [12]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
13. [13]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
14. [14]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
17. [17]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
18. [18]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
19. [19]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
20. [20]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(398)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142