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Citation: NIU Sheng-li, LIU Meng-qi, LU Chun-mei, LI Hui, HUO Meng-jia. Catalytic performance of carbide slag loaded with potassium fluoride in transesterification[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 690-696. shu

Catalytic performance of carbide slag loaded with potassium fluoride in transesterification

  • 1.

    School of Energy and Power Engineering, Shandong University, Jinan 250061, China

  • Corresponding author: NIU Sheng-li, 
  • Received Date: 29 November 2013
    Available Online: 19 January 2014

    Fund Project: 国家自然科学基金(51206098) (51206098)山东省优秀中青年科学家科研奖励基金(BS2012NJ005)。 (BS2012NJ005)

  • Using the potassium fluoride as the active site and the carbide slag as the carrier, a calcium-based loaded catalyst for the transesterification was prepared through the impregnation method. The catalyst was characterized by X-ray fluorescence, thermogravimetric analysis, X-ray diffraction, nitrogen adsorption and desorption, scanning electron microscope and Hammett indicator. Also, the composition of peanut oil was analyzed by gas chromatograph. Then, the performance of prepared catalyst in the transesterification of peanut oil with methanol was examined with a batchwise experimental system. After being loaded with potassium fluoride, the new textural phases of KCaF3, CaF2 and KF emerge. Under the condition of the catalyst addition of 5%, the transesterification temperature of 62 ℃, the transesterification time of 2 h and the molar ratio of methanol to oil of 15, the glycerol yield of 91.58% can be achieved. Compared with calcium hydroxide and unloaded carbide slag, this loaded catalyst has a better performance.
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