Citation: REN Shi-biao, SHEN Zhou, ZHANG Ping, WANG Zhi-cai, LEI Zhi-ping, PAN Chun-xiu, KANG Shi-gang, SHUI Heng-fu. Highly dispersed Ni/SBA-15 catalysts prepared with different nickel salts as nickel precursors:Effects of activation atmospheres[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(5): 591-596. shu

Highly dispersed Ni/SBA-15 catalysts prepared with different nickel salts as nickel precursors:Effects of activation atmospheres

1.
School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Clean Coal Conversion and Utilization, Anhui University of Technology, Ma'anshan 243002, China

Received Date: 16 December 2013
Available Online: 25 February 2014
Fund Project: Supported by the National Natural Science Foundation of China (U1361125, U1261208, 21176001, 51174254) (U1361125, U1261208, 21176001, 51174254)

With nickel nitrate and nickel acetate as nickel precursors, a series of Ni/SBA-15 catalysts were prepared by using the impregnation method and activating in air or hydrogen atmosphere. The Ni/SBA-15 catalysts were characterized with XRD, H₂-TPD, N₂ physisorption and online mass spectroscopy. Their catalytic properties were evaluated with hydrogenation of naphthalene as a model reaction. It was shown that activation in hydrogen greatly increased the Ni dispersion and catalytic activity of Ni/SBA-15 prepared with nickel nitrate, while activation in air significantly improved the sample prepared with nickel acetate. In terms of the thermal decomposition products of the catalyst precursors activated in different atmospheres, the affecting mechanism of the activation atmosphere on the Ni/SBA-15 catalysts prepared with different nickel precursors was proposed.
- Ni/SBA-15,
- nickel nitrate,
- nickel acetate,
- activation atmosphere,
- dispersion,
- hydrogenation of naphthalene
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沈阳化工大学材料科学与工程学院沈阳 110142