Citation: LI Qiao-yan, HOU Ya-qin, HAN Xiao-jin, HUANG Zhang-gen, GUO Qian-qian, SUN De-kui, LIU Jian-dong. Selective catalytic reduction of NO with NH₃ over activated carbon impregnated with melamine at low temperature[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(4): 487-493. shu

Selective catalytic reduction of NO with NH₃ over activated carbon impregnated with melamine at low temperature

1.
1. State key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: HUANG Zhang-gen,
Received Date: 2 December 2013
Available Online: 9 February 2014
Fund Project: 国家自然科学基金(21103218,21106174,21177136) (21103218,21106174,21177136)中国科学院战略性先导科技专项(XDA07030300)。 (XDA07030300)

N-doped activated carbons (ACM) was obtained by impregnated activated carbon (AC) with melamine (M). The relationship between the impregnated time and calcination temperature on the nitrogen content and NH₃-SCR activity was investigated. Results showed that SCR activity of ACM was higher than original AC. For ACM-5-900 was about 51.67% at 80 ℃ while AC was about 21.92%. Characterizations of BET, element analysis and XPS were employed to study the structural properties, nitrogen contents and distribution of nitrogen-containing groups of ACM. Results indicated that NO conversion of ACM was influenced by the form of nitrogen-containing functional groups rather than the nitrogen content. The NO+O₂-TPD revealed that nitrogen-containing surface groups of ACM facilitated the adsorption and oxidation of NO, leading to the higher NO conversion. However, SO₂ played an inhibit role on NO conversion of ACM.
- DeNO_x,
- activated carbon,
- SCR,
- N-containing groups
1. [1]
  [1] 于艳科, 何炽, 陈进生, 孟小然. 电厂烟气脱硝催化剂V₂O₅-WO₃/TiO₂失活机理研究[J]. 燃料化学学报, 2012, 40(11): 1359-1365. (YU Yan-ke, HE Chi, CHEN Jin-sheng, MENG Xiao-ran. Deactivation mechanism of de-NO_x catalyst (V₂O₅-WO₃/TiO₂) used in coal fired power plant[J]. Journal of Fuel Chemistry Technology, 2012, 40(11): 1359-1365.)
2. [2]
  [2] YUN B K, KIM M Y. Modeling the selective catalytic reduction of NO_x by ammonia over a Vanadia-based catalyst from heavy duty diesel exhaust gases[J]. Appl Therm Eng, 2013, 50(1): 152-158.
3. [3]
  [3] 焦峰斌, 张亚平, 沈凯, 孙克勤, 徐海涛, 周长城. γ-Al₂O₃对SCR脱硝催化剂V₂O₅-WO₃/TiO₂的改性研究[J]. 燃料化学学报, 2012, 40(10): 1258-1263. (JIAO Feng-bin, ZHANG Ya-ping, SHEN Kai, SUN Ke-qin, XU Hai-tao, ZHOU Chang-cheng. γ-Al₂O₃ modification on V₂O₅-WO₃/TiO₂ catalyst for selective catalytic reduction (SCR) of NO[J]. Journal of Fuel Chemistry Technology, 2012, 40(10): 1258-1263.)
4. [4]
  [4] HUANG M C, TENG H. Nitrogen-containing carbons from phenol-formaldehyde resins and their catalytic activity in NO reduction with NH₃[J]. Carbon, 2003, 41(5): 951-957.
5. [5]
  [5] 马建蓉, 刘振宇, 郭士杰. 同时脱除烟气中硫和硝的V₂O₅/AC催化剂研究[J]. 燃料化学学报, 2005, 33(1): 5-11. (MA Jian-rong, LIU Zhen-yu, GUO Shi-jie. Simultaneuos removal of SO₂ and NO by V₂O₅/AC catalyst[J]. Journal of Fuel Chemistry Technology, 2005, 33(1): 5-11.)
6. [6]
  [6] 于英民, 郭瑞莉, 李春虎. 半焦吸附剂烟气脱硫脱硝性能[J]. 燃料化学学报, 2011, 39(5): 385-389. (YU Ying-min, GUO Rui-li, LI Chun-hu. Flue gas desulfurization and denitrification performance of the semi-coke adsorbents[J]. Journal of Fuel Chemistry Technology, 2011, 39(5): 385-389.)
7. [7]
  [7] RATHORE R S, SRIVASTAVA D K, AGARVAL A K, VERMA N. Development of surface functionalized activated carbon fiber for control of NO and particulate matter[J]. J Hazard Mater, 2010, 173(1/3): 211-222.
8. [8]
  [8] BASHKOVA S, BANDOSZ T J. The effects of urea modification and heat treatment on the process of NO₂ removal by wood-based activated carbon[J]. J Colloid Interface Sci, 2009, 333(1): 97-103.
9. [9]
  [9] SERP P, FIGUETREDO J L. Carbon materials for catalysis[M]. Hoboken: John Wiley &Sons, Inc, 2009.
10. [10]
  [10] SZYM'NSK G S, GRZYBEK T, PAPP H. Influence of nitrogen surface functionalities on the catalytic activity of activated carbon in low temperature SCR of NO with NH₃[J]. Catal Today, 2004, 90(1/2): 51-59.
11. [11]
  [11] SAMOJEDEN B, KLINIK J, GRZYBEK T, SUORUN W, GLASER R, PAPP H. DeNO_x properties of activated carbons modified with N-compounds. Kraków: V Krakowska Konferencja Modych Uczonych, 2010.
12. [12]
  [12] NOWICKI P, PIETRZAK R, WACHOWSKA H. X-ray photoelectron spectroscopy study of nitrogen-enriched active carbons obtained by ammoxidation and chemical activation of brown and bituminous coals[J]. Energy Fuels, 2010, 24(2): 1197-1206.
13. [13]
  [13] RAYMUNDO E, CZAORAL D, LINARES A, FIND J, WILD U, SCHLOGL R. Structural characterization of N-containing activated carbon fibers prepared from a low softening point petroleum pitch and a melamine resin[J]. Carbon, 2002, 40(4): 597-608.
14. [14]
  [14] PIETRZAK R. XPS study and physico-chemical properties of nitrogen-enriched microporous activated carbon from high volatile bituminous coal[J]. Fuel, 2009, 88(10): 1871-1877.
15. [15]
  [15] BOUDOU J P, PARENT P, SUAREZ F, VILLAR S, MARTINEZ A, TASCON J M D. Nitrogen in aramid-based activated carbon fibers by TPD, XPS and XANES[J]. Carbon, 2006, 44(12): 2452-2462.
16. [16]
  [16] PIETRZAK R, WACHOWSKA H, NOWICKI P. Preparation of nitrogen-enriched activated carbons from brown coal[J]. Energy Fuels, 2006, 20(3): 1275-1280.
17. [17]
  [17] LAHAYE J, NANSE G, BAGREEV A, STRELKO V. Porous structure and surface chemistry of nitrogen containing carbons from polymers[J]. Carbon, 1999, 37(4): 585-590.
18. [18]
  [18] GRZYBEK T, KLINIK J, SAMOJEDEN B, SUPRUN V, PAPP H. Nitrogen-promoted active carbons as DeNO_x catalysts. 1. The influence of modification parameters on the structure and catalytic properties[J]. Catal Today, 2008, 137(2/4): 228-234.
19. [19]
  [19] IZQUIERDO M T, RUBIO B, MAYORAL C, ANDRES J M. Modifications to the surface chemistry of low-rank coal-based carbon catalysts to improve flue gas nitric oxide removal[J]. Appl Catal B: Environ, 2001, 33(4): 315-324.
20. [20]
  [20] SOUSA J P S, PEREIRA M F R, FIGUEIREDO J L. NO oxidation over nitrogen doped carbon xerogels[J]. Appl Catal B: Environ, 2012, 125(21): 398-408.
21. [21]
  [21] SOUSA J P S, PEREIRA M F R, FIGUEIREDO J L. Catalytic oxidation of NO to NO₂on N-doped activated carbons[J]. Catal Today, 2011, 176(1): 383-387.
22. [22]
  [22] SOUSA J P S, PEREIRA M F R, FIGUEIREDO J L. Modified activated carbon as catalyst for NO oxidation[J]. Fuel Process Technol, 2013, 106(2): 727-733.
23. [23]
  [23] WAN X K, SHI H X, ZOU X Q, GE P. Effect of nitrogen doping on the reduction of nitric oxide with activated carbon in the presence of oxygen[J]. J Zhejiang Univ Sci A, 2008, 9(1): 113-117.
24. [24]
  [24] STOHR B, BOEHM H P, SCHLOGL R. Enhancement of the catalytic activity of activated carbons in oxidation reactions by thermal treatment with ammonia or hydrogen cyanide and observation of a superoxide species as a possible intermediate[J]. Carbon, 1991, 29(6): 707–720.
25. [25]
  [25] STRELKO V V, KUTS V S, THROWER P A. On the mechanism of possible influence of heteroatoms of nitrogen,boron and phosphorusin a carbon matrix on the catalytic activity of carbons in electron transfer reactions[J]. Carbon, 2000, 38(10): 1499-1524.
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沈阳化工大学材料科学与工程学院沈阳 110142

Selective catalytic reduction of NO with NH3 over activated carbon impregnated with melamine at low temperature

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通讯作者: 陈斌, bchen63@163.com

Selective catalytic reduction of NO with NH₃ over activated carbon impregnated with melamine at low temperature