Citation: ZHANG San-bing, LI Zuo-peng, LU Run-hua, WANG Xiao-lai. Effects of Ni content of Ni/hydroxyapatite catalysts on catalytic properties for carbon dioxide reforming of methane[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(4): 461-466. shu

Effects of Ni content of Ni/hydroxyapatite catalysts on catalytic properties for carbon dioxide reforming of methane

1.
1. Department of Applied Chemistry, College of Sciences, China Agricultural University, Beijing 100094, China;

Corresponding author: ZHANG San-bing,
Received Date: 27 October 2013
Available Online: 16 December 2013
Fund Project: 北京高等学校"青年英才计划"项目(YETP0325) (YETP0325)中央高校基本科研业务费专项资金(2011JS026)。 (2011JS026)

Carbon dioxide reforming of methane to synthesis gas was investigated with a series of Ni catalysts supported on Hydroxyapatite (HAp) prepared by chemical precipitation at low temperature. The structure and properties of the catalysts were characterized using BET, H₂-TPR, XRD, SEM, FT-IR , TEM and TG-DTA techniques. The 13% NiO/HAp showed the highest activity for catalytic carbon dioxide reforming of methane to synthesis gas. Under the condition of an atmospheric pressure at 850 ℃ and a gas hour space velocity (GHSV) of 3.6 ×10⁴ mL/(h·g_cat), the conversion of CH₄ and CO₂ over 13% Ni/HAp catalyst remained almost constant, at about 72% and 83%, for 10 h, respectively, which was ascribed to strong metal-support interaction. Most of the carbonaceous deposits on the catalyst surface were in whisker form, which did not cover the active sites and then had limited influence on the catalyst activity and stability.
- hydroxyapatite,
- nickel,
- carbon dioxide reforming of methane
1. [1]
  [1] BRADFORD M C J, VANNICE M A. CO₂ reforming of CH₄[J]. Catal Rev Sci Eng, 1999, 41(1): 1-42.
2. [2]
  [2] 王莉, 敖先权, 王诗瀚. 甲烷与二氧化碳催化重整制取合成气催化剂[J]. 化学进展, 2012, 24(9): 1696-1706. (WANG Li, AO Xian-quan, WANG Shi-han. Catalysts for carbon dioxide catalytic reforming of methane to synthesis gas[J]. Progress in Chemistry, 2012, 24(9): 1696-1706.)
3. [3]
  [3] XIE X, OTREMBA T, LITTLEWOOD P, SCHOMCKER R, THOMAS A. One-pot synthesis of supported, nanocrystalline nickel manganese oxide for dry reforming of methane[J]. ACS Catal, 2013, 3(2): 224-229.
4. [4]
  [4] ZHANG S, MURATSUGU S, ISHIGURO N, TADA M. Ceria-doped Ni/SBA-16 catalysts for dry reforming of methane[J]. ACS Catal, 2013, 3(2): 224-229.
5. [5]
  [5] ZUO Z J, SHEN C F, TAN P J, HUANG W. Ni based on dual-support Mg-Al mixed oxides and SBA-15 catalysts for dry reforming of methane[J]. Catal Commun, 2013, 41: 132-135.
6. [6]
  [6] ZHANG S, WANG J, LIU H, WANG X. One-pot synthesis of Ni-nanoparticle-embedded mesoporous titania/silica catalyst and its application for CO₂-reforming of methane[J]. Catal Commun, 2008, 9(6): 995-1000.
7. [7]
  [7] 孙楠楠, 闻霞, 王峰, 彭伟才, 肖福魁, 魏伟, 孙予罕, 李海. 反应条件对Ni-CaO-ZrO₂催化剂上CH₄-CO₂重整反应及积炭的影响[J]. 燃料化学学报, 2012, 40(3): 345-349. (SUN Nan-nan, WEN Xia, WANG Feng, PENG Wei-cai, XIAO Fu-kui, WEI Wei, SUN Yu-han, LI Hai. Influences of reaction conditions on the CH₄-CO₂ reforming and coking properties of a Ni-CaO-ZrO₂ catalyst[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 345-349.)
8. [8]
  [8] 张定林, 赵华文, 赵先英, 刘毅敏, 陈华, 李贤均. 羟基磷灰石作催化剂和催化剂载体的应用[J]. 化学进展, 2011, 23(4): 688-694. (ZHANG Ding-lin, ZHAO Hua-wen, ZHAO Xian-ying, LIU Yi-min, CHEN Hua, LI Xian-jun. Application of hydroxyapatite as catalyst and catalyst carrier[J]. Progress in Chemistry, 2011, 23(4): 688-694.)
9. [9]
  [9] JUN J H, LEE T J, LIM T H, NAM S W, HONG S A, YOON K J. Nickel-calcium phosphate/hydroxyapatite catalysts for partial oxidation of methane to syngas: Characterization and activation[J]. J Catal, 2004, 221(1): 178-190.
10. [10]
  [10] BOUKHA Z, KACIMI M, PEREIRA M F R, FARIA J L, FIGUEIREDO J L, ZIYAD M. Methane dry reforming on Ni loaded hydroxyapatite and fluoroapatite[J]. Appl Catal A: Gen, 2007, 317(2): 299-309.
11. [11]
  [11] KUMAR R, PRAKASH K H, CHEANG P, KHOR K A. Temperature driven morphological changes of chemically precipitated hydroxyapatite nanoparticles[J]. Langmuir, 2004, 20(13): 5196-5200.
12. [12]
  [12] ZHANG Y, LU J. A simple method to tailor spherical nanocrystal hydroxyapatite at low temperature[J]. J Nanopart Res, 2007, 9(4): 589-594.
13. [13]
  [13] HUANG T, HUANG W, HUANG J, JI P. Methane reforming reaction with carbon dioxide over SBA-15 supported Ni-Mo bimetallic catalysts[J]. Fuel Process Technol, 2011, 92(10): 1868-1875.
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沈阳化工大学材料科学与工程学院沈阳 110142