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Citation: WANG Qing, REN Li-guo, WANG Rui, BAI Jing-ru, WANG Hao-tian, YAN Yu-he. Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(3): 303-308. shu

Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN

  • 1.

    Engineering Research Centre of Oil Shale Comprehensive Utilization of Ministry of Education, Northeast Dianli University, Jilin 132012, China

  • Corresponding author: WANG Qing, 
  • Received Date: 17 September 2013
    Available Online: 1 December 2013

    Fund Project: 国家自然科学基金(51276034)。 (51276034)

  • The carbon skeleton structure of oil shales from Gansu Yaojie mine was characterized by the 13C solid-state NMR; the chemical structure parameters of cluster in the oil shales, such as average number of carbons, aromatic carbons, aliphatic carbons and aromatic rings, were determined. TG-FTIR tests were used to obtain the yields of pyrolysis products. Considering the cluster chemical structure parameters determined by 13C solid-state NMR, the release of pyrolysis products was simulated by FLASHCHAIN. The simulation results are in good agreement with the TG-FTIR tests, proving the rationality of the model proposed.
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