Citation:
WANG Yuan-yang, YAN Rui-feng. Effect of imidazolium-based ionic liquids as electrolytes on the performance of fuel cell[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(12): 1520-1524.
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Five imidazolium-based ionic liquids were used as the electrolytes and their effects on the performance of fuel cell were investigated in a free electrolyte fuel cell. The results indicated that with H2 as fuel, the cell potential and the power density at the same current density decrease following the sequence of [Bmim]BF4 > [Bmim]PF6 > NaOH >> [Bmim]Cl > [Bmim]Br > [Bmim]HSO4; on the contrary, when methane is used as fuel, the cell potential and the power density decrease following the sequence of [Bmim]Br > [Bmim]HSO4 > [Bmim]Cl > NaOH > [Bmim]BF4 > [Bmim]PF6. When [Bmim]BF4 is used as the electrolyte of H2 fuel cell, both of the cell potential and the power density decrease with the increase of temperature and water content in the ionic liquid.
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