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Citation: LIANG Hao, SONG Xi-jun, YIN Ze-qun, ZHANG Xi-wen, FANG Xiang-chen. Performance of Fe2O3/LaFeO3 as oxygen carrier in chemical-looping hydrogen generation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(12): 1512-1519. shu

Performance of Fe2O3/LaFeO3 as oxygen carrier in chemical-looping hydrogen generation

  • 1.

    Fushun Institute of Petrochemicals and Petroleum, Fushun 113001, China

  • Corresponding author: LIANG Hao, 
  • Received Date: 7 March 2013
    Available Online: 4 May 2013

  • Fe2O3/LaFeO3 was prepared by citric acid complexation method and used as oxygen carrier in chemical-looping hydrogen generation; the effect of Fe2O3/CH4 ratio, stream amount and metal loading on the performance of Fe2O3/LaFeO3 as oxygen carrier at 900 ℃ and atmospheric pressure were investigated. The results showed that the oxygen carrier performs best with CH4 conversion of 60% and single-loop H2 output of 45 mL, when the ratio of Fe2O3/CH4, stream input and Fe loading are 2, 0.1 mL, 15%, respectively. The XRD and H2-TPR results suggest that the active site is the adsorbed oxygen rather than metal oxide; the easier for the reduction of the adsorbed oxygen, the higher are the conversion of CH4 and the output of H2. Moreover, the oxygen carrier is still in perovskite structure and CH4 conversion and H2 output remain stable even after 60 cycles.
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