Citation:
LI Run-dong, LI Bing-shuo, YANG Tian-hua, XIE Ying-hui. Liquefaction of rice stalk in sub-and supercritical ethanol[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(12): 1459-1465.
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Rice stalk (RS) was liquefied in ethanol under sub-and supercritical conditions in a batch autoclave; the influences of reaction temperature, RS/ethanol ratio and residence time on the liquefaction behavior were investigated. Under the optimized conditions, i.e. 325 ℃, a RS/ethanol ratio of 1/10 (g/mL), and a residence time of 60 min, the RS conversion and oil yield reach 78.32% and 55.03%, respectively. The GC/MS analysis results illustrate that the dominant components of the bio-oil are phenols and esters, which account for about 50% of the bio-oil product. The bio-oil product obtained exhibits a high heat value (HHV) of 28.95 MJ/kg, a kinematic viscosity of 5.63 mm2/s, and a water content of 2.2%.
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Keywords:
- rice stalk,
- ethanol,
- liquefaction,
- bio-oil,
- supercritical fluid,
- GC-MS
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[1]
[1] 赵炜. 农作物秸秆在亚/超临界醇中的液化[D]. 徐州: 中国矿业大学, 2009. (ZHAO Wei. Liquefaction of crop stalks in sub and supercritical alcohols[D]. Xuzhou: China University of Mining and Technology, 2009.)
-
[2]
[2] YANG Y F, FENG C P, INAMORIB Y, MAEKAWAC T. Analysis of energy conversion characteristics in liquefaction of algae[J]. Resour Conserv Recycl, 2004, 43(1), 21-33.
-
[3]
[3] QIAN Y J, ZUO C J, TAN J, HE J H. Structural analysis of bio-oils from sub-and supercritical water liquefaction of woody biomass[J]. Energy, 2007, 32(3): 196-202.
-
[4]
[4] JADE C, PATTARAPAN P. Bio-oil from hydro-liquefaction of bagasse in supercritical ethanol[J]. Energy Fuels, 2010, 24(3): 2071-2077.
-
[5]
[5] JAVAID A, NOR AISHAH SAIDINA A. A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass[J]. Renew Sust Energy Rev, 2011, 15(3): 1615-1624.
-
[6]
[6] 刘华敏, 解新安, 丁年平, 刘焕彬, 黄璐怡. 亚/超临界乙醇液化玉米秸秆反应路径与机理[J]. 农业工程学报, 2010, 26(6): 277-282. (LIU Hua-min, XIE Xin-an, DING Nian-ping, LIU Huan-bin, HUANG Lu-yi. Liquefaction reaction pathway and mechanism of cornstalk in sub-and super-critical ethanol[J]. Transactions of the CSAE, 2010, 26(6): 277-282.)
-
[7]
[7] 郑朝阳, 解新安, 陶红秀, 郑璐丝, 李雁. 亚/超临界乙醇液化秸秆纤维素解聚反应研究与机理初探[J]. 燃料化学学报, 2012, 40(5): 526-532. (ZHENG Chao-yang, XIE Xin-an, TAO Hong-xiu, ZHENG Lu-si, LI Yan. Depolymerization of stalk cellulose during its liquefaction in sub-and supercritical ethanol[J]. Journal of Fuel Chemistry and Technology, 2012, 40(5): 526-532.)
-
[8]
[8] ZHOU D, ZHANG S C, FU H B, CHEN J M. Liquefaction of macroalgae enteromorpha prolifera in sub-/supercritical alcohols: Direct production of ester compounds[J]. Energy Fuels, 2012, 26(4): 2342-2351.
-
[9]
[9] 颜涌捷, 任铮伟. 纤维素连续催化水解研究[J]. 太阳能学报, 1999, 20(1): 55-58. (YAN Yong-jie, REN Zheng-wei. Continuous catalytic hydrolysis of cellulose[J]. Acta Energiae Solaris Sinica, 1999, 20(1): 55-58.)
-
[10]
[10] ZHONG C L, WEI X M. A comparative experimental study on the liquefaction of wood[J]. Energy, 2004, 29(11): 1731-1741.
-
[11]
[11] TAO H X, XIE X A, TANG C Z, TIAN W G. Mechanism of ketones formation from cellulose liquefaction in sub-and supercritical ethanol[J]. Journal of Fuel Chemistry and Technology, 2013, 41(1): 60-66.
-
[12]
[12] LI H, YUAN X Z, ZENG G M, TONG J Y, XIE W. Effect of mixed solvent on the sub-and supercritical liquefaction of agricultural waste[J]. Transactions of the CSAE, 2008, 24(5): 200-203.
-
[13]
[13] 秦岭, 吴玉龙, 邹树平, 陈镇, 杨明德, 陈恒志. 杜氏盐藻在亚/超临界水中液化制生物油[J]. 太阳能学报, 2010, 31(9): 1079-1084. (QIN Ling, WU Yu-long, ZOU Shu-ping, CHEN Zhen, YANG Ming-de, CHEN Heng-zhi. Experimental research on direct liquefaction of microalgae in subcritical/supercritical water[J]. Acta Energiae Solaris Sinica, 2010, 31(9): 1079-1084.)
-
[14]
[14] ANASTASAKIS K, ROSS A B. Hydrothermal liquefaction of the brown macro-alga laminaria saccharina: Effect of reaction conditions on product distribution and composition[J]. Bioresour Technol, 2011, 102(7): 4876-4883.
-
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