Citation: YANG Gai-xiu, LI Ying, YUAN Zhen-hong, KONG Xiao-ying, LI Ting, CHEN Guan-yi, LU Tian-hong, SUN Yong-ming. Electrocatalytic performance of the carbon supported Pd-P catalyst for formic acid oxidation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1367-1370. shu

Electrocatalytic performance of the carbon supported Pd-P catalyst for formic acid oxidation

1.
1. Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: SUN Yong-ming,
Received Date: 28 February 2013
Available Online: 29 May 2013
Fund Project: 中国科学院可再生能源重点实验室(Y207K5)。 (Y207K5)

The Pd-P/C catalyst with the high content of P⁰ was successfully prepared with the organic impregnation-reduction method. Pd-P/C catalysts with different Pd/P atomic ratios were characterized by X-ray diffraction (XRD), Energy Dispersive X-ray Spectrometer (EDX). The effect of Pd-P/C catalysts with different Pd/P atomic ratios on the oxidation of formic acid was also demonstrated by several electrochemical measures. It was found that the potential of the anodic peak of formic acid at catalyst electrodes increased in the order of Pd₁P₆/C < Pd₁P₈/C < Pd/C, and the electrochemical stability of three electrodes was in the order of Pd₁P₆/C > Pd₁P₈/C > Pd/C. The Pd₁P₆ catalyst showed the best performance for the oxidation of formic acid. The Pd-P/C catalysts with the suitable atomic ratio of Pd and P had higher activity and stability for the oxidation of formic acid.
- direct formic acid fuel cells,
- Pd-P/C catalysts,
- formic acid oxidation
1. [1]
  [1] BAIK S M, HAN J, KIM J, KWON Y. Effect of deactivation and reactivation of palladium anode catalyst on performance of direct formic acid fuel cell (DFAFC)[J]. Int J Hydrogen Energy, 2011, 36(22): 14719-14724.
2. [2]
  [2] BAIK S M, KIM J, HAN J, KWON Y. Performance improvement in direct formic acid fuel cells (DFAFCs) using metal catalyst prepared by dual mode spraying[J]. Int J Hydrogen Energy, 2011, 36(19): 12583-12590.
3. [3]
  [3] QU W L, WANG Z B, JIANG Z Z, GU D M, YIN G P. Investigation on performance of Pd/Al₂O₃-C catalyst synthesized by microwave assisted polyol process for electrooxidation of formic acid[J]. Rsc Advances, 2012, 2(1): 344-350.
4. [4]
  [4] RHEE Y W, HA S Y, MASEL R I. Crossover of formic acid through Nafion membranes[J]. J Power Sources, 2003, 117(1): 35-38.
5. [5]
  [5] CAPON A, PARSONS R. The oxidation of formic acid on noble metal electrodes: II. A comparison of the behaviour of pure electrodes[J]. J Electroanal Chem Int Eletronanal Chem, 1973, 44(2): 239-254.
6. [6]
  [6] KWON Y, BAIK S M, HAN J, KIM J. Performance enhancement by adaptation of long term chronoamperometry in direct formic acid fuel cell using palladium anode catalyst[J]. B Korean Chem Soc, 2012, 33(8): 2539-2545.
7. [7]
  [7] WANG R, LIAO S, JI S. High performance Pd-based catalysts for oxidation of formic acid[J]. J Power Sources, 2008, 180(1): 205-208.
8. [8]
  [8] LI R, WEI Z, HUANG T, YU A. Ultrasonic-assisted synthesis of Pd-Ni alloy catalysts supported on multi-walled carbon nanotubes for formic acid electrooxidation[J]. Electrochimica Acta, 2011, 56(19): 6860-6865.
9. [9]
  [9] CHIOU Y J, CHEN K Y, LIN H M, LIOU W J, LIOU H W, WU S H, MIKOLAJCZUK A, MAZURKIEWICZ M, MALOLEPSZY A, STOBINSKI L, BORODZINSKI A, KEDZIERZAWSKI P, KURZYDLOWSKI K, CHIEN S H, CHEN W C. Electrocatalytic properties of hybrid palladium-gold/multi-walled carbon nanotube materials in fuel cell applications[J]. Phys Status Solidi A, 2011, 208(8): 1778-1782.
10. [10]
  [10] DAIMON H, KUROBE Y. Size reduction of PtRu catalyst particle deposited on carbon support by addition of non-metallic elements[J]. Catal Today, 2006, 111(3): 182-187.
11. [11]
  [11] OKAMOTO Y, NITTA Y, IMANAKA T, TERANISHI S. Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions: III. Electronic and catalytic properties of nickel catalysts[J]. J Catal, 1980, 64(2): 397-404.
12. [12]
  [12] XUE X, GE J, LIU C, XING W, LU T. Novel chemical synthesis of Pt-Ru-P electrocatalysts by hypophosphite deposition for enhanced methanol oxidation and CO tolerance in direct methanol fuel cell[J]. Electrochem Commun, 2006, 8(8): 1280-1286.
13. [13]
  [13] XUE X, GE J, TIAN T, LIU C, XING W, LU T. Enhancement of the electrooxidation of ethanol on Pt-Sn-P/C catalysts prepared by chemical deposition process[J]. J Power Sources, 2007, 172(2): 560-569.
14. [14]
  [14] ZHANG L, TANG Y, BAO J, LU T, LI C. A carbon-supported Pd-P catalyst as the anodic catalyst in a direct formic acid fuel cell[J]. J Power Sources, 2006, 162(1): 177-179.
15. [15]
  [15] ZHANG L, LU T, BAO J, TANG Y, LI C. Preparation method of an ultrafine carbon supported Pd catalyst as an anodic catalyst in a direct formic acid fuel cell[J]. Electrochem Commun, 2006, 8(10): 1625-1627.
16. [16]
  [16] BONINO J P, BRUET-HOTELLAZ S, BORIES C, POUDEROUX P, ROUSSET A. Thermal stability of electrodeposited Ni-P alloys[J]. J Appl Electrochem, 1997, 27(10): 1193-1197.
17. [17]
  [17] SUN H, XU J, FU G, MAO X, ZHANG L, CHEN Y, ZHOU Y, LU T, TANG Y. Preparation of highly dispersed palladium-phosphorus nanoparticles and its electrocatalytic performance for formic acid electrooxidation[J]. Electrochimica Acta, 2012, 59: 279-283.
18. [18]
  [18] CHENG L, ZHANG Z, NIU W, XU G, ZHU L. Carbon-supported Pd nanocatalyst modified by non-metal phosphorus for the oxygen reduction reaction[J]. J Power Sources, 2008, 182(1): 91-94.
19. [19]
  [19] PAN Y, ZHANG R, BLAIR S L. Anode poisoning study in direct formic acid fuel cells[J]. Electrochem Solid State Lett, 2009, 12(3): B23-B26.
20. [20]
  [20] YANG G, CHEN Y, ZHOU Y, TANG Y, LU T. Preparation of carbon supported Pd-P catalyst with high content of element phosphorus and its electrocatalytic performance for formic acid oxidation[J]. Electrochem Commun, 2010, 12(3): 492-495.
21. [21]
  [21] YU X, PICKUP P G. Novel Pd-Pb/C bimetallic catalysts for direct formic acid fuel cells[J]. J Power Sources, 2009, 192(2): 279-284.
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