Citation: WANG Rui-yu, LI Zhong. Preparation and catalytic activity of CuNaY zeolite in oxidative carbonylation of methanol[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1361-1366. shu

Preparation and catalytic activity of CuNaY zeolite in oxidative carbonylation of methanol

WANG Rui-yu ¹ ,
LI Zhong ^2,,

1.
1. Key Laboratory of Coal-based CO₂ Capture and Geological Storage of Jiangsu province, China University of Mining and Technology, Xuzhou 221006, China;

Corresponding author: LI Zhong,
Received Date: 29 March 2013
Available Online: 24 June 2013
Fund Project: 国家自然科学基金(20976113) (20976113)中央高校基本科研业务费专项资金(2010QNA11) (2010QNA11)中国矿业大学连云港徐圩新区高新技术研究院创新创业基金(2011KDGXYJJ06)。 (2011KDGXYJJ06)

Ammonia was added to the ion-exchange solution to adjust the pH in the preparation of CuNaY catalyst by ion-exchange of NaY zeolite with Cu²⁺ aqueous solution, and then the ion-exchanged CuNaY was activated by high temperature calcinations. The effect of anion type in the Cu²⁺ aqueous solution on the ion-exchange process and catalytic performance of the catalyst were studied, it is shown that the catalytic activity of CuNaY ion-exchanged of NaY with aqueous solution of copper salts was low, when the pH of ion-exchange solution was adjusted to 11 by adding ammonia, the catalytic activity and selectivity of DMC increased greatly. Based on the characterization of the microstructure of the catalyst by elementary analysis, XRD, XPS and H₂-TPR techniqs, it is shown that by adding ammonia into the ion-exchange solution, the ion-exchanged reaction is promoted, resulting in the increase of the ion-exchanged Cu²⁺, 75% of the Cu²⁺ in the catalyst located in the supercages of the Y zeolite.
- ion-exchange,
- CuNaY catalyst,
- oxidative carbonylation,
- methanol,
- copper ammonia,
- dimethyl carbonate
1. [1]
  [1] DELLEDONNE D, RIVETTI F, ROMANO U. Developments in the production and application of dimethyl carbonate[J]. Appl Catal A: Gen, 2001, 221(1/2): 241-246.
2. [2]
  [2] TOMISHIGE K, SAKAIHORI T, SAKAI S, FUJIMOTO K. Dimethyl carbonate synthesis by oxidative carbonylation on activated carbon supported CuCl₂ catalysts: Catalytic properties and structural change[J]. Appl Catal A: Gen, 1999, 181(1): 95-102.
3. [3]
  [3] JIANG R X, WANG S F, ZHAO X Q, WANG Y J, ZHANG C F. The effects of promoters on catalytic properties and deactivation-regeneration of the catalyst in the synthesis of dimethyl carbonate[J]. Appl Catal A: Gen, 2003, 238(1): 131-139.
4. [4]
  [4] LI Z, XIE K C, SLADE R C T. Studies of interaction between CuCl and HY zeolite for preparing heterogeneous Cu^Ⅰ catalyst[J]. Appl Catal A: Gen, 2001, 209(1/2): 107-115.
5. [5]
  [5] DRAKE I J, FUJDALA K L, BELL A T, TILLEY T D. Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO₂ catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches[J]. J Catal, 2005, 230(1): 14-27.
6. [6]
  [6] DRAKE I J, ZHANG Y H, BRIGGS D, LIM B, CHAU T, BELL A T. The local environment of Cu⁺ in Cu-Y zeolite and its relationship to the synthesis of dimethyl carbonate[J]. J Phys Chem B, 2006, 110(24): 11654-11664.
7. [7]
  [7] RICHTER M, FAIT M J G, ECKELT R, SCHREIER E, SCHNEIDER M, POHL M-M, FRIKE R. Oxidative gas phase carbonylation of methanol to dimethyl carbonate over chloride-free Cu-impregnated zeolite Y catalysts at elevated pressure[J]. Appl Catal B: Environ, 2007, 73(3/4): 269-281.
8. [8]
  [8] RICHTER M, FAIT M J G, ECKELT R, SCHNEIDER M, RADNIK J, HEIDEMANN D, FRICKE R. Gas-phase carbonylation of methanol to dimethyl carbonate on chloride-free Cu-precipitated zeolite Y at normal pressure[J]. J Catal, 2007, 245(1): 11-24.
9. [9]
  [9] ZHANG Y H, DRAKE I J, BRIGGS D N, BELL A T. Synthesis of dimethyl carbonate and dimethoxy methane over Cu-ZSM-5[J]. J Catal, 2006, 244(2): 219-229.
10. [10]
  [10] ZHANG Y H, BRIGGS D N, SMIT E D, BELL A T. Effects of zeolite structure and composition on the synthesis of dimethyl carbonate by oxidative carbonylation of methanol on Cu-exchanged Y, ZSM-5, and Mordenite[J]. J Catal, 2007, 251(2): 443-452.
11. [11]
  [11] ZHANG Y H, BELL A T. The mechanism of dimethyl carbonate synthesis on Cu-exchanged zeolite Y[J]. J Catal, 2008, 255(2): 153-161.
12. [12]
  [12] KING S T. Oxidative carbonylation of methanol to dimethyl carbonate by solid-state ion-exchanged CuY catalysts[J]. Catal Today, 1997, 33(1/3): 173-182.
13. [13]
  [13] CHEN H J, MATSUOKA M, ZHANG J L, ANPO M. The reduction behavior of the Cu ion species exchanged into Y zeolite during the thermovacuum treatment[J]. J Catal, 2004, 228(1): 75-79.
14. [14]
  [14] IWAMOTO M, YAHIRO H, TORIKAI Y, YOSHIOKA T, MIZUNO N. Novel preparation method of highly copper ion-exchanged ZSM-5 zeolite and their catalytic activities for NO decomposition[J]. Chem Lett, 1990, 19(11): 1967-1970.
15. [15]
  [15] IWAMOTO M, YOKOO S, SAKAI K, KAGAWA S. Catalytic decomposition of nitric oxide over copper(Ⅱ)-exchanged, Y-type zeolites[J]. J Chem Soc, Faraday Trans 1, 1981, 77: 1629-1638.
16. [16]
  [16] 李忠, 付廷俊, 王瑞玉, 牛燕燕, 郑华艳. 高活性甲醇氧化羰基化CuY催化剂的结构及催化活性中心[J]. 高等学校化学学报, 2011, 32(6): 1366-1372. (LI Zhong, FU Ting-Jun, WANG Rui-Yu, NIU Yan-Yan, ZHENG Hua-Yan. Structure and catalytic active center of high catalytic activity CuY catalysts in oxidative carbonylation of methanol[J]. Chemical Journal of Chinese Universities, 2011, 32(6): 1366-1372.)
17. [17]
  [17] NARAYANA M, CONTARINI S, KEVAN L. X-ray photoelectron and electron spin resonance spectroscopic studies of CuNaY zeolites[J]. J Catal, 1985, 94(2): 370-375.
18. [18]
  [18] GOSLAR J, WIECKOWSKI A B. Migration and structure of aqueous Cu²⁺complexes in faujasite[J]. J Solid State Chem, 1985, 56(1): 101-115.
19. [19]
  [19] MAXWELL I E, DE BOER J J. Crystal structures of hydrated and dehydrated divalent-copper- exchanged Faujasite[J]. J Phys Chem, 1975, 79(17): 1874-1879.
20. [20]
  [20] LEE C Y, CHOI K Y, HA B H. Catalytic decomposition of nitric-oxide on copper zeolites[J]. Appl Catal B: Environ, 1994, 5(1/2): 7-21.
21. [21]
  [21] 万颖, 马建新, 王正, 周伟, 张益群. Cu-Al-MCM-41的Si/Al比对贫燃条件下NO选择性催化还原的影响[J]. 催化学报, 2004, 25(1): 27-32. (WAN Yin, MA Jian-Xin, WANG Zheng, ZHOU Wei, ZHANG Yi-qun. Effect of Si/Al ratio in Cu-Al-MCM-41 on selective catalytic reduction of NO under lean burn conditions[J]. Chinese Journal of Catalysis, 2004, 25(1): 27-32.)
22. [22]
  [22] BERTHOMIEU D, DELAHAY G. Recent advances in Cu^I/IIY: Experiments and modeling[J]. Catal Rev, 2006, 48(3): 269-313.
23. [23]
  [23] 赵栋良, 赵勇. 碱性条件对NaY分子筛脱钠及其结构的影响[J]. 石油技术与应用, 2005, 23(5): 346-349. (ZHAO Dong-Liang, ZHAO Yong. Influence of alkali condition on removing Na of NaY molecular sieve and its structure[J]. Petrochemical Technology & Application, 2005, 23(5): 346-349.)
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