Citation: ZHOU Zhen-lei, LI Zhuo, WANG Bo, PENG Wei-cai, LI Jian-qing, WU Jin-hu. Hydrothermal treatment of ZSM-5 and its application in syngas to gasoline via DME[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1349-1355. shu

Hydrothermal treatment of ZSM-5 and its application in syngas to gasoline via DME

ZHOU Zhen-lei ^1,2 ,
LI Zhuo ¹ ,
WANG Bo ^1,2 ,
PENG Wei-cai ¹ ,
LI Jian-qing ^1,, ,
WU Jin-hu ^1,,

1.
1. Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China;

Corresponding author: LI Jian-qing, WU Jin-hu,
Received Date: 27 March 2013
Available Online: 7 May 2013
Fund Project: 中国科学院对外合作重点项目(GJHZ1025) (GJHZ1025)国家重点基础研究发展规划(973计划, 2011CB201502) (973计划, 2011CB201502)"十二五"农村领域国家科技计划(2011BAD22B06-01) (2011BAD22B06-01)中国科学院重大装备项目(Y2010022)。 (Y2010022)

The effects of in-situ hydrothermal treatment on the ZSM-5 zeolite were studied, and its performance for syngas to gasoline via DME reaction process was dicussed using two-stage equal-pressure reactor system. The texture, surface acidity and catalytic performance of the treated ZSM-5 zeolite at different temperatures were investigated. Physicochemical properties of the zeolite were characterized by XRD, XRF, BET, NH₃-TPD and TPO. The results indicated that most of Al was removed from the nonframework of zeolite through appropriate hydrothermal treatment at 400℃. A decrease in the amount of acidic sites and an increase of specific surface area were observed, and accordingly, the catalytic activity of the ZSM-5 zeolite and product selectivity were improved significantly.
- ZSM-5,
- hydrothermal treatment,
- syngas,
- DME,
- gasoline
1. [1]
  [1] KUNG H H. Methanol sysnthesis[J]. Cat Rev-Sci Eng, 1980, 22(2): 235-259.
2. [2]
  [2] KANG S H, BAE J W, JUN K W, POTDAR H S. Dimethyl ether synthesis from syngas over the composite catalysts of Cu-ZnO-Al₂O₃/Zr-modified zeolites[J]. Catal Commun, 2008, 9(10): 2035-2039.
3. [3]
  [3] ANDRÉS G T, AGUSTÍN M. Direct synthesis of DME from syngas on hybrid CuZnAl/ZSM-5 catalysts: New insights into the role of zeolite acidity[J]. Appl Catal A: Gen, 2012, 411-412: 170-179.
4. [4]
  [4] 张清德, 谭猗生, 杨彩虹, 韩怡卓. 反应压力对HZSM-5分子筛催化剂上合成气经二甲醚制取芳烃反应的影响[J]. 现代化工, 2009, 29(S1): 112-114. (ZHANG Qing-de, TAN Yi-sheng, YANG Cai-hong, HAN Yi-zhuo. Effect of reaction pressure for syngas to aromatics via dimethyl ether over HZSM-5 catalyst[J]. Modern Chemical Industry, 2009, 29(S1): 112-114.)
5. [5]
  [5] KOLESNICHENKO N V, KITAEV L E, BUKINA Z M, MARKOVA N A, YUSHCHENKO V V, YASHINA O V, LIN G I, ROZOVSKII A Y. Synthesis of gasoline from syngas via dimethyl ether[J]. Kinet Catal, 2007, 48(6): 789-793.
6. [6]
  [6] FUJIMOTO K, ASAMI K, SAIMA H, SHIKADA T, TOMINAGA H. Two-stage reaction system for synthesis gas conversion to gasoline[J]. Ind Eng Chem Pro Res Dev, 1986, 25(2): 262-267.
7. [7]
  [7] 岳瑛, 丁莹如. 用改良MTG方法自合成气两步合成汽油催化剂的研究[J]. 燃料化学学报, 1990, 18(3): 247-252. (YUE Ying, DING Ying-ru. Study on catalysts for two stage gasoline synthesis from syngas[J]. Journal of Fuel Chemistry and Technology, 1990, 18(3): 247-252.)
8. [8]
  [8] TOSHEVA L, VALTCHEV V P. Nanozeolites: Synthesis, crystallization mechanism, and applications[J]. Chem Mat, 2005, 17(10): 2494-2513.
9. [9]
  [9] SONG W, JUSTICE R E, JONES C A, GRASSIAN V H, LARSEN S C. Synthesis, characterization, and adsorption properties of nanocrystalline ZSM-5[J]. Langmuir, 2004, 20(19): 8301-8306.
10. [10]
  [10] LARSEN S C. Nanocrystalline zeolites and zeolite structures: Synthesis, characterization, and applications[J]. J Phys Chem C, 2007, 111(50): 18464-18474.
11. [11]
  [11] 盛清涛, 凌开成, 李振荣, 赵亮富. 水蒸汽及盐酸处理对ZSM-5分子筛性能的影响[J]. 太原理工大学学报, 2012, 43(4): 425-430. (SHENG Qing-tao, LING Kai-cheng, LI Zhen-rong, ZHAO Liang-fu. Effect of steam treatment and HCl solution treatment on catalytic performance of ZSM-5 zeolite for the conversion of ethanol to ethylene[J]. Journal of Tai Yuan University of Technology, 2012, 43(4): 425-430.)
12. [12]
  [12] 张培青, 王祥生, 郭洪臣, 徐舟波, 赵乐平, 胡永康. 水热处理对纳米HZSM-5沸石酸性质及其降低汽油烯烃性能的影响[J]. 催化学报, 2003, 24(12): 900-904. (ZHANG Pei-qing, WANG Xiang-sheng, GUO Hong-chen, XU Zhou-bo, ZHAO Le-ping, HU Yong-kang. Influence of hydrothermal treatment on acid property and catalytic performance of nano-HZSM-5 zeolite for reducing olefins in gasoline[J]. Chinese Journal of Catalysis, 2003, 24(12): 900-904.)
13. [13]
  [13] 汪树军, 梁娟, 郭文珪, 赵素琴, 汪荣慧. ZSM-5沸石骨架铝迁移规律的研究: I.水热处理条件及沸石硅铝比的影响[J]. 催化学报, 1992, 13(1): 38-43. (WANG Shu-jun, LIANG Juan, GUO Wen-gui, ZHAO Su-qin, WANG Rong-hui. Studies on the migration of framework Al of ZSM-5 zeolite: I. Effect of hydrothermal treatment and silica alumina ratio[J]. Chinese Journal of Catalysis, 1992, 13(1): 38-43.)
14. [14]
  [14] DING C H, WANG X S, GUO X W, ZHANG S G. Characterization and catalytic alkylation of hydrothermally dealuminated nanoscale ZSM-5 zeolite catalyst[J]. Catal Commun, 2008, 9(4): 487-493.
15. [15]
  [15] DATKA J, MARSCHMEYER S, NEUBAUER T, MEUSINGER J, PAPP H, SCHUTZE F W, SZPYT I. Physicochemical and catalytic properties of HZSM-5 zeolites dealuminated by the treatment with steam[J]. J Phys Chem, 1996, 100(34): 14451-14456.
16. [16]
  [16] 李剑, 谭猗生, 杨彩虹, 韩怡卓. 水对两段法合成汽油中HZSM-5分子筛稳定性及油相产物的影响[J]. 燃料化学学报, 2010, 38(1): 96-101. (LI Jian, TAN Yi-sheng, YANG Cai-hong, HAN Yi-zhuo. Effect of water on stability of HZSM-5 and product distribution in two-stage gasoline synthes is from syngas [J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 96-101.)
17. [17]
  [17] ONG L H, DOMOK M, OLINDO R, VAN VEEN A C, LERCHER J A. Dealumination of HZSM-5 via steam-treatment[J]. Micropor Mesopor mater, 2012, 164: 9-20.
18. [18]
  [18] EROFEEV V I, ADYAEVA L V, RYABOVA N V. Effect of high-temperature steam treatment of high-silica zeolites of the ZSM-5 type on their acidity and selectivity of formation of lower olefins from straight-run naphthas[J]. Russ J Appl Chem, 2003, 76(1): 95-98.
19. [19]
  [19] 杨成, 李建青, 李琢, 李超, 孙振鹏, 吴晋沪, 王利生. 一种用于合成气制二甲醚的催化剂及其制法和应用: 中国, 101940934A[P]. 2011-01-02. (YANG Cheng, LI Jian-qing, LI Zhuo, LI Chao, SUN Zhen-peng, WU Jin-hu, WANG Li-sheng. A kind of catalyst used for the synthesis gas to dimethyl ether and its preparation and application: CN, 101940934A[P]. 2011-01-02.)
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Shanyuan Bi , Jin Zhang , Dengchao Peng , Danhong Cheng , Jianping Zhang , Lupeng Han , Dengsong Zhang . Improved N₂ selectivity for low-temperature NO_x reduction over etched ZSM-5 supported MnCe oxide catalysts. Chinese Chemical Letters, 2025, 36(5): 110295-. doi: 10.1016/j.cclet.2024.110295
5. [5]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
6. [6]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
7. [7]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
8. [8]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
9. [9]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
10. [10]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
11. [11]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
12. [12]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
15. [15]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
16. [16]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
17. [17]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
18. [18]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
19. [19]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
20. [20]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(514)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142