Citation: CHEN Zhen-ya, NIU Bao-lun, TANG Ling-zhi, ZHANG Liang, HUANG Hai-dong, REN Shao-ran. Experimental study of low temperature oxidation mechanism and activity of oil components[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1336-1342. shu

Experimental study of low temperature oxidation mechanism and activity of oil components

1.
1. College of Petroleum Engineering, China University of Petroleum(East China), Qingdao 266555, China;

Corresponding author: REN Shao-ran,
Received Date: 15 March 2013
Available Online: 15 May 2013
Fund Project: 中国石油化工集团公司先导性科技项目(P09083) (P09083)长江学者和创新团队发展计划资助(IRT1294)。 (IRT1294)

Laboratory experiments and reaction kinetics analysis were conducted to reveal the mechanisms of low temperature oxidation (LTO) reaction of crude oil and oil components in the temperature range from 70 to 120℃. SARA(saturates, aromatics, resins, and asphaltenes)analysis was conducted to study the variations of different oil components before and after LTO reaction. The experiments using pure oil components (i.e. n-hexadecane, wax, anthracene and asphaltenes) were preformed to investigate the oxidation activity of different oil components. At low temperatures (70~90℃), light oil compounds (n-hexadecane and anthracene) can be more resistible to the oxidation than heavy asphaltenes and wax. The activation energies of the various components LTO reactions calculated based on the experimental results show that the heavy components, having a relative low activation energy, can be more easily subjected to low temperature oxidation than the light HC components. Heavy oil exhibits a higher oxidation activity than light oils in the LTO reaction, which also means that the heavy oil components is more easily oxidized at low temperatures. The experimental results can provide a basis for the air injection process design in oilfields.
- air injection,
- low-temperature oxidation,
- oxidation activity,
- SARA analysis,
- oil components
1. [1]
  [1] 陈立波, 郭绍辉, 李术元, 宋兰琪, 张占纲. 航空润滑油中抗氧剂的热氧化动力学研究[J]. 燃料化学学报, 2002, 30(6): 523-527.(CHEN Li-bo, GUO Shao-hui, LI Shu-yuan, SONG Lan-qi, ZHANG Zhan-gang. Study on thermal-oxidative kinetics of n-phenyl- SymbolaA@ -naphthylamine in an aviation lubrication oil[J]. Journal of Fuel Chemistry and Technology, 2002, 30(6): 523-527.)
2. [2]
  [2] REN S R, GREAVES M, RATHBONE R R. Oxidation kinetics of North Sea light crude oils at reservoir temperature[J]. Chem Eng Res Des, 1999, 77(A5): 385-394.
3. [3]
  [3] 关文龙, 席长丰, 陈亚平, 张霞, 木合塔尔, 梁金中, 黄继红, 吴键. 稠油油藏注蒸汽开发后期转火驱技术[J]. 石油勘探与开发, 2011, 38(4): 452-461.(GUAN Wen-long, XI Chang-feng, CHEN Ya-ping, ZHANG Xia, MUHE Ta-er, LIANG Jin-zhong, HUANG Ji-hong, WU Jian. Fire-flooding technologies in post-steam-injected heavy oil reservoirs[J]. Petroleum Exploration and Development, 2011, 38(4): 452-461.)
4. [4]
  [4] YU H, YANG B, XU G, WANG J, REN S R, LIN W, XIAO L, GAO H. Air foam injection for IOR: From laboratory to field implementation in Zhongyuan Oilfield China[C]. SPE/DOE Symposium on Improved Oil Recovery, Tulsa, Oklahoma, USA, 2008.
5. [5]
  [5] REN S R, GREAVES M, RATHBONE R R. Air injection TLO process: An IOR technique for light-oil reservoirs[J]. SPE J, 2002, 7(1): 90-91.
6. [6]
  [6] NIU B L, REN S R, LIU Y H, WANG D Z, TANG L L, CHEN B L. Low-temperature oxidation of oil components in an air injection process for improved oil recovery[J]. Energy Fuels, 2011, 25(10), 4299-4304.
7. [7]
  [7] TURTA A T, SINGHAL A K. Reservoir engineering aspects of light-oil recovery by air injection[J]. SPE Reserv Eval Eng, 2001, 4(4): 336-344.
8. [8]
  [8] 张旭, 刘建仪, 孙良田, 李士伦, 刘卫华. 注空气低温氧化提高轻质油气藏采收率研究[J]. 天然气工业, 2004, 24(4): 78-80.(ZHANG Xu, LIU Jian-yi, SUN Liang-tian, LI Shi-lun, LIU Wei-hua. Research on the mechanisms of enhancing recovery of light-oil reservoir by air-injected low-temperature oxidation technique[J]. Natural Gas Industry, 2004, 24(4): 78-80.)
9. [9]
  [9] REN S R. 注空气低温氧化工艺: 轻质油藏提高采收率技术[J]. 国外石油动态, 2002, 15: 9-22.
10. [10]
  (REN S R. Low temperature oxidation in an air injection process: Improved oil recovery in light oil reservoirs[J]. Foreign Oil & Gas Information, 2002, 15: 9-22.)
11. [11]
  [10] GRABOWSKI J W, VINSOME P K, LIN R C, BEHIE G A, RUBIN B. A fully implicit general purpose finite difference thermal model for in-situ combustion and steam[C]. SPE Annual Technical Conference and Exhibition, Las Vegas, Nevada, 1979.
12. [12]
  [11] DAYAL H S, BHUSHAN B V, MITRA S, SINHA S K, SUR S. In-situ combustion: Opportunities and anxieties[C]. Proceedings of the Society of Petroleum Engineers (SPE) Oil and Gas India Conference and Exhibition, Mumbai, India, 2010.
13. [13]
  [12] 王元基, 何江川, 廖广志, 王正茂. 国内火驱技术发展历程与应用前景[J]. 石油学报, 2012, 33(5): 909-914.(WANG Yuan-ji, HE Jiang-chuan, LIAO Guang-zhi, WANG Zheng-mao. Overview on the development history of combustion drive and its application prospect in China[J]. Acta Petrolei Sinica, 2012, 33(5): 909-914.)
14. [14]
  [13] 任韶然, 刘永军, 王杰祥, 张卫东, 王瑞和. 注空气辅助蒸汽吞吐稠油开采技术: 中国, 200710013035.9[P]. 2007-01-04.(REN Shao-ran, LIU Yong-jun, WANG Jie-xiang, ZHANG Wei-dong, WANG Rui-he. Air-assisted steam stimulation technology for heavy oil: CN, 200710013035.9[P]. 2007-01-04.)
15. [15]
  [14] 毛红, 周亚松, 孙玉华, 陈月珠. 润滑油基础油的化学组成对其氧化安定性的影响[J]. 石油学报, 1999, 15(3): 63-67.(MAO Hong, ZHOU Ya-song, SUN Yu-hua, CHEN Yue-zhu. Influence of chemical composition of lube base oils on their oxidation stability[J]. Acta Petrolei Sinica, 1999, 15(3): 63-67.)
16. [16]
  [15] 于洪敏, 任韶然, 左景栾, 王瑞和, 林伟民. 注空气泡沫低温氧化工艺提高采收率试验[J]. 中国石油大学学报: 自然科学版, 2009, 33(2): 94-99.(YU Hong-min, REN Shao-ran, ZUO Jing-luan, WANG Rui-he, LIN Wei-min. Experiment of improved oil recovery by air foam injection low temperature oxidation process[J]. Journal of China University of Petroleum(Edition of Natural Science), 2009, 33(2): 94-99.)
17. [17]
  [16] LIMKAR P S. Novel in-situ combustion technique using a semipermeable igniter assembly[C]. Proceedings of the Society of Petroleum Engineers (SPE)/European Association of Geoscientists and Engineers(EAGE) Reservoir Characterization and Simulation Conference, AbuDhabi, United Arab Emirates, 2009.
18. [18]
  [17] CHEN Z Y, WANG L, DUAN Q, ZHANG L, REN S R. High pressure air injection for improved oil recovery: Low-temperature oxidation models and thermal effect[J]. Energy Fuels, 2013, 27(2): 780-786.
19. [19]
  [18] GREAVES M, REN S R, RATHBONE R R, FISHLOCK T, IRELAND R. Improved residual light oil recovery by air injection (LTO process)[J]. Can Pet Technol, 2000, 39(1): 57-61.
20. [20]
  [19] 罗渝然. 化学键能数据手册[M]. 北京: 科学技术出版社, 2005.
21. [21]
  (LUO Yu-ran. Chemical bond energy data manual[M]. Beijing: Science and Technology Press, 2005.)
22. [22]
  [20] 于洪敏. 注空气泡沫提高采收率技术研究[D].青岛: 中国石油大学(华东), 2009.(YU Hong-min. Study on improved oil recovery by air foam injection technique[D]. Qingdao: China university of petroleum(east China), 2009.)
23. [23]
  [21] 侯胜明, 刘印华, 于洪敏, 牛保伦, 任韶然. 注空气过程轻质原油低温氧化动力学[J]. 中国石油大学学报(自然科学版), 2011, 1(35): 169-173.(HOU Sheng-min, LIU Yin-hua, YU Hong-min, Niu Bao-lun, REN Shao-ran. Kinetics of low temperature oxidation of light oil in air injection process[J]. Journal of China University of Petroleum(Edition of Natural Science), 2011, 1(35): 169-173.)
24. [24]
  [22] 黎柴佐, 冉景煜. 生物质焦油热裂解动力学参数实验研究[J]. 燃料化学学报, 2012, 40(9): 1060-1066.(LI Chai-zuo, RAN Jing-yu. Experimental study on kinetic parameters of thermal cracking of biomass tar[J]. Journal of Fuel Chemistry and Technology, 2012, 40(9): 1060-1066.)
25. [25]
  [23] 彭家喜, 王树东. 甲醛低温催化氧化动力学研究Ⅰ本征动力学[J]. 燃料化学学报, 2006, 34(2): 252-256.(PENG Jia-xi, WANG Shu-dong. Kinetic study on catalytic oxidation of formaldehyde at low temperature Ⅰ. Intrinsic kinetics[J]. Journal of Fuel Chemistry and Technology, 2006, 34(2): 252-256.)
26. [26]
  [24] 陈登宇, 朱锡锋. 生物质热反应机理与活化能确定方法I干燥段研究[J]. 燃料化学学报, 2011, 39(8): 580-584.(CHEN Deng-yu, ZHU Xi-feng. Thermal reaction mechanism of biomass and determination of activation energy I. Drying section[J]. Journal of Fuel Chemistry and Technology, 2011, 39(8): 580-584.)
27. [27]
  [25] 常兆光, 王清河, 杜彩凤. 应用统计方法[M]. 北京: 石油工业出版社, 2009.
1. [1]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
2. [2]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
3. [3]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
4. [4]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
5. [5]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
6. [6]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
7. [7]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
8. [8]
  Jia Huo , Jia Li , Yongjun Li , Yuzhi Wang . Ideological and Political Design of Physical Chemistry Teaching: Chemical Potential of Any Component in an Ideal-Dilute Solution. University Chemistry, 2024, 39(2): 14-20. doi: 10.3866/PKU.DXHX202307075
9. [9]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
10. [10]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
11. [11]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
12. [12]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
13. [13]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
14. [14]
  Yanting HUANG , Hua XIANG , Mei PAN . Construction and application of multi-component systems based on luminous copper nanoclusters. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2075-2090. doi: 10.11862/CJIC.20240196
15. [15]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
16. [16]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
17. [17]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
18. [18]
  Tingting Jiang , Jing Chang . Application of Ideological and Political Education in Chemical Analysis Experiment under the Background of Emerging Engineering Education: Taking the Redox Titration Experiment as an Example. University Chemistry, 2024, 39(2): 168-174. doi: 10.3866/PKU.DXHX202308007
19. [19]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
20. [20]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(305)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142