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Citation: ZHANG Ping, LI Lu, YU Feng-li, XIE Cong-xia, YU Shi-tao, LIU Shi-wei, LIU Fu-sheng. Preparation of SO42-/ZrO2 catalyst and its performance in the esterification of pyrolytic rubber seed oil[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1322-1327. shu

Preparation of SO42-/ZrO2 catalyst and its performance in the esterification of pyrolytic rubber seed oil

  • 1.

    1. College of Chemical Engineering Qingdao University of Science and Technolygy, Qingdao 266042, China;

  • Corresponding author: YU Shi-tao, 
  • Received Date: 8 May 2013
    Available Online: 21 July 2013

    Fund Project: "十二五"农村领域国家科技计划(2011BAD22B05) (2011BAD22B05)无机合成与制备化学国家重点实验室(吉林大学)开发课题(2011-18) (吉林大学)开发课题(2011-18)青岛市应用基础项目(10-3-4-1-jch) (10-3-4-1-jch)山东省高等学校科技计划项目(J11LB05)。 (J11LB05)

  • Esterification of pyrolytic rubber seed oil with SO42-/ZrO2 soild acid as catalyst was investigated; the effects of zirconium sources, calcination time and temperature on the catalytic performance were considered. The acidic properties of the SO42-/ZrO2 catalyst were characterized by temperature-programmed desorption of ammonia (NH3-TPD) and pyridine adsorption infrared spectroscopy (Py-IR). The results indicated that the SO42-/ZrO2 solid acid prepared by using ZrOCl2 as zirconium source and calcined at 550℃ for 4 h exhibits high catalytic activity and stability in the esterification of the pyrolytic rubber seed oil. The esterification product obtained as a bio-oil was superior to those prepared via conventional methods; its properties are similar to those of 0# diesel oil.
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