Citation: DOU Zhe, FENG Ming, XU Xiu-feng. Catalytic decomposition of N₂O over Au/Co₃O₄ and Au/ZnCo₂O₄ catalysts[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1234-1240. shu

Catalytic decomposition of N₂O over Au/Co₃O₄ and Au/ZnCo₂O₄ catalysts

1.
School of Chemistry and Chemical Engineering, Yantai University;Shandong Applied Research Center of Gold Nanotechnology, Yantai 264005, China

Corresponding author: XU Xiu-feng,
Received Date: 8 April 2013
Available Online: 12 June 2013

Au/Co₃O₄ catalysts with different gold loadings were prepared by the deposition-precipitation method using HAuCl₄ solution through adjustment of the pH value to 7, 9 or 11. Their catalytic properties for N₂O decomposition in the presence of oxygen were investigated. 0.29%Au/Co₃O₄ catalyst prepared at the pH value of 9 exhibited higher catalytic activity than 0.31%Au/ZnCo₂O₄ prepared under optimal conditions although ZnCo₂O₄ was more active than Co₃O₄. AES, BET, XRD, SEM, XPS and H₂-TPR characterization results indicated a synergistic effect existed between gold and cobalt species in Au/Co₃O₄, which is, however, absent in the Au/ZnCo₂O₄. Despite that N₂O was completely decomposed at 500 ℃ in oxygen atmosphere for both the samples, the N₂O conversion was decreased to 92% and 63% after the reaction was carried out for 10 h in the presence of both oxygen and steam over the 0.29%Au/Co₃O₄ and the 0.31%Au/ZnCo₂O₄, respectively.
- N₂O decomposition,
- Co₃O₄,
- ZnCo₂O₄,
- gold catalyst
1. [1]
  [1] WOOD B R, REIMER J A, BELL A T. Studies of N₂O adsorption and decomposition on Fe-ZSM-5[J]. J Catal, 2002, 209(1): 151-158.
2. [2]
  [2] WACLAW A, NOWINSKA K, SCHWIEGER W, ZIELINSKA A. N₂O decomposition over iron modified zeolites ZSM-5[J]. Catal Today, 2004, 90(1/2): 21-25.
3. [3]
  [3] PIRNGRUBER G D, LUECHINGER M, ROY P K, CECCHETTO A, SMIRNIOTIS P. N₂O decomposition over iron-containing zeolites prepared by different methods: A comparison of the reaction mechanism[J]. J Catal, 2004, 224(2): 429-440.
4. [4]
  [4] PIETERSE J A Z, BOONEVELD S, VAN DEN BRINK R W. Evaluation of Fe-zeolite catalysts prepared by different methods for the decomposition of N₂O[J]. Appl Catal B: Environ, 2004, 51(4): 215-228.
5. [5]
  [5] JÍÑA K, NOVÁKOVÁ J, SCHWARZE M, VONDROVÁ A, SKLENÁK S, SOBALIK Z. Role of the Fe-zeolite structure and iron state in the N₂O decomposition: Comparison of Fe-FER, Fe-BEA, and Fe-MFI catalysts[J]. J Catal, 2009, 262(1): 27-34.
6. [6]
  [6] OHNISHI C, ASANO K, IWAMOTO S, CHIKAMA K, INOUE M. Alkali-doped Co₃O₄ catalysts for direct decomposition of N₂O in the presence of oxygen[J]. Catal Today, 2007, 120(2): 145-150.
7. [7]
  [7] ASANO K, OHNISHI C, IWAMOTO S, SHIOYA Y, INOUE M. Potassium-doped Co₃O₄ catalyst for direct decomposition of N₂O[J]. Appl Catal B: Environ, 2008, 78(3/4): 242-249.
8. [8]
  [8] STELMACHOWSKI P, MANIAK G, KOTARBA A, SOJKA Z. Strong electronic promotion of Co₃O₄ towards N₂O decomposition by surface alkali dopants[J]. Catal Commun, 2009, 10(7): 1062-1065.
9. [9]
  [9] PASHA N, LINGAIAH N, BABU N S, REDDY P S S, PRASAD P S S. Studies on cesium doped cobalt oxide catalysts for direct N₂O decomposition in the presence of oxygen and steam[J]. Catal Commun, 2008, 10(2): 132-136.
10. [10]
  [10] SHEN Q, LI L D, LI J J, TIAN H, HAO Z P. A study on N₂O catalytic decomposition over Co/MgO catalysts[J]. J Hazard Mater, 2009, 163(2/3): 1332- 1337.
11. [11]
  [11] 武海鹏, 李文静, 郭丽, 潘燕飞, 徐秀峰. 碱金属助剂类型及前驱物对改性NiAl复合氧化物催化分解N₂O活性的影响[J]. 燃料化学学报, 2011, 39(7): 550-555.
12. [12]
  (WU Hai-peng, LI Wen-jing, GUO Li, PAN Yan-fei, XU Xiu-feng. The effect of promoter species and precursors on catalytic activity of alkali metal promoted NiAl mixed oxides for N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, 2011, 39(7): 550-555.)
13. [13]
  [12] 武海鹏, 钱振英, 徐晓玲, 徐秀峰. K改性NiAl类水滑石衍生复合氧化物催化分解N₂O[J]. 燃料化学学报, 2011, 39(2): 115-121.
14. [14]
  (WU Hai-peng, XU Zhen-ying, XU Xiao-ling, XU Xiu-feng. N₂O decomposition over K-promoted NiAl mixed oxides derived from hydrotalcite-like compounds[J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 115-121.)
15. [15]
  [13] CHENG H K, HUANG Y Q, WANG A Q, LI L, WANG X D, ZHANG T. N₂O decomposition over K-promoted Co-Al catalysts prepared from hydrotalcite-like precursors[J]. Appl Catal B: Environ, 2009, 89(3/4): 391-397.
16. [16]
  [14] ABU-ZIED B M. 碱促进的钴酸镁催化剂上的氧化亚氮分解[J]. 催化学报, 2011, 32(2): 264-272.
17. [17]
  (ABU-ZIED B M. Nitrous oxide decomposition over alkali-promoted magnesium cobaltite catalysts[J]. Chinese Journal of Catalysis, 2011, 32(2): 264-272.)
18. [18]
  [15] PARRES-ESCLAPEZ S, ILLÁN-GÓMEZ M J, SALINAS-MARTÍNEZ DE LECEA C, BUENO-LPEZ A. On the importance of the catalyst redox properties in the N₂O decomposition over alumina and ceria supported Rh, Pd and Pt[J]. Appl Catal B: Environ, 2010, 96(3/4): 370-378.
19. [19]
  [16] BOISSEL V, TAHIR S, KOH C A. Catalytic decomposition of N₂O over monolithic supported noble metal-transition metal oxides[J]. Appl Catal B: Environ, 2006, 64(3/4): 234-242.
20. [20]
  [17] YAN L, ZHANG X M, REN T, ZHANG H P, WANG X L, SUO J S. Superior performance of nano-Au supported over Co₃O₄ catalyst in direct N₂O decomposition[J]. Chem Commun, 2002, (8): 860-861.
21. [21]
  [18] 徐晓玲, 徐秀峰, 张国涛, 牛宪军. 钴铝复合氧化物负载金催化剂的制备及催化分解N₂O[J]. 燃料化学学报, 2009, 37(5): 595-600.
22. [22]
  (XU Xiao-ling, XU Xiu-feng, ZHANG Guo-tao, NIU Xian-jun. Preparation of Co-Al mixed oxide supported gold catalysts and their catalytic activity for N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, 2009, 37(5): 595-600.)
23. [23]
  [19] LEE S J, GAVRIILIDIS A. Supported Au catalysts for low-temperature CO oxidation prepared by impregnation[J]. J Catal, 2002, 206(2): 305-313.
24. [24]
  [20] KUNG H H, KUNG M C, COSTELLO C K. Supported Au catalysts for low temperature CO oxidation[J]. J Catal, 2003, 216(1/2): 425-432.
25. [25]
  [21] MANIAK G, STELMACHOWSKI P, KOTARBA A, SOJKA Z, RICO-PÉREZ V, BUENO-LÓPEZ A. Rationales for the selection of the best precursor for potassium doping of cobalt spinel based deN₂O catalyst[J]. Appl Catal B: Environ, 2013, 136-137: 302-307.
26. [26]
  [22] LIN J N, CHEN J H, HSIAO C Y, KANG Y M, WAN B Z. Gold supported on surface acidity modified Y-type and iron/Y-type zeolite for CO oxidation[J]. Appl Catal B: Environ, 2002, 36(1): 19-29.
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
3. [3]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
4. [4]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
5. [5]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
6. [6]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
7. [7]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
8. [8]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
9. [9]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
10. [10]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
11. [11]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
12. [12]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
13. [13]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
14. [14]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
17. [17]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
18. [18]
  Qi Wu , Changhua Wang , Yingying Li , Xintong Zhang . Enhanced photocatalytic synthesis of H₂O₂ by triplet electron transfer at g-C₃N₄@BN van der Waals heterojunction interface. Acta Physico-Chimica Sinica, 2025, 41(9): 100107-0. doi: 10.1016/j.actphy.2025.100107
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(413)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic decomposition of N2O over Au/Co3O4 and Au/ZnCo2O4 catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic decomposition of N₂O over Au/Co₃O₄ and Au/ZnCo₂O₄ catalysts