Citation: JING Wen, HOU Ya-qin, GUO Qian-qian, HUANG Zhang-gen, HAN Xiao-jin, MA Guo-qiang. Using vanadyl sulfate to prepare carbon-supported vanadium catalyst for flue gas desulfurization[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1223-1233. shu

Using vanadyl sulfate to prepare carbon-supported vanadium catalyst for flue gas desulfurization

1.
1.State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: HUANG Zhang-gen,
Received Date: 8 April 2013
Available Online: 12 June 2013

Vanadyl sulfate (V^IVOSO₄) was used to prepare carbon-supported vanadium catalyst for flue gas desulfurization. The V^IVOSO₄ impregnated on activated carbon (AC) was easily oxidized into vanadium(V) sulfate phase (possibly V₂O₃(SO₄)₂) in air, which exhibited high catalytic activity toward SO₂ oxidation, thus significantly enhancing SO₂ retention on AC. Furthermore, the vanadium(V) sulfate can be decomposed upon calcination in nitrogen with optimum temperature of 500℃ to form vanadium(V) oxide, further improving SO₂ retention mainly due to increase in micorpore volume suitable for sulfate storage and showing suitability of vanadyl sulfate to prepare traditional V₂O₅/AC catalyst. To obtain fully oxidized vanadium oxides, preoxidation was carried out on catalyst after calcination. However, due to ablation of carbon support, reduction of vanadium and/or formation of surface oxygen groups, the preoxidation was negative for SO₂ retention. Additionally, this paper provided preliminary evidence indicating transformation of vanadium(V) oxide in V₂O₅/AC into vanadium(V) sulfate during desulfurization. Combined with catalytic role of vanadium(V) sulfate for SO₂ oxidation, SO₂ removal on V₂O₅/AC likely followed a mechanism that the vanadium(V) oxide firstly transformed into vanadium(V) sulfate and the latter was then responsible for subsequent SO₂ oxidation into H₂SO₄.
- V₂O₅/AC,
- SO₂ removal,
- vanadium(V) sulfate,
- catalytic role,
- low temperature
1. [1]
  [1] LOÓPEZ D, BUITRAGO R, SEPUÙLVEDA-ESCRIBANO A, RODRIÍGUEZ-REINOSO F, MONDRAGOÙN F. Low temperature catalytic adsorption of SO₂ on activated carbon[J]. J Phys Chem C, 2008, 112(39): 15335-15340.
2. [2]
  [2] ARCIBAR-OROZCO J A, RANGEL-MENDEZ J R, BANDOSZ T J. Reactive adsorption of SO₂ on activated carbons with deposited iron nanoparticles[J]. J Hazard Mater, 2013, 246-247: 300-309.
3. [3]
  [3] NAKTIYOK J, BAYRAKÖEKEN H, ÖZER A K, GŰLABOGLU M S. Flue gas desulfurization by calcined phosphate rock and reaction kinetics[J]. Energy Fuels, 2013, 21(3):1466-1472.
4. [4]
  [4] SAKAI M, SU C, SASAOKA E. Simultaneous removal of SO_x and NO_x using slaked lime at low temperature[J]. Ind Eng Chem Res, 2002, 41(20): 5029-5033.
5. [5]
  [5] KAMINSKI J. Technologies and costs of SO₂-emissions reduction for the energy sector[J]. Appl Energy, 2003, 75(3/4): 165-172.
6. [6]
  [6] DAVINI P. SO₂ and NO_x adsorption properties of activated carbons obtained from a pitch containing iron derivatives[J]. Carbon, 2001, 39(14): 2173-2179.
7. [7]
  [7] TSENG H H, WEY M Y. Study of SO₂ adsorption and thermal regeneration over activated carbon-supported copper oxide catalysts[J]. Carbon, 2004, 42(11): 2269-2278.
8. [8]
  [8] BOYANO A, GÁLVEZ M E, MOLINER R, LÁZARO M J. Carbon-based catalytic briquettes for the reduction of NO: Effect of H₂SO₄ and HNO₃ carbon support treatment[J]. Fuel, 2008, 87(10/11): 2058-2068.
9. [9]
  [9] XING X, LIU Z, YANG J. Mo and Co doped V₂O₅/AC catalyst-sorbents for flue gas SO₂ removal and elemental sulfur production[J]. Fuel, 2008, 87(8/9): 1705-1710.
10. [10]
  [10] MACÍAS-PÉREZ M C, BUENO-LÓPEZ A, LILLO-RÓDENAS M A, SALINAS-MARTÍNEZ DE LECEA C, LINARES-SOLANO A. SO₂ retention on CaO/activated carbon sorbents. Part III. Study of the retention and regeneration conditions[J]. Fuel, 2008, 87(15/16): 3170-3175.
11. [11]
  [11] MA J, LIU Z, LIU S, ZHU Z. A regenerable Fe/AC desulfurizer for SO₂ adsorption at low temperatures[J]. Appl Catal B: Environ, 2003, 45(4): 301-309.
12. [12]
  [12] PRZEPIÓRSKI J, CZYZEWSKI A, KAPICA J, MOSZYŃSKI D, GRZMIL B, TRYBA B, MOZIA S, MORAWSKI A W. Low temperature removal of SO₂ traces from air by MgO-loaded porous carbons[J]. Chem Eng J, 2012, 191: 147-153.
13. [13]
  [13] MA J, LIU Z, LIU Q, GUO S, HUANG Z, XIAO Y. SO₂ and NO removal from flue gas over V₂O₅/AC at lower temperatures-Role of V₂O₅ on SO₂ removal[J]. Fuel Process Technol, 2008, 89(3): 242-248.
14. [14]
  [14] XIAO Y, LIU Q, LIU Z, HUANG Z, GUO Y, YANG J. Roles of lattice oxygen in V₂O₅ and activated coke in SO₂ removal over coke-supported V₂O₅ catalysts[J]. Appl Catal B: Environ, 2008, 82(1/2): 114-119.
15. [15]
  [15] 郭彦霞, 刘振宇, 李允梅, 刘清雅. 氨再生条件对V2O5/AC同时脱硫脱硝活性的影响[J]. 燃料化学学报, 2007, 35(3): 344-348.
16. [16]
  (GUO Yan-xia, LIU Zhen-yu, LI Yun-mei, LIU Qing-ya. NH₃ regeneration of SO₂-captured V₂O₅/AC catalyst-sorbent for simultaneous SO₂ and NO removal[J]. Journal of Fuel Chemistry and Technology, 2007, 35(3): 344-348.)
17. [17]
  [16] ZHU Z, NIU H, LIU Z, LIU, S. Decomposition and reactivity of NH₄HSO₄ on V₂O₅/AC catalysts used for NO reduction with ammonia[J]. J Catal, 2000, 195(2): 268-278.
18. [18]
  [17] COULSTON G W, THOMPSON E A, HERRON N. Characterization of VPO catalysts by X-ray photoelectron spectroscopy[J]. J Catal, 1996, 163(1): 122-129.
19. [19]
  [18] NEFEDOV V I, SALYN YA V, LEONHARDT G, SCHEIBE R. A comparison of different spectrometers and charge corrections used in X-ray photoelectron spectroscopy[J]. J Electro Spectrosc Relat Phenom, 1977, 10(2): 121-124.
20. [20]
  [19] KASPERKIEWICZ J, KOVACICH J A, LICHTMAN D. XPS studies of vanadium and vanadium oxides[J]. J Electro Spectrosc Relat Phenom, 1983, 32(2): 123-132.
21. [21]
  [20] GARCÍA-BORDEJÉ E, PINILLA J L, LÁZARO M J, MOLINER R, FIERRO J L G. Role of sulphates on the mechanism of NH₃-SCR of NO at low temperatures over presulphated vanadium supported on carbon-coated monoliths[J]. J Catal, 2005, 233(1): 166-175.
22. [22]
  [21] GIAKOUMELOU I, PARVULESCU V, BOGHOSIAN S. Oxidation of sulfur dioxide over supported solid V₂O₅/SiO₂ and supported molten salt V₂O₅-Cs₂SO₄/SiO₂ catalysts: Molecular structure and reactivity[J]. J Catal, 2004, 225(2): 337-349.
23. [23]
  [22] CHRISTODOULAKIS A, BOGHOSIAN S. Molecular structure of supported molten salt catalysts for SO₂ oxidation[J]. J Catal, 2003, 215(1): 139-150.
24. [24]
  [23] GIAKOUMELOU I, CARABA R M, PARVULESCU V I, BOGHOSIAN S. First in situ raman study of vanadium oxide based SO₂ oxidation supported molten salt catalysts[J]. Catal Lett, 2002, 78(1): 209-214.
25. [25]
  [24] LIZZIO A A, DEBARR J A. Effect of surface area and chemisorbed oxygen on the SO₂ adsorption capacity of activated char[J]. Fuel, 1996, 75(13): 1515-1522.
26. [26]
  [25] LIZZIO A A, DEBARR J A. Mechanism of SO₂ removal by carbon[J]. Energy Fuels, 1997, 11(2): 284-291.
27. [27]
  [26] RAYMUNDO-PIÑERO E, CAZORLA-AMORÓS D, LINARES-SOLANO A. Temperature programmed desorption study on the mechanism of SO₂ oxidation by activated carbon and activated carbon fibres[J]. Carbon, 2001, 39(2): 231-242.
28. [28]
  [27] RAYMUNDO-PIÑERO E, CAZORLA-AMORÓS D, SALINAS-MARTINEZ DE LECEA C, LINARES-SOLANO A. Factors controling the SO₂ removal by porous carbons: Relevance of the SO₂ oxidation step[J]. Carbon, 2000, 38(3): 335-344.
29. [29]
  [28] ZHU Z, LIU Z, NIU H, LIU S, HU T, LIU T, XIE Y. Mechanism of SO₂ promotion for NO reduction with NH₃ over activated carbon-supported vanadium oxide catalyst[J]. J Catal, 2001, 197(1): 6-16.
30. [30]
  [29] ZHOU J H, SUI Z J, ZHU J, LI P, CHEN D, DAI Y C, YUAN W K. Characterization of surface oxygen complexes on carbon nanofibers by TPD, XPS and FT-IR[J]. Carbon, 2007, 45(4): 785-796.
31. [31]
  [30] LEE W H, LEE J G, REUCROFT P J. XPS study of carbon fiber surfaces treated by thermal oxidation in a gas mixture of O₂/(O₂+N₂) [J]. Appl Surf Sci, 2001, 171(1/2): 136-142.
32. [32]
  [31] MARTIN C, PERRARD A, JOLY J P, GAILLARD F, DELECROIX V. Dynamic adsorption on activated carbons of SO₂ traces in air: I. Adsorption capacities[J]. Carbon, 2002, 40(12): 2235-2246.
33. [33]
  [32] DAVINI P, Adsorption and desorption of SO₂ on active carbon: The effect of surface basic groups[J]. Carbon, 1990, 28(4): 565-571.
34. [34]
  [33] ZHU Z, LIU Z, LIU S, NIU H, HU T, LIU T, XIE Y. NO reduction with NH₃ over an activated carbon-supported copper oxide catalysts at low temperatures[J]. Appl Catal B: Environ, 2000, 26(1): 25-35.
35. [35]
  [34] TSENG H H, WEY M Y, LIANG Y S, CHEN K H. Catalytic removal of SO₂, NO and HCl from incineration flue gas over activated carbon-supported metal oxides[J]. Carbon, 2003, 41(5): 1079-1085.
36. [36]
  [35] XING X, LIU Z, WANG J. Elemental sulfur production through regeneration of a SO₂-adsorbed V₂O₅-CoO/AC in H₂[J]. Fuel Process Technol, 2007, 88(7): 717-722.
37. [37]
  [36] GARCÍA-BORDEJÉ E, PINILLA J L, LÁZARO M J, MOLINER R. NH₃-SCR of NO at low temperatures over sulphated vanadia on carbon-coated monoliths: Effect of H₂O and SO₂ traces in the gas feed[J]. Appl Catal B: Environ, 2006, 66(3/4): 281-287.
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