Citation: HAI Hang, YAN Chang-feng, HU Rong-rong, GUO Chang-qing, LI Wen-bo. Effect of promoter on performance of hydrogen production from steam reforming of dimethyl ether with a metal foam microreactor[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1210-1216. shu

Effect of promoter on performance of hydrogen production from steam reforming of dimethyl ether with a metal foam microreactor

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: YAN Chang-feng,
Received Date: 24 February 2013
Available Online: 12 April 2013
Fund Project: 国家自然科学基金(21276254)。 (21276254)

The CuO-ZnO-Al₂O₃/HZSM-5 catalyst prepared by co-precipitation and mechanical mixing with HZSM-5 was used for hydrogen production from steam reforming of dimethyl ether. The effects of Cr, Zr, Co and Ce promoters on catalyst performance were investigated by means of X-ray diffraction(XRD), temperature programmed reduction (H₂-TPR), SEM and BET. The results showed that addition of promoter Cr can reduce the average pore diameter and reduction temperature of catalyst effectively, and inhibited the form of Zn(OH)₂ in the catalyst preparation process. The conversion of dimethyl ether and hydrogen yield reaches 99% and 95% respectively at low reaction temperature. The effects of reaction termperature, space velocity and steam-to-DME ratio were investigated. At the conditions of 250℃, the space velocity of 3884mL/(g.h), H₂O/DME=5, over 97% of DME conversion was obtained over the CuO-ZnO-Al₂O₃-Cr₂O₃/HZSM-5 catalyst and the catalytic activity has no obvious deactivation during 50h durability test.
- steam reforming of dimethyl ether,
- metal foam,
- Cr promoter,
- metal foam microreactor
1. [1]
  [1] EBERLE U, FELDERHOFF M, SCHUTH F. Chemical and physical solutions for hydrogen storage[J]. Chem Int Edition, 2009, 48(36): 6608-6630.
2. [2]
  [2] 王晓蕾, 任克威, 林瑞. 二甲醚重整制氢技术的研究进展[J]. 天然气化工, 2008, 33(03): 65-69.
3. [3]
  (WANG Xiao-lei, REN Ke-wei, LIN Rui. Research progress in hydrogen production from the reforming of dimethyl ether[J]. Nature Gas Chemical Industry, 2008, 33(03): 65-69.)
4. [4]
  [3] 王树东.分布式制氢与燃料电池氢源[C]. 第八届全国氢能学术会议, 西安, 2007.
5. [5]
  (WANG Shu-dong. Distributed hydrogen production and hydrogen source of fuel cell[C]. The 8th China hydrogen energy conference, Xi'an, 2007.)
6. [6]
  [4] CHANG C C, HSU C C, CHANG C T, CHEN Y P, LIAW B J, CHEN Y Z. Effect of noble metal on oxidative steam reforming of methanol over CuO/ZnO/Al₂O₃ catalysts[J]. Int J Hydrogen Energy, 2012, 37(15): 11176-11184.
7. [7]
  [5] PAPAVASILIOU J, AVGOUROPOULOS G, IOANNIDES T. Effect of dopants on the performance of CuO-CeO₂ catalysts in methanol steam reforming[J]. App Catal B: Environ, 2007, 69(3/4): 226-234.
8. [8]
  [6] ALEXEY S, CHAN K. Progress in development of direct dimethyl ether fuel cells[J]. Appl Catal B: Environ, 2009, 91(1/2): 1-10.
9. [9]
  [7] SEMELSBERGER T A, BORUP R L, GREENE H L. Dimethyl ether (DME) as an alternative fuel[J]. J Power Sources, 2006, 156(2): 497-511.
10. [10]
  [8] 李超, 李琢, 李建青, 杨成, 吴晋沪. 一步法合成二甲醚整体式催化剂的制备及反应性能研究[J]. 燃料化学学报, 2011, 39(4): 287-292.
11. [11]
  (LI Chao, LI Zhuo, LI Jian-qing, YANG Cheng, WU Jin-hu. Preparation and catalytic propertiesof amonolithic catalyst for one step synthesis of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2011, 39(4): 287-292.)
12. [12]
  [9] 左宜赞, 张强, 安欣, 韩明汉, 王铁锋, 王金福, 金涌. 浆态床中Cu/ZnO/Al₂O₃/ZrO₂+γ-Al₂O₃双功能催化剂一步法合成二甲醚[J]. 燃料化学学报, 2010, 38(1): 102-107.
13. [13]
  (ZUO Yi-zan, ZHANG Qiang, AN Xin, HAN Ming-han, WANG Tie-feng, WANG Jin-fu, JIN Yong. Single-step dimethyl ether synthesison a Cu/ZnO/Al₂O₃/ZrO₂+γ-Al₂O₃ bifunctional catalyst in slurry reactor[J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 102-107.)
14. [14]
  [10] 陈卫国, 胡娟. 二甲醚(DME)的开发和应用[J]. 城市燃气, 2006, 375(5): 3-14.
15. [15]
  (CHEN Wei-guo, HU Juan. The development and application of dimethyl ether(DME)[J]. City Gas, 2006, 375(5): 3-14.)
16. [16]
  [11] GALVITA V V, SEMIN G L, BELYAEV V D, YURIEVA T M, SOBYANIN V A. Production of hydrogen from dimethyl ether [J]. Appl Catal A: Gen, 2001, 216(1/2): 85-90.
17. [17]
  [12] PARK S, CHOI B, KIM H, KIM J H. Hydrogen production from dimethyl ether over Cu/gamma-Al₂O₃ catalyst with zeolites and its effects in the lean NO_x trap performance [J]. Int J Hydrogen Energy, 2012, 37(6): 4762-4773.
18. [18]
  [13] LI J, ZHANG Q J, LONG X, QI P, LIU Z T, LIU ZW. Hydrogen production for fuel cells via steam reforming of dimethyl ether over commercial Cu/ZnO/Al₂O₃ and zeolite[J]. Chem Eng J, 2012, 187: 299-305.
19. [19]
  [14] 王晓蕾, 任克威, 潘相敏, 林瑞, 马建新.固体酸催化剂对二甲醚水蒸气重整制氢过程的影响[J]. 催化学报, 2009, 30(4): 297-304.
20. [20]
  (WANG Xiao-lei, REN Ke-wei, PAN Xiang-min, LIN Rui, MA Jian-xin. Influence of solid acid catalysts on steam reforming of dimethyl ether for hydrogen production[J]. Chinese Journal of Catalysis, 2009, 30(4): 297-304.)
21. [21]
  [15] PAJAIE H S, TAGHIZADEH M. Investigation of promoted Cu/ZnO/Al₂O₃ methanol steam reforming nanocatalysts by full factorial design[J]. Chem Eng Technol, 2012, 35(10): 1857-1864.
22. [22]
  [16] KAWABATA T, MATSUOKA H, SHISHIDO T, LI D L, TIAN Y, SANO T, TAKEHIRA K. Steam reforming of dimethyl ether over ZSM-5 coupled with Cu/ZnO/Al₂O₃ catalyst prepared by homogeneous precipitation[J]. Appl Catal A: Gen, 2006, 32(4): 82-90.
23. [23]
  [17] YU H, CHEN H Q, PAN M Q, TANG Y, ZENG K, PENG F, WANG H J. Effect of the metal foam materials on the performance of methanol steam micro-reformer for fuel cells[J]. Appl Catal A: Gen, 2007, 327(1): 106-113.
24. [24]
  [18] 李娟, 海航, 闫常峰, 胡蓉蓉, 么志伟, 罗伟民, 郭常青, 李文博. 焙烧温度对二甲醚水蒸气重整制氢Cu/ZnO/Al₂O₃/Cr₂O₃+H-ZSM-5双功能催化剂性能的影响[J]. 燃料化学学报, 2012, 40(10): 1240-1245.
25. [25]
  (LI Juan, HAI Hang, YAN Chang-feng, HU Rong-rong, YAO Zhi-wei, LUO Wei-min, GUO Chang-qing, LI Wen-bo. Effect of calcination temperature on properties of Cu/ZnO/Al₂O₃/Cr₂O₃+HZSM-5 bi-functional catalysts for steam reforming of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 1240-1245.)
26. [26]
  [19] 刘智信, 李东风. 多孔金属在催化中的作用[J]. 金属功能材料, 2004, 11(2): 35-37.
27. [27]
  (LIU Zhi-xin, LI Dong-feng. The role of the porous metal in the catalytic[J]. Metallic Function Materials, 2004, 11(2): 35-37.)
28. [28]
  [20] 高军, 董新法, 林维明. 泡沫金属微反应器内富氢重整气中CO选择性甲烷化[J]. 燃料化学学报, 2010, 38(3): 337-342.
29. [29]
  (GAO Jun, DONG Xin-fa, LIN Wei-ming. Selective catalytic methanation of CO in hydrogen-rich gas with a metal foam microreactor[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 337-342.
30. [30]
  [21] FAUNGNAWAKIJ K, EGUCHI K. Dimethyl ether-reforming catalysts for hydrogen production[J]. Catal Surv Asia, 2011, 15(1): 12-24.
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