Citation: HAI Hang, YAN Chang-feng, HU Rong-rong, GUO Chang-qing, LI Wen-bo. Effect of promoter on performance of hydrogen production from steam reforming of dimethyl ether with a metal foam microreactor[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1210-1216. shu

Effect of promoter on performance of hydrogen production from steam reforming of dimethyl ether with a metal foam microreactor

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: YAN Chang-feng,
Received Date: 24 February 2013
Available Online: 12 April 2013
Fund Project: 国家自然科学基金(21276254)。 (21276254)

The CuO-ZnO-Al₂O₃/HZSM-5 catalyst prepared by co-precipitation and mechanical mixing with HZSM-5 was used for hydrogen production from steam reforming of dimethyl ether. The effects of Cr, Zr, Co and Ce promoters on catalyst performance were investigated by means of X-ray diffraction(XRD), temperature programmed reduction (H₂-TPR), SEM and BET. The results showed that addition of promoter Cr can reduce the average pore diameter and reduction temperature of catalyst effectively, and inhibited the form of Zn(OH)₂ in the catalyst preparation process. The conversion of dimethyl ether and hydrogen yield reaches 99% and 95% respectively at low reaction temperature. The effects of reaction termperature, space velocity and steam-to-DME ratio were investigated. At the conditions of 250℃, the space velocity of 3884mL/(g.h), H₂O/DME=5, over 97% of DME conversion was obtained over the CuO-ZnO-Al₂O₃-Cr₂O₃/HZSM-5 catalyst and the catalytic activity has no obvious deactivation during 50h durability test.
- steam reforming of dimethyl ether,
- metal foam,
- Cr promoter,
- metal foam microreactor
1. [1]
  [1] EBERLE U, FELDERHOFF M, SCHUTH F. Chemical and physical solutions for hydrogen storage[J]. Chem Int Edition, 2009, 48(36): 6608-6630.
2. [2]
  [2] 王晓蕾, 任克威, 林瑞. 二甲醚重整制氢技术的研究进展[J]. 天然气化工, 2008, 33(03): 65-69.
3. [3]
  (WANG Xiao-lei, REN Ke-wei, LIN Rui. Research progress in hydrogen production from the reforming of dimethyl ether[J]. Nature Gas Chemical Industry, 2008, 33(03): 65-69.)
4. [4]
  [3] 王树东.分布式制氢与燃料电池氢源[C]. 第八届全国氢能学术会议, 西安, 2007.
5. [5]
  (WANG Shu-dong. Distributed hydrogen production and hydrogen source of fuel cell[C]. The 8th China hydrogen energy conference, Xi'an, 2007.)
6. [6]
  [4] CHANG C C, HSU C C, CHANG C T, CHEN Y P, LIAW B J, CHEN Y Z. Effect of noble metal on oxidative steam reforming of methanol over CuO/ZnO/Al₂O₃ catalysts[J]. Int J Hydrogen Energy, 2012, 37(15): 11176-11184.
7. [7]
  [5] PAPAVASILIOU J, AVGOUROPOULOS G, IOANNIDES T. Effect of dopants on the performance of CuO-CeO₂ catalysts in methanol steam reforming[J]. App Catal B: Environ, 2007, 69(3/4): 226-234.
8. [8]
  [6] ALEXEY S, CHAN K. Progress in development of direct dimethyl ether fuel cells[J]. Appl Catal B: Environ, 2009, 91(1/2): 1-10.
9. [9]
  [7] SEMELSBERGER T A, BORUP R L, GREENE H L. Dimethyl ether (DME) as an alternative fuel[J]. J Power Sources, 2006, 156(2): 497-511.
10. [10]
  [8] 李超, 李琢, 李建青, 杨成, 吴晋沪. 一步法合成二甲醚整体式催化剂的制备及反应性能研究[J]. 燃料化学学报, 2011, 39(4): 287-292.
11. [11]
  (LI Chao, LI Zhuo, LI Jian-qing, YANG Cheng, WU Jin-hu. Preparation and catalytic propertiesof amonolithic catalyst for one step synthesis of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2011, 39(4): 287-292.)
12. [12]
  [9] 左宜赞, 张强, 安欣, 韩明汉, 王铁锋, 王金福, 金涌. 浆态床中Cu/ZnO/Al₂O₃/ZrO₂+γ-Al₂O₃双功能催化剂一步法合成二甲醚[J]. 燃料化学学报, 2010, 38(1): 102-107.
13. [13]
  (ZUO Yi-zan, ZHANG Qiang, AN Xin, HAN Ming-han, WANG Tie-feng, WANG Jin-fu, JIN Yong. Single-step dimethyl ether synthesison a Cu/ZnO/Al₂O₃/ZrO₂+γ-Al₂O₃ bifunctional catalyst in slurry reactor[J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 102-107.)
14. [14]
  [10] 陈卫国, 胡娟. 二甲醚(DME)的开发和应用[J]. 城市燃气, 2006, 375(5): 3-14.
15. [15]
  (CHEN Wei-guo, HU Juan. The development and application of dimethyl ether(DME)[J]. City Gas, 2006, 375(5): 3-14.)
16. [16]
  [11] GALVITA V V, SEMIN G L, BELYAEV V D, YURIEVA T M, SOBYANIN V A. Production of hydrogen from dimethyl ether [J]. Appl Catal A: Gen, 2001, 216(1/2): 85-90.
17. [17]
  [12] PARK S, CHOI B, KIM H, KIM J H. Hydrogen production from dimethyl ether over Cu/gamma-Al₂O₃ catalyst with zeolites and its effects in the lean NO_x trap performance [J]. Int J Hydrogen Energy, 2012, 37(6): 4762-4773.
18. [18]
  [13] LI J, ZHANG Q J, LONG X, QI P, LIU Z T, LIU ZW. Hydrogen production for fuel cells via steam reforming of dimethyl ether over commercial Cu/ZnO/Al₂O₃ and zeolite[J]. Chem Eng J, 2012, 187: 299-305.
19. [19]
  [14] 王晓蕾, 任克威, 潘相敏, 林瑞, 马建新.固体酸催化剂对二甲醚水蒸气重整制氢过程的影响[J]. 催化学报, 2009, 30(4): 297-304.
20. [20]
  (WANG Xiao-lei, REN Ke-wei, PAN Xiang-min, LIN Rui, MA Jian-xin. Influence of solid acid catalysts on steam reforming of dimethyl ether for hydrogen production[J]. Chinese Journal of Catalysis, 2009, 30(4): 297-304.)
21. [21]
  [15] PAJAIE H S, TAGHIZADEH M. Investigation of promoted Cu/ZnO/Al₂O₃ methanol steam reforming nanocatalysts by full factorial design[J]. Chem Eng Technol, 2012, 35(10): 1857-1864.
22. [22]
  [16] KAWABATA T, MATSUOKA H, SHISHIDO T, LI D L, TIAN Y, SANO T, TAKEHIRA K. Steam reforming of dimethyl ether over ZSM-5 coupled with Cu/ZnO/Al₂O₃ catalyst prepared by homogeneous precipitation[J]. Appl Catal A: Gen, 2006, 32(4): 82-90.
23. [23]
  [17] YU H, CHEN H Q, PAN M Q, TANG Y, ZENG K, PENG F, WANG H J. Effect of the metal foam materials on the performance of methanol steam micro-reformer for fuel cells[J]. Appl Catal A: Gen, 2007, 327(1): 106-113.
24. [24]
  [18] 李娟, 海航, 闫常峰, 胡蓉蓉, 么志伟, 罗伟民, 郭常青, 李文博. 焙烧温度对二甲醚水蒸气重整制氢Cu/ZnO/Al₂O₃/Cr₂O₃+H-ZSM-5双功能催化剂性能的影响[J]. 燃料化学学报, 2012, 40(10): 1240-1245.
25. [25]
  (LI Juan, HAI Hang, YAN Chang-feng, HU Rong-rong, YAO Zhi-wei, LUO Wei-min, GUO Chang-qing, LI Wen-bo. Effect of calcination temperature on properties of Cu/ZnO/Al₂O₃/Cr₂O₃+HZSM-5 bi-functional catalysts for steam reforming of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 1240-1245.)
26. [26]
  [19] 刘智信, 李东风. 多孔金属在催化中的作用[J]. 金属功能材料, 2004, 11(2): 35-37.
27. [27]
  (LIU Zhi-xin, LI Dong-feng. The role of the porous metal in the catalytic[J]. Metallic Function Materials, 2004, 11(2): 35-37.)
28. [28]
  [20] 高军, 董新法, 林维明. 泡沫金属微反应器内富氢重整气中CO选择性甲烷化[J]. 燃料化学学报, 2010, 38(3): 337-342.
29. [29]
  (GAO Jun, DONG Xin-fa, LIN Wei-ming. Selective catalytic methanation of CO in hydrogen-rich gas with a metal foam microreactor[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 337-342.
30. [30]
  [21] FAUNGNAWAKIJ K, EGUCHI K. Dimethyl ether-reforming catalysts for hydrogen production[J]. Catal Surv Asia, 2011, 15(1): 12-24.
1. [1]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
2. [2]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
3. [3]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
4. [4]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
8. [8]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
9. [9]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
10. [10]
  Haiyu Zhu , Zhuoqun Wen , Wen Xiong , Xingzhan Wei , Zhi Wang . 二维半金属/硅异质结中肖特基势垒高度的准确高效预测. Acta Physico-Chimica Sinica, 2025, 41(7): 100078-. doi: 10.1016/j.actphy.2025.100078
11. [11]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
12. [12]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
13. [13]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
14. [14]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
15. [15]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
16. [16]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
17. [17]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
18. [18]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
19. [19]
  Yang Chen , Xiuying Wang , Nengqin Jia . Ideological and Political Design, Blended Teaching Practice of Physical Chemistry Experiment: Pb-Sn Binary Metal Phase Diagram. University Chemistry, 2025, 40(3): 223-229. doi: 10.12461/PKU.DXHX202405184
20. [20]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(433)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142