Citation: WANG Chang-zhen, SI Lan-jie, LI Hai, WEN Xia, SUN Nan-nan, ZHAO Ning, WEI Wei, SUN Yu-han. Template-free one-pot synthesis of mesoporous Ni-CaO-ZrO₂ catalyst and its application in CH₄-CO₂ reforming[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1204-1209. shu

Template-free one-pot synthesis of mesoporous Ni-CaO-ZrO₂ catalyst and its application in CH₄-CO₂ reforming

WANG Chang-zhen ^1,2 ,
SI Lan-jie ¹ ,
LI Hai ³ ,
WEN Xia ⁴ ,
SUN Nan-nan ¹ ,
ZHAO Ning ¹ ,
WEI Wei ^1,4,, ,
SUN Yu-han ^1,5

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: WEI Wei,
Received Date: 10 June 2013
Available Online: 20 August 2013
Fund Project: 国家重点基础研究发展规划(973计划, 2011CB201405) (973计划, 2011CB201405)国家自然科学基金(21203230) (21203230)山西省自然科学基金(2012021005-5)。 (2012021005-5)

A novel mesoporous Ni-CaO-ZrO₂ catalyst with high surface area and pore volume was prepared by one-pot template-free method and applied in CH₄-CO₂ reforming. The mesoporous Ni-CaO-ZrO₂ catalyst was characterized by means of nitrogen sorption, SEM, TEM, XRD, H₂-TPR and TG-DSC. The results indicated that a strong metal support interaction (SMSI) present in the Ni-CaO-ZrO₂ catalyst induces an intimate contact between Ni and ZrO₂ nano-particles, which is favorable for the surface reaction of adsorbed reactant species for CH₄-CO₂ reforming. Owing to the mesoporous framework and SMSI, the Ni-CaO-ZrO₂ catalyst shows promising activity and stability in CH₄-CO₂ reforming. Most of the carbonaceous deposits on the catalyst surface are in whisker form, which does not cover the active sites and then has little influence on the catalyst stability.
- template-free,
- one-pot,
- nickel-based catalyst,
- methane reforming,
- mesoporous catalyst,
- carbon dioxide
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Template-free one-pot synthesis of mesoporous Ni-CaO-ZrO2 catalyst and its application in CH4-CO2 reforming

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通讯作者: 陈斌, bchen63@163.com

Template-free one-pot synthesis of mesoporous Ni-CaO-ZrO₂ catalyst and its application in CH₄-CO₂ reforming