Citation: ZHANG Qiang, SUN Yu-dong, WANG Xue, YANG Chao-he. Influence of ultrasonic treatment on residue hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(10): 1199-1203. shu

Influence of ultrasonic treatment on residue hydrogenation

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: SUN Yu-dong,
Received Date: 24 February 2013
Available Online: 4 April 2013
Fund Project: 中央高校基本科研业务费专项基金(11CX05008A) (11CX05008A)中国石油科技创新基金(2011D-5006-0405) (2011D-5006-0405)中国石油重大科技专项(10-01A-05-01-04) (10-01A-05-01-04)中国石油大学(华东)研究生创新工程项目(CX201304)。 (华东)研究生创新工程项目(CX201304)

The effect of ultrasomic treatment on the hydrotreating of residue was studied using 4 vacuum residues. Ultrasonic treatment can change the average structure of residue and the content of SARA fractions, and the structure of asphaltene at the same time, improving the hydrogenation performance. The hydrogenation of residue after ultrasonic treatment makes a decrease in the yield of coke and residue of above 500℃ but a increase in the yield of gas, gasoline, diesel distillate fractions and VGO and an increase of about 6 to 10 percentage points in light oil yield. The conversion of residue is improved, and the upgrading action is apparent. The upgrading of residue with ultrasonic treatment is related to the material type. The changes can be explained by the syphonage model in a macro level. It is also found that the removal of heteroatom, especially vanadium metal, is improved with the average removal rate of over 96%. After hydrogenation of residue, SARA fractions of residue are changed, the content of saturate and asphaltene is increased, but the aromatic and resin is reduced.
- ultrasonic treatment,
- residue hydrotreating,
- asphaltene,
- demetalization,
- removal of heteroatoms
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