Citation: LIU Hai-chao, LIU Ji-quan, GUO Qi-wen, LI Lian-di, LI Hong-guang, WEN Xia, XIAO Fu-kui, ZHAO Ning, WEI Wei, SUN Yu-han. Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1146-1152. shu

Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂

LIU Hai-chao ^1,2 ,
LIU Ji-quan ^1,2 ,
GUO Qi-wen ³ ,
LI Lian-di ^1,2 ,
LI Hong-guang ^1,2 ,
WEN Xia ¹ ,
XIAO Fu-kui ¹ ,
ZHAO Ning ¹ ,
WEI Wei ^1,, ,
SUN Yu-han ^1,4

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: WEI Wei,
Received Date: 12 November 2012
Available Online: 15 March 2013

Immobilized ZnCl₂ (Silzic) catalyst was prepared and used in the synthesis of 3-methyl-3-buten-1-ol (MBOH) from isobutylene and formaldehyde; the effects of the reaction parameters, such as temperature, molar ratio of isobutene to formaldehyde, reaction time and catalyst content on the reaction behavior were investigated. The results showed that the conversion of formaldehyde is over 99% under various conditions. The reaction temperature as well as the catalyst acidity and the amount of the acid sites are dominant factors in influencing the selectivity to MBOH. Under the optimum reaction conditions, i.e. 210 ℃, 8 g 1,4-dioxane, 1.5 g polyoxymethylene, n(isobutylene)/n(polyoxymethylene) ratio of 7, 30 mg Silzic (1 mmol/g), and reaction time of 2 h, the selectivity and yield of MBOH reach 93.8% and 93.4%, respectively. The Silzic catalyst exhibits certain reusability; the yield of MBOH remains 85.2% after reusing the catalyst for 5 times.
- Prins reaction,
- formaldehyde,
- isobutene,
- 3-methyl-3-buten-1-ol,
- SiO₂-ZnCl₂(Silzic)
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl2

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Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂