Citation: LI Yong, LI Lei, WEN Xia, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1122-1128. shu

Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method

LI Yong ^1,2 ,
LI Lei ¹ ,
WEN Xia ¹ ,
WANG Feng ¹ ,
ZHAO Ning ¹ ,
XIAO Fu-kui ¹ ,
WEI Wei ^1,, ,
SUN Yu-han ^1,3

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: WEI Wei,
Received Date: 12 February 2013
Available Online: 9 April 2013
Fund Project: 国家自然科学基金(20906099) (20906099)中国科学院战略性先导科技专项(XDA05010109、XDA05010110、XDA05010204)。 (XDA05010109、XDA05010110、XDA05010204)

A series of amine modified SBA-15 was prepared by a twice grafting method for CO₂ capture. The resulted materials were characterized by X-ray diffraction (XRD), N₂ adsorption/desorption, thermogravimetry (TG), elemental analysis, transmission electron microscopy (TEM) and Flourier transform infrared (FT-IR) spectrometry. CO₂ adsorption capacity of the adsorbents was obtained in a fixed bed through a breakthrough curve method. Effects of different preparation methods and different types of grafted organic amines were studied and recycled adsorption/desorption testing was carried out to evaluate the stability of the adsorbents. The results showed that, polyethylenimine(PEI) grafted SBA-15 prepared by supersonic method showed the best adsorption capacity, the optimist result was 1.72 mmol/g at 25 ℃ and 10 kPa CO₂ partial pressure. Furthermore, its adsorption capacity was found to be remaining constant after multiple adsorption/desorption cycles, indicating the high thermal stability of this adsorbent.
- twice grafting,
- amine modified,
- CO₂,
- adsorbent
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