Citation: LI Yong, LI Lei, WEN Xia, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1122-1128. shu

Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method

LI Yong ^1,2 ,
LI Lei ¹ ,
WEN Xia ¹ ,
WANG Feng ¹ ,
ZHAO Ning ¹ ,
XIAO Fu-kui ¹ ,
WEI Wei ^1,, ,
SUN Yu-han ^1,3

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: WEI Wei,
Received Date: 12 February 2013
Available Online: 9 April 2013
Fund Project: 国家自然科学基金(20906099) (20906099)中国科学院战略性先导科技专项(XDA05010109、XDA05010110、XDA05010204)。 (XDA05010109、XDA05010110、XDA05010204)

A series of amine modified SBA-15 was prepared by a twice grafting method for CO₂ capture. The resulted materials were characterized by X-ray diffraction (XRD), N₂ adsorption/desorption, thermogravimetry (TG), elemental analysis, transmission electron microscopy (TEM) and Flourier transform infrared (FT-IR) spectrometry. CO₂ adsorption capacity of the adsorbents was obtained in a fixed bed through a breakthrough curve method. Effects of different preparation methods and different types of grafted organic amines were studied and recycled adsorption/desorption testing was carried out to evaluate the stability of the adsorbents. The results showed that, polyethylenimine(PEI) grafted SBA-15 prepared by supersonic method showed the best adsorption capacity, the optimist result was 1.72 mmol/g at 25 ℃ and 10 kPa CO₂ partial pressure. Furthermore, its adsorption capacity was found to be remaining constant after multiple adsorption/desorption cycles, indicating the high thermal stability of this adsorbent.
- twice grafting,
- amine modified,
- CO₂,
- adsorbent
1. [1]
  [1] FIGUEROA J D, FOUT T, PLASYNSKI S, MCILVRIED H, SRIVASTAVA R D. Advances in CO₂ capture technology-The U.S. department of energy's carbon sequestration program[J]. Int J Green Gas Con, 2008, 2(1): 9-20.
2. [2]
  [2] HASZELDINE R S. Carbon capture and storage: How green can black be?[J] Sci, 2009, 325(5948): 1647-1652.
3. [3]
  [3] 黄黎明, 陈赓良. 二氧化碳的回收利用与捕集储存[J]. 石油天然气化工, 2006, 35(5): 453. (HUANG Li-ming, CHEN Geng-liang. The recovery, ultilization, capture and storage of carbon dioxide[J]. Chemcal Engineering of Oil & Gas, 2006, 35(5): 453.)
4. [4]
  [4] TONTIWACHWUTHIKUL P, MEISEN A, LIM C J. Solubility of CO₂ in 2-amino-2-methyl-1-propanol solutions[J]. J Chem Eng Data, 1991, 36(1): 130-133.
5. [5]
  [5] PLAZA M G, PEVIDA C, ARENILLAS A, RUBIERA F, PIS J J. CO₂ capture by adsorption with nitrogen enriched carbons[J]. Fuel, 2007, 86(14): 2204-2212.
6. [6]
  [6] DANTAS T L P, AMORIM S M, LUNA F M T, SILVA I J, AZEVEDO D C S, RODRIGUES A E, MOREIRA R. Adsorption of carbon dioxide onto activated carbon and nitrogen-enriched activated carbon: Surface changes, equilibrium, and modeling of fixed-bed adsorption[J]. Sep Sci Technol, 2010, 45(1): 73-84.
7. [7]
  [7] HAO G P, LI W C, QIAN D, LU A H. Rapid synthesis of nitrogen-doped porous carbon monolith for CO₂capture[J]. Adv Mater (Weinheim, Ger), 2010, 22(7): 853-857.
8. [8]
  [8] YANG H, GONG M C, CHEN Y Q. Preparation of activated carbons and their adsorption properties for greenhouse gases: CH₄ and CO₂[J]. J Nat Gas Chem, 2011, 20(5): 460-464.
9. [9]
  [9] 简相坤, 刘石彩, 边轶. 活性炭对CO₂的吸附与解吸研究进展[J]. 生物质化学工程, 2012, 46(3): 20-26. (JIAN Xiang-kun, LIU Shi-cai, BIAN Yi. Research progress of adsorption and desorption of CO₂ on activated carbon[J]. Biomass Chemical Engineering, 2012, 46(3): 20-26.)
10. [10]
  [10] KHELIFA A, BENCHEHIDA L, DERRICHE Z. Adsorption of carbon dioxide by X zeolites exchanged with Ni²⁺ and Cr³⁺: Isotherms and isosteric heat[J]. J Colloid Interface Sci, 2004, 278(1): 9-17.
11. [11]
  [11] SIRIWARDANE R V, SHEN M S, FISHER E P. Adsorption of CO₂ on zeolites at moderate temperatures[J]. Energy Fuels, 2005, 19(3): 1153-1159.
12. [12]
  [12] SHAO W, ZHANG L Z, LI L X, LEE R L. Adsorption of CO₂ and N₂ on synthesized NaY zeolite at high temperatures[J]. Adsorpt, 2009, 15(5/6): 497-505.
13. [13]
  [13] 王宝品. 分子筛在烟气净化中的应用[J]. 河北化工, 2012, 35(6): 69-71. (WANG Bao-pin. Application of molecular sieve in the flue gas purification[J]. Hebei Chemical Industry, 2012, 35(6): 69-71.)
14. [14]
  [14] REDDY M K R, XU Z P, LU G Q, COSTA J C D. Layered double hydroxides for CO₂ capture: Structure evolution and regeneration[J]. Ind Eng Chem Res, 2006, 45(22): 7504-7509.
15. [15]
  [15] WANG X P, YU J J, CHENG J, HAO Z P, XU Z P. High-temperature adsorption of carbon dioxide on mixed oxides derived from hydrotalcite-like compounds[J]. Environ Sci Technol, 2008, 42(2): 614-618.
16. [16]
  [16] LEON M, DIAZ E, BENNICI S, VEGA A, ORDONEZ S, AUROUX A. Adsorption of CO₂ on hydrotalcite-derived mixed oxides: Sorption mechanisms and consequences for adsorption irreversibility[J]. Ind Eng Chem Res, 2010, 49(8): 3663-3671.
17. [17]
  [17] FU X, ZHAO N, LI J P, XIAO F K, WEI W, SUN Y H. Carbon dioxide capture by MgO-modified MCM-41 materials[J]. Adsorpt Sci Technol, 2009, 27(6): 593-601.
18. [18]
  [18] LI L, WEN X, FU X, WANG F, ZHAO N, XIAO FK, WEI W, SUN YH. MgO/Al₂O₃ sorbent for CO₂ capture[J]. Energy Fuels, 2010, 24(10): 5773-5780.
19. [19]
  [19] LI L, LI Y, WEN X, WANG F, ZHAO N, XIAO F, WEI W, SUN Y. CO₂ capture over K₂CO₃/MgO/Al₂O₃ dry sorbent in a fluidized bed[J]. Energy Fuels, 2011, 25(8): 3835-3842.
20. [20]
  [20] 李碧,闻霞, 赵宁, 王秀枝, 魏伟, 孙予罕, 任泽厚, 王志杰. 高稳定性介孔MgO-ZrO₂固体碱的制备及其高温CO₂吸附性能[J]. 燃料化学学报, 2010, 38(4): 473-477. (LI Bi, WEN Xia, ZHAO Ning, WANG Xiu-zhi, WEI Wei, SUN Yu-han, REN Ze-hou, WANG Zhi-jie. Preparation of high stability MgO-ZrO2 solid base and its high temperature CO₂ capture properties[J]. Journal of Fuel Chemistry and Technology, 2010, 38(4): 473-477.)
21. [21]
  [21] 闻霞, 孙楠楠, 李碧, 李军平, 王峰, 赵宁, 肖福魁, 魏伟, 孙予罕, 任泽厚, 郭金刚, 王志杰, 李庆, 吴志斌. MgO/Al₂O₃吸附剂对CO₂动态吸附性能的研究[J]. 燃料化学学报, 2010, 38(2): 247-251. (WEN Xia, SUN Nan-nan, LI Bi, LI Jun-ping, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEIWei, SUN Yun-han, REN Ze-hou, GUO Jin-gang, WANG Zhi-jie, LI Qing, WU Zhi-bin. Dynamic adsorption study of CO₂ adsorption by MgO/Al₂O₃[J]. Journal of Fuel Chemistry and Technology, 2010, 38(2): 247-251.)
22. [22]
  [22] VITILLO J G, SAVONNET M, RICCHIARDI G, BORDIGA S. Tailoring metal-organic frameworks for CO₂ capture: The amino effect[J]. Chem Sus Chem, 2011, 4(9): 1281-1290.
23. [23]
  [23] WANG X R, LI H Q, HOU X J. Amine-functionalized metal organic framework as a highly selective adsorbent for CO₂ over CO[J]. J Phys Chem C, 2012, 116(37): 19814-19821.
24. [24]
  [24] HIYOSHI N,YOGO K,YASHIMA T. Adsorption of carbon dioxide on aminosilane-modified mesoporous silica[J]. J Jpn Pet Inst, 2005, 48(1): 29-36.
25. [25]
  [25] KHATRI RA,CHUANG SSC, SOONG Y, GRAY M. Carbon dioxide capture by diamine-grafted SBA-15: A combined fourier transform infrared and mass spectrometry study[J]. Ind Eng Chem Res, 2005, 44(10): 3702-3708.
26. [26]
  [26] WANG L, YANG R T, increasing selective. CO₂ adsorption on amine-grafted SBA-15 by increasing silanol density[J]. J Phys Chem C, 2011, 115(43): 21264-21272.
27. [27]
  [27] YAN X L, ZHANG L, ZHANG Y, YANG G D, YAN Z F. Amine-modified SBA-15: Effect of pore structure on the performance for CO₂ capture[J]. Ind Eng Chem Res, 2011, 50(6): 3220-3226.
28. [28]
  [28] QI G G, FU L L, CHOI B H, GIANNELIS E P. Efficient CO₂ sorbents based on silica foam with ultra-large mesopores[J]. Energy Environ Sci, 2012, 5(6): 7368-7375.
29. [29]
  [29] YUE M B, SUN L B, CAO Y, WANG Y, WANG Z J, ZHU J H. Efficient CO₂ capturer derived from as-synthesized MCM-41 modified with amine[J]. Chem Eur J, 2008, 14(11): 3442-3451.
30. [30]
  [30] XU X C, SONG C S, ANDRESEN J M, MILLER B G, SCARONI A W. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO₂ capture[J]. Energy Fuels, 2002, 16(6): 1463-1469.
31. [31]
  [31] 王林芳, 马磊, 王爱琴, 刘茜, 张涛. 氨基硅烷修饰的SBA-15用于CO₂的吸附[J]. 催化学报, 2007, 28(9): 805-810. (WANG Lin-fang, MA Lei, WANG Ai-qin, LIU Qian, ZHANG Tao. CO₂ adsorption on SBA-15 modified by aminosilane[J]. Chinese Journal of Catalysis, 2007, 28(9): 805-810.)
32. [32]
  [32] 岳明波, 朱建华. 从介孔分子筛原粉研制高效吸附二氧化碳的有机胺介孔复合材料[J]. 催化学报, 2008, 29(10): 1051-1057. (YUE Ming-bo, ZHU Jian-hua. Efficient CO₂ capturer derived from as-synthesized mesoporous silica modified with amines[J]. Chinese Journal of Catalysis, 2008, 29(10): 1051-1057.)
33. [33]
  [33] 付新, 李军平, 赵宁, 肖福魁, 魏伟, 孙予罕. 氨基修饰的介孔分子筛对CO₂的吸附性能[J]. 石油化工, 2008, 37(10): 1021-1025. (FU Xin, LI Jun-ping, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. CO₂ adsorption on mesoporous molecular sieves modified by aminosiliane[J].Petrochemical Technology, 2008, 37(10): 1021-1025.)
34. [34]
  [34] 王亚坤, 赵瑞红, 冯晓霞, 张伟, 李肖飞. 氨基化有序介孔氧化铝合成及吸附CO₂性能研究[J]. 材料导报, 2012, 26(8): 71-74. (WANG Ya-kun,ZHAO Rui-hong,FENG Xiao-xia,ZHANG Wei,LI Xiao-fei. Study on synthesis of amino-functionalized organized mesoporous alumina and their CO₂ adsorption properities[J]. Materials Review, 2012, 26(8): 71-74.)
35. [35]
  [35] 赵会民, 林丹, 杨刚, 淳远, 须沁华. 有机胺修饰具有较大孔径介孔材料的二氧化碳吸附性能[J]. 物理化学学报, 2012, 28(4): 985-992. (ZHAO Hui-min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-hua.Adsorption capacity of carbon dioxide on amine modified mesoporous materials with larger pore sizes[J]. Acta Physico-Chimica Sinica, 2012, 28(4): 985-992.)
36. [36]
  [36] GOEPPERT A, METH S, PRAKASH G K S, OLAH G A. Nanostructured silica as a support for regenerable high-capacity organoamine-based CO₂ sorbents\[J]. Energy Environ Sci, 2010, 3(12): 1949-1960.
37. [37]
  [37] ZHAO D Y, FENG J L, HUO Q S, MELOSH N, FREDRICKSON G H, CHMELKA B F, stucky G D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. Science, 1998, 279(5350): 548-552.
38. [38]
  [38] LIU Y M, SHI J J, CHEN J, YE Q, PAN H, SHAO Z H, SHI Y. Dynamic performance of CO₂ adsorption with tetraethylenepentamine-loaded KIT-6[J]. Microporous Mesoporous Mater, 2010, 134(1/3): 16-21.
39. [39]
  [39] HIYOSHI N, YOGO K, YASHIMA T. Adsorption characteristics of carbon dioxide on organically functionalized SBA-15[J]. Microporous Mesoporous Mater, 2005, 84(1/3): 357-365.
40. [40]
  [40] BADANICOVA M, ZELENAK V. Organo-modified mesoporous silica for sorption of carbon dioxide[J]. Monatsh Chem, 2010, 141(6): 677-684.
1. [1]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
2. [2]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
3. [3]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
4. [4]
  Li Li , Fanpeng Chen , Bohang Zhao , Yifu Yu . Understanding of the structural evolution of catalysts and identification of active species during CO₂ conversion. Chinese Chemical Letters, 2024, 35(4): 109240-. doi: 10.1016/j.cclet.2023.109240
5. [5]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . 非均相催化CO₂与烃类协同催化转化的最新进展. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-0. doi: 10.1016/j.actphy.2025.100073
6. [6]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
7. [7]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
8. [8]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
9. [9]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
10. [10]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
11. [11]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
14. [14]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
15. [15]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
16. [16]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
17. [17]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
18. [18]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
19. [19]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-0. doi: 10.3866/PKU.WHXB202308052
20. [20]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(585)
HTML views(94)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142