Advanced Search

Citation: SUN Ming, YU Lin, NA Xiu-hui, DIAO Gui-qiang, YE Fei. Preparation and catalytic performance of OMS-2/Al2O3/cordierite monolithic catalyst[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1115-1121. shu

Preparation and catalytic performance of OMS-2/Al2O3/cordierite monolithic catalyst

  • 1.

    School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

  • Corresponding author: SUN Ming, 
  • Received Date: 4 January 2013
    Available Online: 7 May 2013

    Fund Project: 广东省自然科学基金(10251009001000003, S2012010009680) (10251009001000003, S2012010009680)广东省科技计划项目(012A030600006) (012A030600006)广东省高等学校学科建设基金(cgzhzd1104)。 (cgzhzd1104)

  • Monolithic catalysts for catalytic combustion of dimethyl ether (DME) were prepared by a dip-coating method using Al2O3/cordierite as support and manganese oxide octahedral molecular sieve (OMS-2) as active component. The effect of different types of organic polymer binder and the coating times of active component on the performance of DME combustion were investigated. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), hydrogen temperature-programmed reduction (H2-TPR) and oxygen temperature-programmed desorption (O2-TPD) techniques. The results showed that the best catalyst was the one using methoxy polyethylene glycol (MPEG) as the coating binder by one-time coating. The active component OMS-2 was in a cluster form and homogeneously dispersed on the surface of the support because of the strong interaction between OMS-2 and Al2O3 coating. The Al2O3 coating could significantly improve the surface area of catalysts, and thus enhance the activity performance. The highest catalytic activity for DME combustion with a complete combustion temperature (t90) of 257 ℃ was obtained.
  • 加载中
    1. [1]

      [1] ADACHI Y, KOMOTO M, WATANABE I, OHNO Y, FUJIMOTO K. Effective utilization of remote coal through dimethyl ether synthesis[J]. Fuel, 2000, 79(3/4): 229-234.

    2. [2]

      [2] GUO X. Progress and prospect of single-step synthesis of DME[J]. China Pet Process PE Technology, 2010, 12(2): 1-7.

    3. [3]

      [3] 高志华, 孙旭伟, 黄伟, 阴丽华, 谢克昌. 不同含量CO2热处理气氛对完全液相法制备二甲醚催化剂性能的影响[J]. 燃料化学学报, 2008, 36(4): 503-507. (GAO Zhi-hua, SUN Xu-wei, HUANG Wei, YIN Li-hua, XIE Ke-chang. Effect of heat treatment atmosphere with the different content of CO2 on the performance of DME catalysts prepared by the complete liquid-phase technology[J]. Journal of Fuel Chemistry and Technology, 2008, 36(4): 503-507.)

    4. [4]

      [4] 马俊国, 葛庆杰, 马现刚, 徐恒泳. 浆态床反应器中生物质合成气合成二甲醚的研究[J]. 燃料化学学报, 2012, 40(7): 843-847. (MA Jun-guo, GE Qing-jie, MA Xian-gang, XU Heng-yong. DME synthesis from biomass-derived syngas in a slurry-bed reactor[J]. Journal of Fuel Chemistry and Technology, 2012, 40(7): 843-847.)

    5. [5]

      [5] 许庆利, 蓝平, 周明, 颜涌捷. 生物质间接液化合成燃料二甲醚[J]. 燃料化学学报, 2010, 36(3): 292-296. (XU Qing-li, LAN Ping, ZHOU Ming, YAN Yong-jie. Synthesis of fuel dimethyl ether by indirect liquefaction of biomass[J]. Journal of Fuel Chemistry and Technology, 2010, 36(3): 292-296.)

    6. [6]

      [6] SEMELSBERGER T A, BORUP R L, GREENE H L. Dimethyl ether (DME) as an alternative fuel[J]. J Power Sources, 2006, 156(2): 497-511.

    7. [7]

      [7] ARCOUMANIS C, BAE C, CROOKES R, KINOSHITA E.The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: A review[J]. Fuel, 2008, 97(7): 1014-1030.

    8. [8]

      [8] SEROV A, KWAK C. Progress in development of direct dimethyl ether fuel cells[J]. Appl Catal B: Environ, 2009, 91(1/2): 1-10.

    9. [9]

      [9] 马忠, 蒋淇忠, 马紫峰. 车载二甲醚重整制氢技术的研究进展[J].化工进展, 2011, 30(2): 292-297. (MA Zhong, JIANG Qi-zhong, MA Zi-fen. Advance in onboard reforming technology of DME to hydrogen[J]. Chemical Industry and Engineering Progress, 2011, 30(2): 292-297.)

    10. [10]

      [10] 李娟, 海航, 闫常峰, 胡蓉蓉, 么志伟, 罗伟民, 郭常青, 李文博. 焙烧温度对二甲醚水蒸气重整制氢Cu/ZnO/Al2O3/Cr2O3+H-ZSM-双功能催化剂性能的影响[J]. 燃料化学学报, 2012, 40(10): 1240-1245. (LI Juan, HAI Hang, YAN Chang-feng, HU Rong-rong, YAO Zhi-wei, LUO Wei-min, GUO Chang-qing, LI Wen-bo. Effect of calcination temperature on properties of Cu/ZnO/Al2O3/Cr2O3+H-ZSM-5 bi-functional catalysts for steam reforming of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 1240-1235.)

    11. [11]

      [11] 孙明, 余林, 余倩, 余坚, 郝志峰. Ce掺杂的OMS-2催化剂上二甲醚催化燃烧性能的研究[J]. 燃料化学学报, 2012, 40(1): 108-115. (SUN Ming, YU Lin, YU Qian, YU Jian, Hao Zhi-feng. Catalytic combustion of dimethyl ether over Ce-doped cryptomelane-type manganese oxide[J]. Journal of Fuel Chemistry and Technology, 2010, 40(1): 108-115.)

    12. [12]

      [12] 董国君, 罗璇, 杨治, 梁涛, 张文平. Cu、Mn、Ce 改性V2O5-WO3/TiO2/堇青石催化剂Urea-SCR脱除NO[J]. 燃料化学学报, 2012, 40(10): 608-614. (DONG Guo-jun, LUO Xuan, YANG Zhi, LIANG Tao, ZHANG Wen-ping. Urea-SCR of NO over V2O5-WO3/TiO2/cordierite catalyst modified with Cu, Mn, Ce[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 608-614.)

    13. [13]

      [13] 那秀辉, 余 林, 孙 明, 刁贵强, 杨霞卿, 史利涛, 潘霁飞. OMS-2/堇青石整体式催化剂的制备及其对二甲醚燃烧的催化性能[J]. 催化学报, 2010, 31(8): 1019-1024. (NA Xiu-hui, YU Lin, SUN Ming, DIAO Gui-qiang, YANG Xia-qing, SHI Li-tao, PAN Ji-fe. Preparation of OMS-2/cordierite monolithic catalysts and their catalytic performance for dimethyl ether combustion[J]. Chinese Journal of Catalysis, 2010, 38(01): 108-115.)

    14. [14]

      [14] ARENA F, TORRE T, RAIMONDO C, PARMALIANA A. Structure and redox properties of bulk and supported manganese oxide catalysts[J]. Phys Chem Chem Phys, 2001, 3(10): 1911-1917.

    15. [15]

      [15] ETTIREDDY P R, ETTIREDDY N, MAMEDOV S, BOOLCHAND P, SMIRNIOTIS P G.. Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3[J]. Appl Catal B: Environ, 2007, 96(1/2): 123-134.

    16. [16]

      [16] SANTOS V P, PEREIRA M F R, RFO J J M, FIGUEIREDO J L. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds[J]. Appl Catal B: Environ, 2010, 99(1/2): 353-363.

    17. [17]

      [17] 胡蓉蓉, 程易, 谢兰英, 王德峥. 掺Ag对氧化锰八面体分子筛催化CO氧化性能的影响[J]. 催化学报, 2007, 28(5): 463-468. (HU Rong-rong, CHENG Yi, XIE Lan-ying, WANG De-zheng. Effect of doped Ag on performance of manganese oxide octahedral molecular sieve for CO oxidation[J]. Chinese Journal of Catalysis, 2007, 28(5): 463-468.)

  • 加载中
    1. [1]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    2. [2]

      Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO2 Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028

    3. [3]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    4. [4]

      Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029

    5. [5]

      Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398

    6. [6]

      Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

    7. [7]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    8. [8]

      Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-0. doi: 10.3866/PKU.WHXB202312024

    9. [9]

      Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    10. [10]

      Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni2P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045

    11. [11]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    12. [12]

      Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

    13. [13]

      Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071

    14. [14]

      Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO4. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104

    15. [15]

      Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040

    16. [16]

      Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003

    17. [17]

      Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086

    18. [18]

      Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    19. [19]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    20. [20]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(514)
  • HTML views(56)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return