Citation: XU Bing-qing, ZHANG Xiao-qing, LONG Hua-li, SHANG Shu-yong, YIN Yong-xiang. Hydrogen making from steam-carbon reaction catalyzed by K₂CO₃ with light irradiation heating[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1102-1107. shu

Hydrogen making from steam-carbon reaction catalyzed by K₂CO₃ with light irradiation heating

1.
1. Center of Plasma Application, School of Chemical Engineering, Sichuan University, Chengdu 610065, China;

Corresponding author: SHANG Shu-yong, YIN Yong-xiang,
Received Date: 15 January 2013
Available Online: 4 March 2013
Fund Project: 国家自然科学基金(11075113)。 (11075113)

With the simulated solar reaction system irradiated by Xenon lamp, an experiment of hydrogen making from steam-carbon reaction catalyzed by K₂CO₃ was carried out at about 700 ℃. It is found that the rate of hydrogen production with catalysts is 10 times more than that without catalysts, and there is no obvious difference in the rate of hydrogen production with the catalyst content from 10% to 20%. The oxygen-transfer mechanism for hydrogen making from steam-carbon reaction catalyzed by K₂CO₃ was discussed in detail, which was used to explain the unbalanced phenomenon of hydrogen and oxygen in reaction product. The efficiency of light energy conversion to chemical energy reaches to 13.12% in the experiment, which is better than that of photovoltaic method(10.85%). Some approaches for improving the energy conversion efficiency were proposed.
- concentrated solar power,
- steam-carbon catalytic gasification,
- catalytic mechanism,
- energy conversion efficiency,
- hydrogen
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrogen making from steam-carbon reaction catalyzed by K2CO3 with light irradiation heating

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通讯作者: 陈斌, bchen63@163.com

Hydrogen making from steam-carbon reaction catalyzed by K₂CO₃ with light irradiation heating