Citation: CHANG Jin-yu, LIAO Jun-jie, ZHANG Yan-jun, FAN Li-jun, MA Lin, BAO Wei-ren, CHANG Li-ping. Effect of operation parameters on adsorption of thiophene from benzene over CeY sorbent[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1092-1096. shu

Effect of operation parameters on adsorption of thiophene from benzene over CeY sorbent

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State Key Laboratory Breeding Base of Coal Science and Technology Co-founded by Shanxi Province and the Ministry of Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: CHANG Li-ping,
Received Date: 13 November 2012
Available Online: 11 February 2013
Fund Project: 国家自然科学基金(51242003, 51372161) (51242003, 51372161)太原市科技局资助(110148085) (110148085)山西省研究生优秀创新项目(20113032) (20113032)山西省回国留学人员科研资助(2012-0039)。 (2012-0039)

The effect of operation parameters, such as particle size of the CeY sorbent, space velocity, and concentration of the solution and temperature of the fixed bed, on the adsorption of thiophene from benzene was investigated. The results show that this effect can be ascribed to the change of the inner and external diffusion process of the mass transfer resistance and the adsorption type, which are affected by those operation parameters respectively. The suitable operation parameters were the particle sizes of 0.2~0.3 mm, space velocity of the solution of 0.85 h^-1. At the conditions of room temperature and atmospheric pressure, CeY sorbent can entirely remove the thiophene from benzene with the breakthrough time and adsorption capacity of thiophene of above 400 min and 4.61 mg/g in the benzene containing thiophene 500 mg/L, respectively.
- CeY sorbent,
- thiophene,
- benzene,
- adsorption,
- operation parameter
1. [1]
  [1] 陈艳珍. 吸附法脱除焦化苯中噻吩的研究[D]. 太原: 太原理工大学, 2008. (CHEN Yan-zhen. Research on adsorption of thiophene in cooking benzol[D]. Taiyuan: Taiyuan University of Technology, 2008.)
2. [2]
  [2] 何建平, 李辉. 炼焦化学产品回收技术[M]. 北京: 化学工业出版社, 2006: 221-226. (HE Jian-ping, LI Hui. Coking chemical products recovery technology[M]. Beijing: Chemical Industry Press, 2006: 221-226.)
3. [3]
  [3] 程时富, 安莹, 司晓娟, 付贤磊, 高国华. Ti-TWW分子筛催化叔丁基过氧化氢氧化脱硫[J]. 燃料化学学报, 2011, 39(10): 771-775. (HE Shi-fu, AN Ying, SI Xiao-juan, FU Xian-lei, GAO Guo-hua. Oxidative desulfurization of diesel oil over Ti-MWW catalyst with TBHP as oxidant[J]. Journal of Fuel Chemistry and Technology, 2011, 39(10): 771-775.)
4. [4]
  [4] KONG L, LI G, WANG X, WANG Y. Thiophene oxidative over titanium silicate using hydrogen peroxide[J]. Chin J Catal, 2004, 25(2): 89-90.
5. [5]
  [5] KONG L, LI G, WANG X, WU B. Oxidative desulfurization of organic sulfur in gasoline over Ag/TS-1[J]. Energy Fuels, 2006, 20(3): 896-902.
6. [6]
  [6] SHIRAISHI Y, HIRRAI T, KOMASAWA I. Oxidative desulfurization process for light oil using titanium silicate molecular sieve catalysts[J]. J Chem Eng Jpn, 2002, 35(1/2): 1305-1310.
7. [7]
  [7] HULEA V, FAJULA F, BOUSQUET J. Mild oxidative desulfurization with H₂O₂ over Ti-containing molecular sieves-A very efficient method for removing aromatic sulfur compounds from fuels[J]. J Catal, 2001, 198(1): 179-186.
8. [8]
  [8] 廖俊杰, 王文博, 王海堂, 靳庆麦, 常丽萍. 焦化苯中噻吩类硫化物脱除的研究[J]. 现代化工, 2009, 29(S1): 219-221. (LIAO Jun-jie, WANG Wen-bo, WANG Hai-tang, JIN Qing-mai, CHANG Li-ping. Study on removing thiophene-like sulfides from cooking benzene[J]. Modern Chemical Industry, 2009, 29(S1): 219-221.)
9. [9]
  [9] SONG C S. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel[J]. Catal Today, 2003, 86: 211-263.
10. [10]
  [10] YANG R T. HERN A NDEZ-MALDONADO A J, Yang F Y. Desulfurization of transportataion fuels with zeolites under ambient conditions[J]. Science, 2003, 301(5629): 79-80.
11. [11]
  [11] HERNÁNDEZ-MALDONADO A J, YANG R T. Desulfurization of diesel fuels by adsorption via SymbolpA@-complexation with vapor-phase exchanged Cu(I)-Y zeolites[J]. J Am Chem Soc, 2004, 126(4): 992-993.
12. [12]
  [12] LIN L G, ZHANG Y Z, ZHANG H Y, LU F W. Adsorption and solvent desorption behavior of ion-exchanged modified Y zeolites for sulfur removal and for fuel cell applications[J]. J Colloid Interface Sci, 2011, 360(2): 753-759.
13. [13]
  [13] LIAO J J, WANG W B, ZHANG Y J, XIE Y Y, CHANG L P, BAO W R. Adsorptive removal of thiophene from benzene by NaY zeolite ion exchanged with Ce(IV)[J]. Sep Sci Technol, 2012, 47(13): 1880-1885.
14. [14]
  [14] HASHIMOTO K, MATZUO K, KOMINAMI H, KERA Y. Cerium oxides incorporated into zeolite cavities and their reactivity[J]. J Chem Soc, Faraday Trans, 1997, 20: 3729-3732.
15. [15]
  [15] LIAO J J, ZHANG Y J, WANG W B, Li X L, CHANG L P. Detection of thiophene and CS₂ in coking benzene using GC-FPD[C]. 2011 International Conference on Computer Distributed Control and Intelligent Environmental Monitoring (CDCIEM 2011). 2011: 44-47.
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沈阳化工大学材料科学与工程学院沈阳 110142