Citation: MA Xian-gang, GE Qing-jie, XU Heng-yong. Direct synthesis of liquefied petroleum gas from syngas over hybrid catalyst[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(8): 1010-1014. shu

Direct synthesis of liquefied petroleum gas from syngas over hybrid catalyst

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics,Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: GE Qing-jie,
Received Date: 1 June 2013
Available Online: 23 June 2013
Fund Project: 国家科技支撑计划(2011BAD22B06). (2011BAD22B06)

Direct synthesis of liquefied petroleum gas (LPG) from syngas could be realized over a hybrid catalyst consisting of methanol synthesis catalyst and zeolite. In this work, SAPO-5 was chosen consciously for LPG synthesis, because its pore size (0.73 nm×0.73 nm) is similar to that of Y zeolite. As expected, the corresponding hybrid catalyst of SAPO-5 exhibits high selectivity (73.0%) to LPG, which confirms the previous deduction that large pore size of zeolite was beneficial to LPG synthesis. In addition, as one step process of syngas to LPG, the formation of hydrocarbons from methanol or dimethyl ether follows the hydrocarbon pool mechanism.
- LPG,
- syngas,
- hybrid catalyst,
- SAPO-5
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沈阳化工大学材料科学与工程学院沈阳 110142