Citation: MA Xian-gang, GE Qing-jie, XU Heng-yong. Direct synthesis of liquefied petroleum gas from syngas over hybrid catalyst[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(8): 1010-1014. shu

Direct synthesis of liquefied petroleum gas from syngas over hybrid catalyst

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics,Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: GE Qing-jie,
Received Date: 1 June 2013
Available Online: 23 June 2013
Fund Project: 国家科技支撑计划(2011BAD22B06). (2011BAD22B06)

Direct synthesis of liquefied petroleum gas (LPG) from syngas could be realized over a hybrid catalyst consisting of methanol synthesis catalyst and zeolite. In this work, SAPO-5 was chosen consciously for LPG synthesis, because its pore size (0.73 nm×0.73 nm) is similar to that of Y zeolite. As expected, the corresponding hybrid catalyst of SAPO-5 exhibits high selectivity (73.0%) to LPG, which confirms the previous deduction that large pore size of zeolite was beneficial to LPG synthesis. In addition, as one step process of syngas to LPG, the formation of hydrocarbons from methanol or dimethyl ether follows the hydrocarbon pool mechanism.
- LPG,
- syngas,
- hybrid catalyst,
- SAPO-5
1. [1]
  [1] ASAMI K, ZHANG Q, LI X, ASAOKA S, FUJIMOTO K. Selective synthesis of LPG from synthesis gas[J]. Stud Surf Sci Catal, 2004, 147: 427-432.
2. [2]
  [2] ZHANG Q, LI X, ASAMI K, ASAOKA S, FUJIMOTO K. A highly stable and efficient catalyst for direct synthesis of LPG from syngas[J]. Catal Lett, 2005, 102(1/2): 51-55.
3. [3]
  [3] ZHANG Q, LI X, ASAMI K, ASAOKA S, FUJIMOTO K. Direct synthesis of LPG fuel from syngas with the hybrid catalyst based on modified Pd/SiO₂ and zeolite[J]. Catal Today, 2005, 104(1): 30-36.
4. [4]
  [4] GE Q, LI X, FUJIMOTO K. Application of modified beta zeolite in the direct synthesis of LPG from syngas[J]. Stud Surf Sci Catal, 2007, 170: 1260-1266.
5. [5]
  [5] GE Q, LI X, KANEKO H, FUJIMOTO K. Direct synthesis of LPG from synthesis gas over Pd-Zn-Cr/Pd-beta hybrid catalysts[J]. J Mol Catal A: Chem, 2007, 278(1/2): 215-219.
6. [6]
  [6] GE Q, LIAN Y, YUAN X, LI X, FUJIMOTO K. High performance Cu-ZnO/Pd-beta catalysts for syngas to LPG[J]. Catal Commun, 2008, 9(2): 256-261.
7. [7]
  [7] 吕永兴, 王铁军, 李宇萍, 吴创之, 马隆龙. 生物质合成气一步法合成LPG的实验研究[J]. 燃料化学学报, 2008, 36(2): 246-249. (Lv Yong-xing, Wang Tie-jun, Li Yu-ping, Wu Chuang-zhi, Ma Long-long. Direct synthesis of liquefied petroleum gas from biomass synthesis gas[J]. Journal of Fuel Chemistry and Technology, 2008, 36(2): 246-249.)
8. [8]
  [8] 马现刚, 葛庆杰, 方传艳, 马俊国, 徐恒泳. 合成气制液化石油气复合催化剂的性能[J]. 催化学报, 2010, 31(12): 1501-1506. (Ma Xian-gang, Ge Qing-jie, Fang Chuan-yan, Ma Jun-guo, Xu Heng-yong. Hybrid catalysts for liquefied petroleum gas synthesis from syngas[J]. Chinese Journal of Catalysis, 2010, 31(12): 1501-1506.)
9. [9]
  [9] MA X, GE Q, FANG C, MA J, XU H. Direct synthesis of LPG from syngas derived from air-POM[J]. Fuel, 2011, 90(5): 2051-2054.
10. [10]
  [10] WANG L, GUO C, YAN S, HUANG X, LI Q. High-silica SAPO-5 with preferred orientation: Synthesis, characterization and catalytic applications[J]. Microporous Mesoporous Mat, 2003, 64(1/3): 63-68.
11. [11]
  [11] ROWNAGHI A A, REZAEI F, HEDLUND J. Yield of gasoline-range hydrocarbons as a function of uniform ZSM-5 crystal size[J]. Catal Commun, 2011, 14(1): 37-41.
12. [12]
  [12] NI Y, SUN A, WU X, HAI G, HU J, LI T, LI G. Preparation of hierarchical mesoporous Zn/HZSM-5 catalyst and its application in MTG reaction[J]. J Nat Gas Chem, 2011, 20(3): 237-242.
13. [13]
  [13] STOCKER M. Methanol-to-hydrocarbons: catalytic materials and their behavior[J]. Microporous Mesoporous Mat, 1999, 29(1/2): 3-48.
14. [14]
  [14] SVELLE S, OLSBYE U, JOENSEN F, BJØRGEN M. Conversion of methanol to alkenes over medium- and large-pore acidic zeolites: Steric manipulation of the reaction intermediates governs the ethene/propene product selectivity[J]. J Phys Chem C, 2007, 111(49): 17981-17984.
15. [15]
  [15] OLSBYE U, SVELLE S, BJØRGEN M, BEATO P, JANSSENS T V W, JOENSEN F, BORDIGA S, LILLERUD K P. Conversion of methanol to hydrocarbons: How zeolite cavity and pore size controls product selectivity[J]. Angew Chem Int Edit, 2012, 51(24): 5810-5831.
16. [16]
  [16] SONG W, FU H, HAW J F. Supramolecular origins of product selectivity for methanol-to-olefin catalysis on HSAPO-34[J]. J Am Chem Soc, 2001, 123(20): 4749-4754.
17. [17]
  [17] SVELLE S, JOENSEN F, NERLOV J, OLSBYE U, LILLERUD K P, KOLBOE S, BJØRGEN M. Conversion of methanol into hydrocarbons over zeolite H-ZSM-5: Ethene formation is mechanistically separated from the formation of higher alkenes[J]. J Am Chem Soc, 2006, 128(46): 14770-14771.
18. [18]
  [18] BJØRGEN M, SVELLE S, JOENSEN F, NERLOV J, KOLBOE S, BONINO F, PALUMBO L, BORDIGA S, OLSBYE U. Conversion of methanol to hydrocarbons over zeolite H-ZSM-5: On the origin of the olefinic species[J]. J Catal, 2007, 249(2): 195-207.
19. [19]
  [19] BJØRGEN M, JOENSEN F, LILLERUD K P, OLSBYE U, SVELLE S. The mechanisms of ethene and propene formation from methanol over high silica H-ZSM-5 and H-beta[J]. Catal Today, 2009, 142(1/2): 90-97.
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沈阳化工大学材料科学与工程学院沈阳 110142