Citation: NIU Sheng-li, LI Hui, LU Chun-mei, LIU Meng-qi, HUO Meng-jia. Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(7): 856-861. shu

Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol

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National Engineering Laboratory for Coal-Burning Pollutants Emission Reduction, School of Energy and Power Engineering, Shandong University, Jinan 250061,China

Corresponding author: NIU Sheng-li,
Received Date: 1 June 2013
Available Online: 24 June 2013
Fund Project: 国家自然科学基金(51206098) (51206098) 中国博士后科学基金(2012M511021) (2012M511021) 山东省优秀中青年科学家科技奖励基金(BS2012NJ005). (BS2012NJ005)

The catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol was investigated in terms of catalyst quantity, molar ratio of methanol to oil, reaction temperature, and time. Meanwhile, the catalyst is characterized by thermogravimetric analysis, X-ray fluorescence, X-ray diffraction, nitrogen adsorption and Hammett indicator. After a sequence of pretreatments involving calcination at 800 ℃, hydration at room temperature and activation at 600 ℃, the catalyst mainly consists of calcium oxide, with surface area of 7.28 m²/g and basic strength of 9.8 < H_ < 15.0. The preferred conditions are catalyst percentage of 6%, methanol/oil molar ratio of 12 and reaction time of 2 h at 64 ℃; under these conditions, the transesterification efficiency reaches 90.74%. The catalyst from papermaking white clay exhibits good reusability; after being reused for six times, the transesterification efficiency remains above 88.63% under the preferred condition.
- transesterification,
- papermaking white clay,
- heterogeneous base catalyst,
- glycerol conversion
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沈阳化工大学材料科学与工程学院沈阳 110142