Citation: WANG Yu-gao, WEI Xian-yong, YAN Hong-lei, LIU Jing, LIU Fang-jing, LI Peng, ZONG Zhi-min. Mild oxidation of Jincheng No.15 anthracite[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(7): 819-825. shu

Mild oxidation of Jincheng No.15 anthracite

1.
Key Laboratory of Coal Processing and Efficient Utilization (Ministry of Education), China University of Mining & Technology, Xuzhou 221116, China

Received Date: 16 May 2013
Available Online: 12 June 2013
Fund Project: National Basic Research Program of China (973 program, 2011CB201302) (973 program, 2011CB201302) National Natural Science Foundation of China (20936007, 50974121, 51074153 and 21276268) (20936007, 50974121, 51074153 and 21276268) the Fund from National Natural Science Foundation of China for Innovative Research Group (51221462) (51221462) Strategic Chinese-Japanese Joint Research Program (2013DFG60060) (2013DFG60060)

Jincheng No.15 anthracite (J15A) was subjected to ruthenium ion-catalyzed oxidation to characterize its structural feature. The results show that J15A is abundant in peri-condensed aromatic structure. The NaOCl oxidation of J15A promoted by pretreatment with H₂O₂ was conducted under mild conditions to produce benzene polycarboxylic acids (BPCAs). The pretreatment with H₂O₂ is proved to enhance the yields of BPCAs. It is potential to obtain BPCAs in high yield and selectivity by NaOCl oxidation of pretreated J15A with H₂O₂.
- anthracite,
- benzene polycarboxylic acid,
- mild oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142