Advanced Search

Citation: HU Jiang-liang, SUN Tian-jun, REN Xin-yu, CHANG Li-ping, WANG Shu-dong. Separation of CH4/N2 on ZIF-8 adsorbent and its thermodynamic properties[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 754-760. shu

Separation of CH4/N2 on ZIF-8 adsorbent and its thermodynamic properties

  • 1.

    1. Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Ministry of Education and Shanxi Province, Taiyuan 030024, China;

  • Corresponding author: WANG Shu-dong, 
  • Received Date: 14 November 2012
    Available Online: 21 January 2013

    Fund Project: 中国科学院知识创新工程创新基金项目(K20110812)。 (K20110812)

  • With triethylamine (TEA) as structure directing agent, ZnSO4 as metal ion source and water as the solvent, zeolitic imidazolate framework-8 (ZIF-8) adsorbent was prepared by hydrothermal synthesis and used in the separation and enrichment of exhausted coal-bed methane. XRD, physical adsorption, dynamic adsorption equilibrium and inverse gas chromatography (IGC) methods were employed to characterize the physical structure, chemical stability, adsorption and separation performance of the ZIF-8 adsorbent; the adsorption thermodynamics of CH4 and N2 on it was also considered. The results indicated that ZIF-8 structure is stable in the acid, alkali and strongly polarized solvent. At 298 K, the separation factor of the ZIF-8 adsorbent towards CH4/N2 is up to 3.4, which is comparable to activated carbon; however, ZIF-8 should be more promising in practical application, because the adsorption heat over it is about 20% lower than that over activated carbon.
  • 加载中
    1. [1]

      [1] 鲜学福. 我国煤层气开采利用现状及其产业化展望[J]. 重庆大学学报(自然科学版), 2000, 23(z1): 1-5. (XIAN Xue-fu. The present situation of coal-bed methane mining and utilization in our country and looking forward to its industrialization[J]. Journal of Chongqing University(Natural Science Edition), 2000, 23(z1): 1-5.)

    2. [2]

      [2] 杨江峰, 赵强, 于秋红, 董晋湘, 李晋平. 煤层气回收及CH4/N2分离PSA材料的研究进展[J]. 化工进展, 2011, 30(4): 793-801. (YANG Jiang-feng, ZHAO Qiang, YU Qiu-hong, DONG Jin-xiang, LI Jin-ping. Progress of recovery of coal bed methane and adsorption materials for separation of CH4/N2 by pressure swing adsorption[J]. Chemical Industry and Engineering Progress, 2011, 30(4): 793-801.)

    3. [3]

      [3] 冯明, 陈力, 徐承科, 李春凯. 中国煤层气资源与可持续发展战略[J]. 资源科学, 2007, 29(3): 100-104. (FENG Ming, CHEN Li, XU Cheng-ke, LI Chun-kai. Coal-bed methane resources and sustainable development in China[J]. Resources Science, 2007, 29(3): 100-104.)

    4. [4]

      [4] 辜敏, 刘克万, 鲜学福, 曾来, 姚伟静. 烟煤制备成型活性炭及其PSA浓缩CH4/N2中CH4的性能研究[J]. 功能材料, 2010, 2(41): 204-207. (GU Min, LIU Ke-wan, XIAN Xue-fu, ZENG Lai, YAO Wei-jing. Study on the preparation of shaped active carbon by bituminous coal and its performance for concentrating methane from CH4/N2 by pressure swing adsorption[J]. Journal of Functional Materials, 2010, 2(41): 204-207.)

    5. [5]

      [5] 刘漫, 鲁晓明, 冯俊鹤, 韩丽. 美国沸石咪唑酯骨架结构材料的研究进展[J]. 现代化工, 2008, 28(6): 81-84. (LIU Man, LU Xiao-ming, FENG Jun-he, HAN Li. Research advances in zeolitic imidazolate frameworks(ZIFs) in America [J]. Modern Chemical Industry, 2008, 28(6): 81-84.)

    6. [6]

      [6] HUANG X C, LIN Y Y, ZHANG J P, CHEN X M. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies[J]. Angew Chem Int Ed, 2006, 45(10): 1557-1559.

    7. [7]

      [7] CRAVILLON J, MÜNZER S, LOHMEIER S J, FELDHOFF A, HUBER K, WIEBCKE M. Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework[J]. Chem Mater, 2009, 21(8): 1410-1412.

    8. [8]

      [8] AMELOOT R, GOBECHIYA E, UJI-I H, MARTENS J A, HOFKENS J, ALAERTS L, SELS B F, DEVOS D E. Direct patterning of oriented metal-organic framework crystals via control over crystallization kinetics in clear precursor solutions[J]. Adv Mater, 2010, 22(24): 2685-2688.

    9. [9]

      [9] PAN Y C, LIU Y Y, ZENG G F, ZHAO L, LAI Z P. Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system[J]. Chem Commun, 2011, 47(7): 2071-2073.

    10. [10]

      [10] PARK K S, NI Z, CÔTÉ A P, CHOI J Y, HUANG R, URIBE-ROMO F J, CHAE H K, O'KEEFFE M, YAGHI O M. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J]. P Natl Acad Sci USA, 2006, 103(27): 10186-10191.

    11. [11]

      [11] KÜSGENS P, ROSE M, SENKOVSKA I, FRDE H, HENSCHEL A, SIEGLE S, KASKEL S. Characterization of metal-organic frameworks by water adsorption[J]. Micropor Mesopor Mater, 2009, 120(3): 325-330.

    12. [12]

      [12] RUTHVEN D M. Principles of adsorption and adsorption processes[M]. New York: Wiley, 1984: 275-290.

    13. [13]

      [13] DABROWSKI A. Adsorption-from theory to practice[J]. Adv Colloid Interface Sci, 200l, 93(1-3): 135-224.

    14. [14]

      [14] 庞先勇, 田取珍, 贾兆昌, 刘刚, 李瑞丰. N2和CO在5A分子筛上吸附的气相色谱研究[J]. 化学工程, 2007, 35(2): 48-51. (PANG Xian-yong, TIAN Qu-zhen, JIA Zhao-chang, LIU Gang, LI Rui-feng. Adsorption thermodynamics of N2 and CO on 5A zeolite with gas chromatography[J]. Chemical Engineering(China), 2007, 35(2): 48-51.)

    15. [15]

      [15] KATSANOS N A, THEDE R, ROUBANI-KALANTZOPOULOU F. Diffusion, adsorption and catalytic studies by gas chromatography[J]. J Chromatogr A, 1998, 795(2): 133-184.

    16. [16]

      [16] YILMAZ B, TRUKHAN N, MVLLER U. Industrial outlook on zeolites and metal organic frameworks[J]. Chin J Catal, 2012, 33(1): 3-10.

    17. [17]

      [17] GROSS A F, SHERMAN E, VAJO J J. Aqueous room temperature synthsis of cobalt and zinc sodalite zeolitic imidizolate frameworks[J]. Dalton Trans, 2012, 41(18): 5458-5460.

    18. [18]

      [18] 王玉新, 苏伟, 周亚平. 不同结构活性炭对CO2、CH4、N2及O2的吸附分离性能[J]. 化工进展, 2009, 28(2): 206-209. (WANG Yu-xin, SU Wei, ZHOU Ya-ping. Adsorptive separation properties of activated carbons with different pore structures for CO2, CH4, N2 and O2[J]. Chemical Industry and Engineering Progress, 2009, 28(2): 206-209.)

    19. [19]

      [19] NIST Chemistry WebBook. National institute of standards and technology[OB]. Gaithersburg, http://webbook.nist.gov, 2001.

    20. [20]

      [20] WU H, ZHOU W, YILDIRIM T. Methane sorption in nanoporous metal-organ frameworks and first-order phase transition of confined methane[J]. J Phys Chem C, 2009, 113(7): 3029-3035.

  • 加载中
    1. [1]

      Min ZHU , Yuxin WANG , Xiao LI , Yaxu XU , Junwen ZHU , Zihao WANG , Yu ZHU , Xiaochen HUANG , Dan XU , Monsur Showkot Hossain Abul . Construction of AgVO3/ZIF-8 composites for enhanced degradation of tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 994-1006. doi: 10.11862/CJIC.20240392

    2. [2]

      Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490

    3. [3]

      Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO2 nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751

    4. [4]

      Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385

    5. [5]

      Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835

    6. [6]

      Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889

    7. [7]

      Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075

    8. [8]

      Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

    9. [9]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

    10. [10]

      Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060

    11. [11]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    12. [12]

      Fang Niu ,  Rong Li ,  Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102

    13. [13]

      Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408

    14. [14]

      Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430

    15. [15]

      Fei Xie ,  Chengcheng Yuan ,  Haiyan Tan ,  Alireza Z. Moshfegh ,  Bicheng Zhu ,  Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O2的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013

    16. [16]

      Xueqi Yang ,  Juntao Zhao ,  Jiawei Ye ,  Desen Zhou ,  Tingmin Di ,  Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO2吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074

    17. [17]

      Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276

    18. [18]

      Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061

    19. [19]

      Qianqian Zhong ,  Yucui Hao ,  Guotao Yu ,  Lijuan Zhao ,  Jingfu Wang ,  Jian Liu ,  Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013

    20. [20]

      Xinyu Yin ,  Haiyang Shi ,  Yu Wang ,  Xuefei Wang ,  Ping Wang ,  Huogen Yu . Spontaneously Improved Adsorption of H2O and Its Intermediates on Electron-Deficient Mn(3+δ)+ for Efficient Photocatalytic H2O2 Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(519)
  • HTML views(105)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return