Advanced Search

Citation: FENG Ming, DOU Zhe, XU Xiu-feng. Catalytic decomposition of N2O over Zn-Fe spinel oxides[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 729-734. shu

Catalytic decomposition of N2O over Zn-Fe spinel oxides

  • 1.

    School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China

  • Corresponding author: XU Xiu-feng, 
  • Received Date: 16 February 2013
    Available Online: 23 April 2013

    Fund Project: The Research Project from Department of Science and Technology of Shandong Province (2012GGA01012) (2012GGA01012)the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry (2004-527). (2004-527)

  • Zn-Fe spinel oxides were prepared by co-precipitation method and used as the catalysts in N2O decomposition in the presence of oxygen; the effects of spinel oxide composition, calcination temperature, and K doping on their catalytic activity were investigated. In addition, the Zn-Fe spinel oxides were characterized by N2 physisorption, X-ray diffraction and H2-TPR techniques. The results indicated that the Zn-Fe spinel oxides are active in N2O decomposition in the presence of oxygen; over the Zn0.8Fe0.2Fe2O4-400 catalyst with the optimized composition and calcined at 400℃, the conversions of N2O in the absence and in the presence of steam achieve 63.5% and 22.2%, respectively, after reaction at 500℃ for 10h, which are much higher than those over Fe3O4. However, the K-doped Zn-Fe spinel oxides exhibit lower activity than the bare Zn-Fe oxide, as K doping may lead to a substantial decrease of surface area and the migration of potassium crystallites to FeOx surface that will inhibit the ferric species from reduction and active oxygen species from removal from the catalyst surface.
  • 加载中
    1. [1]

      [1] CHANG K S, SONG H, PARK Y S, WOO J W. Analysis of N2O decomposition over fixed bed mixed metal oxide catalysts made from hydrotalcite-type precursors[J]. Appl Catal A: Gen, 2004, 273(1-2): 223-231.

    2. [2]

      [2] CHENG H K, HUANG Y Q, WANG A Q, LI L, WANG X D, ZHANG T. N2O decomposition over K-promoted Co-Al catalysts prepared from hydrotalcite-like precursors[J]. Appl Catal B: Environ, 2009, 89(3-4): 391-397.

    3. [3]

      [3] OBALOVÁ L, MANIAK G, KARÁSKOVÁ K, KOVANDA F, KOTARBA A. Electronic nature of potassium promotion effect in Co-Mn-Al mixed oxide on the catalytic decomposition of N2O[J]. Catal Commun, 2011, 12(12): 105-1058.

    4. [4]

      [4] OBALOVÁ L, FÍLA V. Kinetic analysis of N2O decomposition over calcined hydrotalcites[J]. Appl Catal B: Environ, 2007, 70(1/4): 353-359.

    5. [5]

      [5] WU H P, QIAN Z Y, XU X L, XU X F. N2O decomposition over K-promoted NiAl mixed oxides derived from hydrotalcite-like compounds[J]. J Fuel Chem Technol, 2011, 39(2): 115-121.

    6. [6]

      [6] WU H P, LI W J, GUO L, PANY F, XU X F. The effect of promoter species and precursors on catalytic activity of alkali metal promoted NiAl mixed oxides for N2O decomposition[J]. J Fuel Chem Technol, 2011, 39(7): 550-555.

    7. [7]

      [7] PAN Y F, FENG M, CUI X, XU X F. Catalytic activity of alkali metal doped Cu-Al mixed oxides for N2O decomposition in the presence of oxygen[J]. J Fuel Chem Technol, 2012, 40(5): 601-607.

    8. [8]

      [8] RUSSO N, FINO D, SARACCO G, SPECCHIA V. N2O catalytic decomposition over various spinel-type oxides[J]. Catal Today, 2007, 119(1-4): 228-232.

    9. [9]

      [9] CHELLAM U, XU Z P, ZENG H C. Low-temperature synthesis of MgxCo1-xCo2O4 spinel catalysts for N2O decomposition [J]. Chem Mater, 2000, 12(3): 650-658.

    10. [10]

      [10] YAN L, REN T, WANG X L, GAO Q, JI D, SUO J S. Excellent catalytic performance of ZnxCo1-xCo2O4 spinel catalysts for the decomposition of nitrous oxide[J]. Catal Commun, 2003, 4(10): 505-509.

    11. [11]

      [11] YAN L, REN T, WANG X L, JI D, SUO J S. Catalytic decomposition of N2O over MxCo1-xCo2O4 (M = Ni, Mg) spinel oxides[J]. Appl Catal B: Environ, 2003, 45(2): 85-90.

    12. [12]

      [12] AMROUSSE R, KATSUMI T. Substituted ferrite MxFe1-xFe2O4 (M=Mn, Zn) catalysts for N2O catalytic decomposition processes[J]. Catal Commun, 2012, 26: 194-198.

  • 加载中
    1. [1]

      Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

    2. [2]

      Qin Hu ,  Liuyun Chen ,  Xinling Xie ,  Zuzeng Qin ,  Hongbing Ji ,  Tongming Su . Ni掺杂构建电子桥及激活MoS2惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

    3. [3]

      Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    4. [4]

      Wei Zhong ,  Dan Zheng ,  Yuanxin Ou ,  Aiyun Meng ,  Yaorong Su . K原子掺杂高度面间结晶的g-C3N4光催化剂及其高效H2O2光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

    5. [5]

      Heng Chen ,  Longhui Nie ,  Kai Xu ,  Yiqiong Yang ,  Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C3N4纳米片及其高效光催化产H2O2. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019

    6. [6]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    7. [7]

      Xuejiao Wang ,  Suiying Dong ,  Kezhen Qi ,  Vadim Popkov ,  Xianglin Xiang . Photocatalytic CO2 Reduction by Modified g-C3N4. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

    8. [8]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    9. [9]

      Lina Guo ,  Ruizhe Li ,  Chuang Sun ,  Xiaoli Luo ,  Yiqiu Shi ,  Hong Yuan ,  Shuxin Ouyang ,  Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002

    10. [10]

      Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

    11. [11]

      Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

    12. [12]

      Yu Dai ,  Xueting Sun ,  Haoyu Wu ,  Naizhu Li ,  Guoe Cheng ,  Xiaojin Zhang ,  Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052

    13. [13]

      Qianqian Liu ,  Xing Du ,  Wanfei Li ,  Wei-Lin Dai ,  Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb2O6/Nitrogen-Enriched C3N5 S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016

    14. [14]

      Zhao Lu ,  Hu Lv ,  Qinzhuang Liu ,  Zhongliao Wang . Modulating NH2 Lewis Basicity in CTF-NH2 through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005

    15. [15]

      Jingzhuo Tian ,  Chaohong Guan ,  Haobin Hu ,  Enzhou Liu ,  Dongyuan Yang . Waste plastics promoted photocatalytic H2 evolution over S-scheme NiCr2O4/twinned-Cd0.5Zn0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-. doi: 10.1016/j.actphy.2025.100068

    16. [16]

      Guoqiang Chen ,  Zixuan Zheng ,  Wei Zhong ,  Guohong Wang ,  Xinhe Wu . 熔融中间体运输导向合成富氨基g-C3N4纳米片用于高效光催化产H2O2. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021

    17. [17]

      Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

    18. [18]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    19. [19]

      Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

    20. [20]

      Yi Yang ,  Xin Zhou ,  Miaoli Gu ,  Bei Cheng ,  Zhen Wu ,  Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn2S4 photocatalyst for H2O2 production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(503)
  • HTML views(53)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return