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Citation: YU Chang-lin, HU Jiu-biao, YANG Kai, ZHOU Xiao-chun. Effects of preparation methods on the catalytic performance of Ni/CeO2-Al2O3 catalyst in methane partial oxidation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 722-728. shu

Effects of preparation methods on the catalytic performance of Ni/CeO2-Al2O3 catalyst in methane partial oxidation

  • 1.

    1. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China;

  • Corresponding author: YU Chang-lin, 
  • Received Date: 21 November 2012
    Available Online: 4 February 2013

    Fund Project: 国家自然科学基金(21067004,21263005) (21067004,21263005)江西省教育厅科技基金(GJJ12344) (GJJ12344)江西省青年科学家培养项目(20122BCB23015) (20122BCB23015)国家留学基金(2011836054)。 (2011836054)

  • A series of Ni/CeO2-Al2O3 catalysts were prepared by the methods of impregnation-precipitation, hydrothermal synthesis, co-precipitation and citric acid complexation. The effects of preparation method on the physical structures and catalytic performance of the resultant catalysts in partial oxidation of methane (POM) were investigated. The fresh and spent catalysts were characterized by N2 physical adsorption, X-ray diffraction (XRD), temperature-programmed reduction by hydrogen (H2-TPR), temperature programmed desorption of ammonia (NH3-TPD) and thermogravimetry (TG) analysis. The results show that Ni/CeO2-Al2O3 prepared by impregnation-precipitation method exhibits the lowest activity and selectivity to H2 and CO; the highest catalytic performance is achieved by the catalyst prepared through citric acid complexation. The Ni/CeO2-Al2O3 catalyst prepared by citric acid complexation has the largest specific surface area and the smallest CeO2 crystals with good dispersion. Both Ni species and NiAl2O4 spinel in Ni/CeO2-Al2O3 prepared by citric acid complexation are prone to being reduced to metal Ni, which can produce more active sites for methane partial oxidation reaction. There is more acidic sites and deposited carbon over the catalyst prepared by citric acid complexation; however, taking its high activity into account, its stability is relatively high with low carbon deposition rate.
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