Citation: LIU Li-hua, LIU Shu-qun, CHAI Yong-ming, LIU Yun-qi, LIU Chen-guang. Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 698-702. shu

Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline

1.
1. School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China;

Corresponding author: LIU Li-hua,
Received Date: 1 March 2013
Available Online: 29 April 2013
Fund Project: Major State Basic Research Development Program of China (973 Program,2010CB226905) (973 Program,2010CB226905) the Natural Science Foundation of Educational Committee of Anhui Province (KJ2013B243) (KJ2013B243) the Youth Foundation of Huaibei Normal University (2012xq47, 2013xqz01). (2012xq47, 2013xqz01)

The synergetic effect between Ni₂P/Al₂O₃ and MoS₂/Al₂O₃ catalysts on their performance in the hydrodenitrogenation of quinoline was proved by a simplified experimental design and explained by the remote control model through a migration of hydrogen spillover. The results indicated that the synergism factor of Ni₂P and MoS₂ is slightly higher than that of NiS_x and MoS₂; it decreases with the increase of reaction temperature. Since the spillover hydrogen with Ni₂P can increase the amount of hydrogenation active sites of MoS₂, the hydrogenation rate of 1,2,3,4-tetrahydroquinoline and 5,6,7,8-tetrahydroquinoline to decahydroquinoline over the Ni₂P/Al₂O₃ and MoS₂/Al₂O₃ catalyst system is then greatly enhanced; as a result, Ni₂P is a superior promoter for MoS₂ catalyst for hydrodenitrogenation.
- hydrogen spillover,
- synergetic effect,
- hydrodenitrogenation,
- MoS₂,
- Ni₂P,
- quinoline
1. [1]
  [1] TOPSΦE H, CLAUSEN B S. Importance of Co-Mo-S type structures in hydrodesulfurization[J]. Catal Rev Sci Eng, 1984, 26(3/4): 395-420.
2. [2]
  [2] KARROUA M, MATRALIS H, GRANGE P, DELMON B. Synergy between "NiMoS" and Co₉S₈ in the hydrogenation of cyclohexene and hydrodesulfurization of thiophene[J]. J Catal, 1993, 139(2): 371-374.
3. [3]
  [3] DELMON B. Are solid catalysts successfully emulating enzymes[J]. Chin J Catal, 2010, 26(8): 859-871.
4. [4]
  [4] TOPSΦE H, CLAUSEN B S. Active sites and support effects in hydrodesulfurization catalysts[J]. Appl Catal, 1986, 25(1-2): 273-293.
5. [5]
  [5] TOPSΦE H, HINNEMANN B, NΦRSKOV J K, LAURITSEN J V, BESENBACHER F, HANSEN P L, HYTOFT G, EGEBERG R G, KNUDSEN K G. The role of reaction pathways and support interactions in the development of high activity hydrotreating catalysts[J]. Catal Today, 2005, 107-108: 12-22.
6. [6]
  [6] LAURITSEN J V, KIBSGAARD J, OLESEN G H, MOSES P G, HINNEMANN B, HELVEG S, NΦRSKOV J K, CLAUSEN B S, TOPSΦE H, LAGSGAARD E, BESENBACHER F. Location and coordination of promoter atoms in Co-and Ni-promoted MoS₂-based hydrotreating catalysts[J]. J Catal, 2007, 249(2): 220-233.
7. [7]
  [7] VILLARROEL M, BAEZA P, GRACIA F, ESCALONA N, AVILA P, GIL-LLAMBÍAS F J. Phosphorus effect on Co//Mo and Ni//Mo synergism in hydrodesulphurization catalysts[J]. Appl Catal A: Gen, 2009, 364(1-2): 75-79.
8. [8]
  [8] VILLARROEL M, BAEZA P, ESCALONA N, OJEDA J, DELMON B, GIL-LLAMBÍAS F J. MD//Mo and MD//W[MD = Mn, Fe, Co, Ni, Cu and Zn] promotion via spillover hydrogen in hydrodesulfurization[J]. Appl Catal A: Gen, 2008, 345(2): 152-157.
9. [9]
  [9] BAEZA P, VILLARROEL M, ÁVILA P, LÓPEZ AGUDO A, DELMON B, GIL-LLAMBÍAS F J. Spillover hydrogen mobility during Co-Mo catalyzed HDS in industrial-like conditions[J]. Appl Catal A: Gen, 2006, 304: 109-115.
10. [10]
  [10] BAEZA P, URETA-ZAÑARTU M S, ESCALONA N, OJEDA J, GIL-LLAMBÍAS F J, DELMON B. Migration of surface species on supports: A proof of their role on the synergism between CoS_x or NiS_x and MoS₂ in HDS[J]. Appl Catal A: Gen, 2004, 274(1-2): 303-309.
11. [11]
  [11] OJEDA J, ESCALONA N, BAEZA P, ESCUDEY M, GIL-LLAMBÍAS F J. Synergy between Mo/SiO₂ and Co/SiO₂ beds in HDS: A remote control effect[J]. Chem Commun, 2003, (13): 1608-1609.
12. [12]
  [12] VALDEVENITO F, GARCÍA R, ESCALONA N, GIL-LLAMBIAS F J, RASMUSSEN S B, LÓPEZ-AGUDO A. Ni//Mo synergism via hydrogen spillover, in pyridine hydrodenitrogenation[J]. Catal Commun, 2010, 11(14): 1154-1156.
13. [13]
  [13] LIU L, LIU B, CHAI Y, LIU Y, LIU C. Synergetic effect between sulfurized Mo/γ-Al₂O₃ and Ni/γ-Al₂O₃ catalysts in hydrodenitrogenation of quinoline[J]. J Nat Gas Chem, 2011, 20(2): 214-217.
14. [14]
  [14] LIU L, LI G, LIU B, LIU D, LIU Y, LIU C. Hydrodesulfurization performence study of Ni₂P-modiffied MoS₂/Al₂O₃ catalysts[J]. Chem Ind Eng Soc Chin, 2011, 62(5): 1296-1231.
15. [15]
  [15] GUAN Q, LI W. The synthesis and evaluation of highly active Ni₂P-MoS₂ catalysts using the decomposition of hypophosphites[J]. Catal Sci Technol, 2012, 2(11): 2356-2360.
16. [16]
  [16] LAN L, GE S, LIU K, HOU Y, BAO X. Synthesis of Ni₂P promoted trimetallic NiMoW/γ-Al₂O₃ catalysts for diesel oil hydrotreatment[J]. J Nat Gas Chem, 2011, 20(2): 117-122.
17. [17]
  [17] MCDONALD J W, FRIESEN G D, ROSENHEIN L D, NEWTON W E. Syntheses and characterization of ammonium and tetraalkylammonium thiomolybdates and thiotungstates[J]. Inorg Chim Acta, 1983, 72(1): 205-210.
18. [18]
  [18] LU M, WANG A, LI X, DUAN X, TENG Y, WANG Y, SONG C, HU Y. Hydrodenitrogenation of quinoline catalyzed by MCM-41-supported nickel phosphides[J]. Energy Fuels, 2007, 21(2): 554-560.
19. [19]
  [19] INFANTES-MOLINA A, CECILIA J A, PAWELEC B, FIERRO J L G, RODRÍGUEZ-CASTELLÓN, EJIMÉNEZ-LÓPEZ A. Ni₂P and CoP catalysts prepared from phosphite-type precursors for HDS-HDN competitive reactions[J]. Appl Catal A: Gen, 2010, 390(1/2): 253-263.
20. [20]
  [20] KORÁNYI T I, COUMANS A E, HENSEN E J M, RYOO R, KIM H S, PFEIFER É, KASZTOVSZKY Z. The influence of metal loading and activation on mesoporous materials supported nickel phosphide hydrotreating catalysts[J]. Appl Catal A: Gen, 2009, 365(1): 48-54.
21. [21]
  [21] KORÁNYI T I, VÍT Z, PODUVAL D G, RYOO R, KIM H S, HENSEN E J M. SBA-15-supported nickel phosphide hydrotreating catalysts[J]. J Catal, 2008, 253(1): 119-131.
22. [22]
  [22] WANG X, CLARK P, OYAMA S T. Synthesis, characterization, and hydrotreating activity of several iron group transition metal phosphides[J]. J Catal, 2002, 208(2): 321-331.
23. [23]
  [23] ARAI M, FUKUSHIMA M, NISHIYAMA Y. Interrupted-temperature programmed desorption of hydrogen over silica-supported platinum catalysts: The distribution of activation energy of desorption and the phenomena of spillover and reverse spillover of hydrogen[J]. Appl Surf Sci, 1996, 99(2): 145-150.
24. [24]
  [24] CHEN J, SUN L, WANG R, ZHANG J. Hydrodechlorination of chlorobenzene over Ni₂P/SiO₂ catalysts: Influence of Ni₂P loading[J]. Catal Lett, 2009, 133(3-4): 346-353.
25. [25]
  [25] DEEPA G, SANKARANARAYANAN T M, SHANTHI K, VISWANATHAN B. Hydrodenitrogenation of model N-compounds over NiO-MoO₃ supported on mesoporous materials[J]. Catal Today, 2012, 198(1): 252-262.
26. [26]
  [26] JIAN M, PRINS R. Mechanism of the hydrodenitrogenation of quinoline over NiMo(P)/Al₂O₃ catalysts[J]. J Catal, 1998, 179(1): 18-27.
27. [27]
  [27] EIJSBOUTS S, VAN GESTEL J N M, VAN VEEN J A R, DE BEER V H J, PRINS R. The effect of phosphate on the hydrodenitrogenation activity and selectivity of alumina-supported sulfided Mo, Ni, and Ni Mo catalysts[J]. J Catal, 1991, 131(2): 412-432.
28. [28]
  [28] ESCALONA N, GARCÍA R, LAGOS G, NAVARRETE C, BAEZA P, GIL-LLAMBÍAS F J. Effect of the hydrogen spillover on the selectivity of dibenzothiophene hydrodesulfurization over CoS_x/γ-Al₂O₃, NiS_x/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts[J]. Catal Commun, 2006, 7(12): 1053-1056.
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沈阳化工大学材料科学与工程学院沈阳 110142

Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline

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通讯作者: 陈斌, bchen63@163.com

Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline