Citation:
GUO Ai-jun, ZHANG Yan-qi, LIU He, WANG Zong-xian. Effect of heavy metals on characteristics of coke formation during thermal conversion of heavy oils[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(6): 685-690.
-
Three inferior heavy oils from Venezuela, Liaohe and Karamay were chosen as the feedstocks, and the effect of heavy metals on the characteristics of coke formation during thermal conversion process was studied. The results indicate that the higher content of heavy metals, the shorter coke induction period. With the increasing of the content of heavy metals, the yield of coke is increased obviously; the coke particle size becomes larger. Furthermore, the analysis of product from the delayed coking process indicates that the oil with higher content of heavy metals produces a higher coke yield, but a lower yield of liquid.
-
-
-
[1]
[1] 娄世松. 石油中的镍钒存在形态及其脱除方法[J]. 石油化工腐蚀与防护, 1996, 13(4): 30-32. (LOU Shi-song. The existence form of nickel and vanadium in petroleum and removal methods[J]. Petrochemical Corrosion and Protection, 1996, 13(4): 30-32.)
-
[2]
[2] 李东胜, 崔苗苗, 刘洁. 石油中卟啉化合物的研究进展[J]. 化学工业与工程, 2009, 26(4): 366-370. (LI Dong-sheng, CUI Miao-miao, LIU Jie. Development of porphyrin compound in petroleum[J]. Chemical Industry and Engineering, 2009, 26(4): 366-370.)
-
[3]
[3] 徐海, 于道永, 王宗贤, 阙国和. 石油卟啉化学的研究进展[J]. 化学研究与应用, 2001, 13(4): 347-352. (XU Hai, YU Dao-yong, WANG Zong-xian, QUE Guo-he. Review of the studies on petroporphyrin chemistry[J]. Chemical Research and Application, 2001, 13(4): 347-352.)
-
[4]
[4] 高涵, 马波, 王少军, 凌凤香, 张喜文, 侯彩丽. 石油中镍、钒的研究进展[J]. 当代化工, 2007, 36(6): 572-576. (GAO Han, MA Bo, WANG Shao-jun, LING Feng-xiang, ZHANG Xi-wen, HOU Cai-li. Research development of the studies on Ni and V in petroleum[J]. Contemporary Chemical Industry, 2007, 36(6): 572-576.)
-
[5]
[5] 张孔远, 燕京, 吕才山. 重油加氢脱金属催化剂的性能及沉积金属的分布研究[J]. 石油炼制与化工, 2004, 35(8): 30-33. (ZAHNG Kong-yuan, YAN Jing, LÜ Cai-shan. The performance of heavy oil hydrodemetallization catalyst and its deposited metal distribution[J]. Petroleum Processing and Petrochemicals, 2004, 35(8): 30-33.)
-
[6]
[6] 徐海, 于道永, 王宗贤, 阙国和. 镍和钒对石油加工过程的影响及对策[J]. 炼油设计, 2000, 30(11): 1-5. (XU Hai, YU Dao-yong, WANG Zong-xian, QUE Guo-he. Effects of nickel and vanadium on petroleum processing and countermeasures[J]. Petroleum Refinery Engineering, 2000, 30(11): 1-5.)
-
[7]
[7] 徐海, 于道永, 王宗贤, 阙国和. 镍卟啉临氮和临氢反应行为的研究[J]. 燃料化学学报, 2001, 29(3): 264-268. (XU Hai, YU Dao-yong, WANG Zong-xian, QUE Guo-he. Reaction characteristics of nickel porphyrin in presence of N2 and H2[J]. Journal of Fuel Chemistry and Technology, 2001, 29(3): 264-268.)
-
[8]
[8] 梁朝林, 沈本贤, 谢颖, 吴世逵. 减压渣油性质对焦化反应产物收率的影响[J]. 炼油技术与工程, 2008, 38(2): 1-5. (LIANG Chao-lin, SHEN Ben-xian, XIE Ying, WU Shi-kui. Impact of vacuum residue properties on product coke yield[J]. Petroleum Refinery Engineering, 2008, 38(2): 1-5.)
-
[9]
[9] KELEMEN S R, SISKIN M, GORBATY M L, FERRUGHELLI F T, WIATEK P J K, BROWN L D, EPPIG C P, KENNEDY R J. Delayed coker coke morphology fundamentals: Mechanistic implication based on XPS analysis of the composition of vanadium-and nickel-containing additives during coke formation[J]. Energy Fuels, 2007, 21(2): 927-940.
-
[10]
[10] PICON-HERNANDEZ H J, CENTENO-HURTADO A, PANTOJA-AGREDA E F. Morphological classification of coke formed from the castilla and jazmin crude oils[J]. CT&F-Ciencia, Tecnologia Y Futuro, 2008, 3(4): 169-183.
-
[11]
[11] 郭爱军, 林祥钦, 王圆圆, 王宗贤. 延迟焦化工艺弹丸焦生成的实验研究[J]. 燃料化学学报, 2012, 40(8): 958-966. (GUO Ai-jun, LIN Xiang-qin, WANG Yuan-yuan, WANG Zong-xian. Experimental study on shot coke formation in delayed coking process[J]. Journal of Fuel Chemistry and Technology, 2012, 40(8): 958-966.)
-
[12]
[12] 王宗贤, 何岩, 郭爱军, 张宏玉, 阙国和. 辽河和孤岛渣油供氢能力与生焦趋势[J]. 燃料化学学报, 1999, 27(3): 251-255. (WANG Zong-xian, HE Yan, GUO Ai-jun, ZHANG Hong-yu, QUE Guo-he. Study on hydrogen-donating ability of vacuum residues and their sub-fractions[J]. Journal of Fuel Chemistry and Technology, 1999, 27(3): 251-255.)
-
[13]
[13] 张力, 张政伟. 延迟焦化加热炉炉管结焦原因分析及对策[J]. 石油炼制与化工, 2010, 41(1): 21-25. (ZHANG Li, ZHANG Zheng-wei. Causes analysis and countermeasures of coking on furnace tube in delayed coking unit[J]. Petroleum Processing and Petrochemicals, 2010, 41(1): 21-25.)
-
[14]
[14] 高媛媛, 沈本贤, 刘纪昌. 委内瑞拉原油中钒卟啉的分离与鉴定[J]. 石油学报(石油加工), 2011, 27(1): 101-106. (GAO Yuan-yuan, SHEN Ben-xian, LIU Ji-chang. Isolation and characterization of vanadium porphyrins in Venezuela crude oil[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2011, 27(1): 101-106.)
-
[15]
[15] 徐丽娜. 石油卟啉的分离分析方法研究[J]. 江汉石油学院学报, 1986, (1): 117-126. (XU Li-na. Studies of the separation and analysis methods of porphyrin in petroleum[J]. Journal of Jianghan Petroleum Institute, 1986, (1): 117-126.)
-
[16]
[16] 高媛媛, 沈本贤, 陈锦, 刘纪昌. 重油中金属卟啉化合物对催化裂化性能的影响[J]. 石油炼制与化工, 2012, 43(2): 19-27. (GAO Yuan-yuan, SHEN Ben-xian, CHEN Jin, LIU Ji-chang. Impact of metal porphyrins in heavy oil on catalytic cracking[J]. Petroleum Processing and Petrochemicals, 2012, 43(2): 19-27.)
-
[1]
-
-
-
[1]
Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
-
[2]
Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
-
[3]
Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)27团簇用于硝酸盐电还原制氨:一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
-
[4]
Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
-
[5]
Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
-
[6]
Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO2制C2+产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
-
[7]
Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
-
[8]
Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
-
[9]
Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
-
[10]
Tianlong Zhang , Jiajun Zhou , Hongsheng Tang , Xiaohui Ning , Yan Li , Hua Li . Virtual Simulation Experiment for Laser-Induced Breakdown Spectroscopy (LIBS) Analysis. University Chemistry, 2024, 39(6): 295-302. doi: 10.3866/PKU.DXHX202312049
-
[11]
Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
-
[12]
Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
-
[13]
. Cover and Table of Contents for Vol.40 No. 12. Acta Physico-Chimica Sinica, 2024, 40(12): -.
-
[14]
. . University Chemistry, 2024, 39(2): 0-0.
-
[15]
. . University Chemistry, 2024, 39(3): 0-0.
-
[16]
. . University Chemistry, 2024, 39(4): 0-0.
-
[17]
. . University Chemistry, 2024, 39(5): 0-0.
-
[18]
. . University Chemistry, 2024, 39(6): 0-0.
-
[19]
. . University Chemistry, 2024, 39(7): 0-0.
-
[20]
. . University Chemistry, 2024, 39(8): 0-0.
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(355)
- HTML views(16)