Citation: GONG Rui, ZHOU Li-mei, MA Na, HU Jue, CHEN Jian-rong, HU Xin, DAI Wei. Adsorptive performance of benzothiophene using metal organic framework material MOF-5[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(5): 607-612. shu

Adsorptive performance of benzothiophene using metal organic framework material MOF-5

GONG Rui ¹ ,
ZHOU Li-mei ¹ ,
MA Na ² ,
HU Jue ¹ ,
CHEN Jian-rong ² ,
HU Xin ¹ ,
DAI Wei ^1,,

1.
1. College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China;

Corresponding author: DAI Wei,
Received Date: 31 October 2012
Available Online: 2 January 2013
Fund Project: 国家自然科学基金面上项目(21275131) (21275131) 浙江省教育厅项目(Y201329292)。 (Y201329292)

Removal of benzothiophenic compounds from fuels plays a key role in deep desulfurization. The adsorptive performance of benzothiophene with typical Metal-Organic Frameworks material MOF-5 was investigated using batch experiments. Results showed that the adsorption kinetics data of benzaothiophene onto MOF-5 from model fuel could be well described by a pseudo-second-order model. The adsorption equilibrium data of benzaothiophene onto MOF-5 fitted well to the Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models (Freundlich>D-R>Langmuir). Thermodynamic parameters showed that the adsorption of benzaothiophene onto MOF-5 was spontaneous and endothermic in nature.
- MOF-5,
- benzothiophene,
- adsorptive performance
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