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Citation: LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(4): 469-476. shu

CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials

  • 1.

    1. Center of Chemical Engineering and Technology for Energy, North China Electric Power University, Beijing 102206, China;

  • Corresponding author: ZHANG Kai, 
  • Received Date: 29 September 2012
    Available Online: 11 December 2012

    Fund Project: 国家自然科学基金 (51061130538) (51061130538) 国家高技术发展研究计划(863计划, 2012AA06A115) (863计划, 2012AA06A115) 111引智计划(B12034). (B12034)

  • The adsorption properties of CO2 on MCM-41 mesoporous materials impregnated with ethylenediamine (EDA), tetraethylenepentamine (TEPA) and two kinds of polyethylenimines (PEI600 and PEI1800), respectively, were studied with mass spectrometry (MS) and thermogravimetry (TG) techniques. The sample obtained by impregnating EDA (EDA-MCM-41) showed a low CO2 adsorption capacity due to the ready volatilization of EDA, while those samples prepared by TEPA (TEPA-MCM-41), PEI600 (PEI600-MCM-41) or PEI1800 (PEI1800-MCM-41) exbibit higher adsorption capacity and thermal stability although the adsorption capacity decreased with increasing molecular weight of amines. A maximum CO2 adsorption capacity of 2.7 mmol/g was achieved on the TEPA-MCM-41 with 40% TEPA. When this sample was regenerated at 100 ℃ under pure nitrogen atmosphere, its CO2 adsorption capacity was decreased by 7.4% after ten recycles in contrast to less than 1% for both PEI600-MCM-41 and PEI1800-MCM-41. However, when the regeneration atmosphere was changed to 80% CO2/20% N2, the regeneration temperature should be be increased to more than 160 ℃ for all the samples despite that PEI-MCM-41 showed high thermal stability than TEPA-MCM-41.
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