Citation:
YAN Yun-fei, ZHANG Lei, ZHANG Li, LEI Qiang, ZHANG Jie. Influence of oxygen concentration on combustion characteristics of inferior coal and sludge mixture[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(4): 430-435.
-
Combustion characteristics and thermal dynamic characteristics of inferior coal and core board mixture in O2 and N2 atmosphere were studied with O2 concentration of 20%, 30%, 50%, 70%, 90% respectively. With the increase of O2 concentration, DTG curves tend to move to lower temperature region. Also, ignition temperature, maximum weight loss rate and its corresponding temperature, the temperature of burnout, and synthetic combustion factor of mixture, are compared. The results indicate that O2 concentration can significantly improve the combustion conditions. Apparent activation energy of the fixed carbon combustion section is put into the calculation and analysis, which shows that the apparent activation energy increases with the increasing O2 concentration. In order to quantize combustion condition internal and external, definition of combustion enhancement factor(C.E.F.) is put forward. In selected fixed carbon combustion segment, C.E.F. increases rapidly with the increase in O2 concentration, which proves the positive role of oxygen concentration on combustion. There are kinetic compensation effect between C.E.F. and apparent activation energy.
-
-
-
[1]
[1] 樊越胜, 邹峥, 高巨宝, 曹子栋. 富氧气氛中煤粉燃烧特性改善的实验研究[J]. 西安交通大学学报, 2006, 40(1): 20-21. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Experimental research of rich oxygen content on improving combustion characteristics of pulverized coal[J]. Journal of Xi’an Jiao Tong University, 2006, 40(1): 20-21.)
-
[2]
[2] 韩亚芬. 富氧条件下煤燃烧特性的热重法实验研究. 哈尔滨: 哈尔滨工业大学, 2007. (HAN Ya-fen. Study on combustion characteristics of coal at oxygen enriched condition by thermogravimetric. Harbin: Harbin Institute of Technology, 2007.)
-
[3]
[3] 刘国伟, 董芃, 韩亚芬, 别如山. 富氧条件下煤燃烧特性的热重分析实验研究[J]. 哈尔滨工业大学学报, 2011, 1(43): 104-108. (LIU Guo-wei, DONG Peng, HAN Ya-fen, BIE Ru-shan. Experimental study on combustion characteristics of coals under enriched-oxygen condition by thermo-gravimetric analysis[J]. Journal of Harbin Institute of Technology, 2011, 1(43): 104-108.)
-
[4]
[4] MURPHY J J, SHADDIX C R. Combustion kinetics of coal chars in oxygen-enriched environments[J]. Comb Flame, 2006, 144(4): 710-729.
-
[5]
[5] QIN Y P, LIU W, YANG C, FAN Z Z, WANG L L, JIA G W. Experimental study on oxygen consumption rate of residual coal in goaf[J]. Safety Science, 2012, 50(4): 787-791.
-
[6]
[6] YUZBASI N S, SELUK N. Air and oxy-fuel combustion behaviour of petcoke/lignite blends[J]. Fuel, 2012, 92(1): 137-144.
-
[7]
[7] LIU H, ZAILANI R, GIBBS B M. Comparisons of pulverized coal combustion in air and in mixtures of O2/CO2 [J]. Fuel, 2005, 84(7-8): 833-840.
-
[8]
[8] 万嘉瑜, 金余其, 池涌. 不同氧浓度下城市污泥燃烧特性及动力学分析[J]. 中国电机工程学报, 2010, 5(30): 35-40. (WAN Jia-yu, JIN Yu-qi, CHI Yong. Study on combustion characteristics and kinetics of municipal sludge under different oxygen concentrations[J]. Proceedings of the CSEE, 2010, 5(30): 35-40.)
-
[9]
[9] 李春雨, 蒋旭光, 费振伟, 安春国, 池涌, 严建华,俞恺, 傅娟娟, 潘金华, 施政. 制革、造纸和湖泊污泥燃烧特性的研究[J]. 燃料化学学报, 2009, 6(37): 757-762. (LI Chun-yu, JIANG Xu-guang, FEI Zhen-wei, AN Chun-guo, CHI Yong, YAN Jian-hua, YU Kai, FU Juan-juan, PAN Jin-hua, SHI Zheng. Study on the combustion characteristics of the sludge from leather industry and lake[J]. Journal of Fuel Chemistry and Technology, 2009, 6(37): 757-762.)
-
[10]
[10] ARIAS B, PEVIDA C, RUBIERA F, PIS J J. Effect of biomass blending on coal ignition and burnout during oxy-fuel combustion[J]. Fuel, 2008, 87(12): 2753-2759.
-
[11]
[11] 陈祎, 段佳, 林鹏, 罗永浩. 氧量对典型生物质燃烧特性的影响[J]. 中国电机工程学报, 2008, 28(2): 43-48. (CHEN Yi, DUAN Jia, LIN Peng, LUO Yong-hao. Effect of oxygen concentration on combustion characteristics of typical biomass materials [J].Proceedings of the CSEE, 2008, 28(2): 43-48.)
-
[12]
[12] 樊越胜, 邹峥, 高巨宝, 曹子栋. 煤粉在富氧条件下燃烧特性的实验研究[J]. 中国电机工程学报, 2005, 25(24): 118-121. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Study of oxygen content on combustion characteristics of pulverized coal[J]. Proceedings of the CSEE, 2005, 25(24): 118-121.)
-
[13]
[13] ZHANG N, NING X A, ZHOU J B, WEI P T, LUO H J. Investigation on the co-combustion characteristics of pulverized coal and paper mill sludge[J]. Appl Mech Mater, 2011, 55-57: 1132-1137
-
[14]
[14] OTERO M, DZE C, CALVO L F, GARCA A I, MORN A. Analysis of the co-combustion of sewage sludge and coal by TG-MS[J].Biomass and Bioenergy, 2002, 22(4): 319-329.
-
[15]
[15] OTERO M, GMEZ X, GARCA A, MORN A. Effects of sewage sludge blending on the coal combustion: A thermogravimetric assessment[J]. Chemosphere, 2007, 69(11): 1740-1750.
-
[16]
[16] OTERO M, SNCHEZ M E, GARCA A, MORN A. Simultaneous thermogravimetric-mass spectrometric study on the co-combustion of coal and sewage sludges[J]. Journal of Thermal Analysis and Calorimetry, 2006, 86(2): 489-495.
-
[17]
[17] 邹学权, 王新红, 吴建军, 陈越. 用热重-差热-红外光谱技术研究煤粉的燃烧特性[J]. 煤炭转化, 2003, 26(1): 71-73. (ZOU Xue-quan, WANG Xin-hong, WU Jian-jun, CHEN Yue. Study on combustion characteristic of coal by means of technology of TG-DSC-FTIR[J]. Coal Conversion, 2003, 26(1): 71-73.)
-
[18]
[18] 姜秀民, 李巨斌, 邱健荣. 超细化煤粉燃烧特性的研究[J]. 中国电机工程学报. 2000, 20(6): 71-74. (JIANG Xiu-min, LI Ju-bin, QIU Jian-rong. Study on combustion characteristic of micro-pulverized coal[J]. Proceeding of the CSEE, 2000, 20(6): 71-74.)
-
[19]
[19] 胡荣祖, 史启祯. 热分析动力学[M]. 北京: 科学出版社, 2001, 99-100. (HU Rong-zhu, SHI Qi-zhen. Kinetics of thermal analysis[M]. Beijing: Science Press, 2001, 99-100.)
-
[20]
[20] FANG M X, SHEN D K, LI Y X, YU C J, LUO Z Y, CEN K F. Kinetic study on pyrolysis and combustion of wood under different oxygen concentrations by using TG-FTIR analysis[J]. J Anal Appl Pyrolysis, 2006, 77(1): 22-27.
-
[21]
[21] YU Z S, MA X Q, LIU A. Thermogravimetric analysis of rice and wheat straw catalytic combustion in air-and oxygen-enriched atmospheres[J]. Energy Convers Manage, 2009, 50(3): 561-566.
-
[22]
[22] 闵凡飞, 张明旭. 生物质与不同变质程度煤混合燃烧特性的研究[J]. 中国矿业大学学报, 2005, 34(2): 236-241. (MIN Fan-fei, ZHANG Ming-xu. Research on combustion characteristics of biomass and coals with different ranks[J]. Journal of China University of Mining and Technology, 2005, 34(2): 236-241.)
-
[1]
-
-
-
[1]
Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
-
[2]
Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
-
[3]
Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
-
[4]
Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-. doi: 10.1016/j.actphy.2025.100085
-
[5]
Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
-
[6]
Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
-
[7]
Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
-
[8]
Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
-
[9]
Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
-
[10]
Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-. doi: 10.1016/j.actphy.2025.100084
-
[11]
Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO2 for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
-
[12]
Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
-
[13]
Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
-
[14]
Meiyu Lin , Yuxin Fang , Songzhang Shen , Yaqian Duan , Wenyi Liang , Chi Zhang , Juan Su . Exploration and Implementation of a Dual-Pathway Blended Teaching Model in General Chemistry Experiment Course: A Case Study of Copper Glycine Synthesis and Its Thermal Analysis. University Chemistry, 2024, 39(8): 48-53. doi: 10.3866/PKU.DXHX202312042
-
[15]
You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
-
[16]
Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
-
[17]
Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
-
[18]
Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
-
[19]
Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
-
[20]
Shuyong Zhang , Yaxian Zhu , Wenqing Zhang , Yuzhi Wang , Jing Lu . Ideological and Political Design of Combustion Heat Measurement Experiment: Determination of Heat Value of Agricultural and Forestry Wastes. University Chemistry, 2024, 39(2): 1-6. doi: 10.3866/PKU.DXHX202303026
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(459)
- HTML views(25)