Citation: QU Cheng-rui, XU Bin, WU Jian, LIU Jian-xin, WANG Xue-tao. Effect of oxygen concentration on PM2.5 formation during coal combustion under O2/CO2 atmosphere[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 356-360. shu

Effect of oxygen concentration on PM2.5 formation during coal combustion under O2/CO2 atmosphere

  • Corresponding author: QU Cheng-rui, 
  • Received Date: 17 August 2012
    Available Online: 9 November 2012

    Fund Project: 国家自然科学基金(50806020)。 (50806020)

  • Pulverized coals were burned in a tube furnace under O2/CO2 atmosphere, and an electrical low pressure-impactor (ELPI) was used to collect the PM2.5. The results show that a bimodal distribution of PM2.5 appears, which is located at 0.1 µm and 2.0 µm, respectively. The mass concentrations of PM2.5 increase with5 enhancing the O2 concentraion. The enrichment of S, Na and K on the sub-micron particles is observed, but that of Si and Ca is not observed. It is proposed that sub-micron particles are formed via the mechanism of vaporization and condensation, and the super-micron particles are formed by the fragmentation of coal char and the coalescence of inherent mineral matter based on the analyses of particle size distribution, elements distribution and morphology of PM2.5.
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    1. [1]

      [1] LINAK W P, YOO J I, WASSON S J, ZHU W Y, WENDT J O L, HUGGINS F E, CHEN Y Z, SHAH N, HUFFMAN G P, GILMOUR M I. Ultrafine ash aerosols from coal combustion: Characterization and health effects[J]. Proceedings of the Combustion Institute, 2007, 31(2): 1929-1937.

    2. [2]

      [2] WANG Q Y, ZHANG L, SATO A, NINOMIYA Y, YAMASHITA T. Effects of coal blending on the reduction of PM(10) during high-temperature combustion 2. A coalescence-fragmentation model[J]. Fuel, 2009, 88(1): 150-157.

    3. [3]

      [3] WANG S Z, BAXTER L, FONSECA F. fly ash in concrete: SEM, EDX and ESEM analysis[J]. Fuel, 2008, 87(2): 372-379.

    4. [4]

      [4] BUHRE B J P, HINKLEY J T, GUPTA R P, NELSON P F, WALL T F.Fine ash formation during combustion of pulverized coal–coal property impacts[J].Fuel, 2006, 85(10):185-193.

    5. [5]

      [5] YU Y, XU M H, YAO H, YU D X, QIAO Y, SUI J C, LIU X W, CAO Q.Char characteristics and particulate matter formation during Chinese bituminous coal combustion[J]. Proceedings of the Combustion Institute, 2007, 31(2): 1947-1954.

    6. [6]

      [6] CHEN Y Z, NARESH S, HUGGINS F E. Investigation of primary fine particulate matter from coal combustion by computer-controlled scanning electron microscopy[J]. Fuel Processing Technology, 2004, 85(6-7): 743-761.

    7. [7]

      [7] 吕建燚, 李晶欣. 煤粉物化特性对燃烧后灰颗粒物的影响[J]. 燃料化学学报, 2011, 39(6): 419-424. (LU Jian-yi, LI Jing-xin.Influence of coal physicochemical properties on ash particulate matter after coal combustion[J].Journal of Fuel Chemistry and Technology, 2011, 39(6): 19-424)

    8. [8]

      [8] 朱建航, 胡勤海, 陈菊芬, 张辉, 刘建忠, 岑可法. 污泥水煤浆燃烧和污染排放特性研究[J]. 燃料化学学报, 2012,40(2): 252-256. (ZHU Jian-hang, HU Qin-hai, CHEN Ju-fen, ZHANG hui, LIU Jian-zhong, CEN Ke-fa.Combustion of sludge coal water slurry and emission property of contaminants[J].Journal of Fuel Chemistry and Technology, 2012, 40(2): 252-256)

    9. [9]

      [9] BUHRE B J P, HINKLEY J T, GUPTA R P, WALL T F, LSON P F. Submicron ash formation from coal combustion[J]. Fuel, 2005, 84(10): 1206-1214.

    10. [10]

      [10] XU M H, YU D X, YAO H, LIU X W, QIAO Y. Coal combustion-generated aerosols: Formation and properties[J]. Proceedings of the Combustion Institute, 2011, 33(1): 1681-1697.

    11. [11]

      [11] SHENG C D, LU Y H, GAO X P, YAO H.Fine ash formation during pulverized coal combustions-a comparison of O2/CO2 combustion versus air combustion[J].Energy & Fuels, 2007, 21(2): 435-440.

    12. [12]

      [12] WU H, PEDERSEN A J, GLARBORG P, FRANDSEN F J, JOHANSEN K D, SANTER B. Formation of fine particles in co-combustion of coal and solid recovered fuel in a pulverized coal-fired power station[J]. Proceedings of the Combustion Institute, 2011, 33(2): 2845-2852.

    13. [13]

      [13] ZHANG L, NINOMIYA Y.Emission of suspended PM10 from laboratory:scale coal combustion and its correlation with coal mineral properties[J].Fuel, 2006, 85(1): 194-203.

    14. [14]

      [14] MORRIS W J, YU D X, WENDT J O L. Soot, unburned carbon and ultrafine particle emissions from air- and oxy-coal flames[J]. Proceedings of the Combustion Institute, 2011, 33(2): 3415-3421.

    15. [15]

      [15] FRYDA L, SOBRINO C, GLAZER M. Study of ash deposition during coal combustion under oxyfuel conditions[J]. Fuel, 2012, 92(1): 308-317.

    16. [16]

      [16] 王春波, 雷鸣, 阎维平, 王松岭. 煤粉的增压富氧燃烧特性及煤灰矿物演变[J]. 燃料化学学报, 2012, 40(7):790-794. (WANG Chun-bo, LEI Ming, YAN Wei-ping, WANG Song-ling.Combustion characteristics of pulverized coal and mineral conversion under pressurized oxy-fuel condition[J]. Journal of Fuel Chemistry and Technology, 2012, 40(7): 790-794 )

    17. [17]

      [17] FLAGAN R C, TAYLOR D D. Aerosols from a laboratory pulverized coal combustor//ACS Symposium Series, Pasadena, USA, 1980.

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