Citation: LIU Li-hua, LIU Shu-qun, CHAI Yong-ming, LIU Chen-guang. Preparation mechanism and hydrodenitrogenation performance of nickel phosphide catalyst[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 335-340. shu

Preparation mechanism and hydrodenitrogenation performance of nickel phosphide catalyst

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1. School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China;

Corresponding author: LIU Li-hua,
Received Date: 9 August 2012
Available Online: 7 November 2012
Fund Project: 国家重点基础研究发展规划(973计划,2010CB226905) (973计划,2010CB226905)安徽省教育厅自然科学基金(KJ2013B243) (KJ2013B243)淮北师范大学青年科研项目(2012xq47)。 (2012xq47)

Thermal decomposition of nickel hypophosphite precursor into nickel phosphide (Ni₂P) was studied using thermogravimetry-mass spectrometry analysis. The results indicated that nickel ion (Ni²⁺) influenced the decomposition pathway of hypophosphite, because it might catalyze the reaction of hypophosphite to produce PH₃ at lower temperature. Silica-supported Ni₂P catalysts with different loadings were prepared and characterized using X-ray diffraction, N₂ adsorption-desorption, and high resolution transmission electron microscopy. It was indicated that Ni₂P was well dispersed on the support with a particle size of 5～8 nm. The catalytic performance of as-prepared catalysts was evaluated in a fixed-bed reactor for hydrodenitrogenation of quinoline. Under the reaction temperature of 360℃, hydrogen pressure of 2.0 MPa, LHSV of 2.0 h^-1, and H₂/oil volume ratio of 500:1, the conversion of quinoline over Ni₂P(20%)/SiO₂ catalyst reached 41.5%.
- nickel phosphide,
- preparation mechanism,
- thermogravimetry-mass spectrometry,
- hydrodenitrogenation
1. [1]
  [1] SHU Y, OYAMA S T. Synthesis, characterization, and hydrotreating activity of carbon-supported transition metal phosphides[J]. Carbon, 2005, 43(7): 1517-1532.
2. [2]
  [2] 宋华, 张永江, 宋华林, 代敏. 柠檬酸对Ni₂P/TiO₂-Al₂O₃催化剂加氢脱硫性能的影响[J]. 物理化学学报, 2012, 28(3): 661-666. (SONG Hua, ZHANG Yong-jiang, SONG Hua-lin, DAI Min. Effect of citric acid on the hydrodesulfurization performance of Ni₂P/TiO₂-Al₂O₃ catalyst[J]. Acta Physico-Chimica Sinica, 2012, 28(3): 661-666.)
3. [3]
  [3] 宋华, 郭云涛, 李锋, 于洪坤. Ni₂P/TiO₂-Al₂O₃催化剂的制备及其加氢脱硫、脱氮性能[J]. 物理化学学报, 2010, 26(9): 2461-2467. (SONG Hua, GUO Yun-tao, LI Feng, YU Hong-kun. Preparation, hydrodesulfurization and hydrodenitrogenation performance of a Ni₂P/TiO₂-Al₂O₃ catalyst[J]. 2010, 26(9): 2461-2467.)
4. [4]
  [4] 宋华, 张永江, 宋华林, 代敏. 柠檬酸对负载型磷化镍催化剂加氢脱硫性能的影响[J]. 燃料化学学报, 2012, 40(10): 1246-1251. (SONG Hua, ZHANG Yong-jiang, SONG Hua-lin, DAI Min. Effect of citric acid on hydrodesulfurization performance of the supported nickel phosphide catalyst[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 1246-1251.)
5. [5]
  [5] LIU L, LI G, LIU D, LIU Y, LIU C. Preparation and catalytic performance of the transition metal phosphides[J]. Prog Chem, 2010, 22(9): 1701-1708.
6. [6]
  [6] LIU S, LIU X, XU L, QIAO Y, MA X. Controlled synthesis and characterization of nickel phosphide nanocrystal[J]. J Cryst Growth, 2007, 304(2): 430-434.
7. [7]
  [7] LI W, DHANDAPANI B, OYAMA S T. Molybdenum phosphide: A novel catalyst for hydrodenitrogenation[J]. Chem Lett, 1998, 27(3): 207-208.
8. [8]
  [8] SHI G, SHEN J. New synthesis method for nickel phosphide nanoparticles: Solid phase reaction of nickel cations with hypophosphites[J]. J Mater Chem, 2009, 19(2295-2297.
9. [9]
  [9] GUAN Q, LI W, ZHANG M, TAO K. Alternative synthesis of bulk and supported nickel phosphide from the thermal decomposition of hypophosphites[J]. J Catal, 2009, 263(1): 1-3.
10. [10]
  [10] LU M, WANG A, LI X, DUAN X, TENG Y, WANG Y, SONG C, HU Y. Hydrodenitrogenation of quinoline catalyzed by MCM-41-supported nickel phosphides[J]. Energy Fuels, 2007, 21(2): 554-560.
11. [11]
  [11] JIAN M, PRINS R. Mechanism of the hydrodenitrogenation of quinoline over NiMo(P)/Al₂O₃ catalysts[J]. J Catal, 1998, 179(1): 18-27.
12. [12]
  [12] GUAN Q, LI W. A novel synthetic approach to synthesizing bulk and supported metal phosphides[J]. J Catal, 2010, 271(2): 413-415.
13. [13]
  [13] SHI G, SHEN J. Mesoporous carbon supported nickel phosphide catalysts prepared by solid phase reaction[J]. Catalysis Communications, 2009, 10(13): 1693-1696.
14. [14]
  [14] YANG S, PRINS R. New synthesis method for nickel phosphide hydrotreating catalysts[J]. Chem Commun, 2005, 33: 4178-4180.
15. [15]
  [15] STINNER C, PRINS R, WEBER T. Binary and ternary transition-metal phosphides as HDN catalysts[J]. J Catal, 2001, 202(1): 187-194.
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沈阳化工大学材料科学与工程学院沈阳 110142