Citation: ZHANG Xu, SUN Wen-jing, CHU Wei. Effect of glow discharge plasma treatment on the performance of Ni/SiO₂ catalyst in CO₂ methanation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(1): 96-101. shu

Effect of glow discharge plasma treatment on the performance of Ni/SiO₂ catalyst in CO₂ methanation

1.
Department of Chemical Engineering, Sichuan University, Chengdu 610065, China

Corresponding author: CHU Wei,
Received Date: 18 June 2012
Available Online: 19 August 2012
Fund Project: 国家自然科学基金(205903603)。 (205903603)

Ni/SiO₂ catalysts were prepared by impregnation method and treated by glow discharge plasma. The Ni/SiO₂ catalysts were characterized by CO₂-TPD and H₂-TPR; the effects of plasma treatment on the performances of Ni/SiO₂ in adsorption, reduction, and catalytic methanation of CO₂ were investigated. The results showed that the plasma treatment can remarkably improve the dispersion of active components and enhance the reactivity of Ni/SiO₂ catalyst. The catalytic performance of Ni/SiO₂ in CO₂ methanation is also enhanced by the plasma treatment; the conversion of CO₂ and the space time yield of CH₄ over the plasma modified catalyst are higher than those over the Ni/SiO₂ catalyst obtained through conventional impregnation and calcination method.
- glow discharge plasma,
- Ni/SiO₂,
- catalytic performance,
- carbon dioxide,
- methanation.
1. [1]
  [1] 郭芳, 储伟, 石新雨, 张旭. 等离子体引入方式对强化制备二氧化碳重整甲烷反应的Ni/γ- Al₂O₃催化剂的影响[J]. 高等学校化学学报, 2009, 30(4): 746-751. (GUO Fang, CHU Wei, SHI Xin-Yu, ZHANG Xu. Effects of plasma introduction mode on Ni/γ-Al₂O₃ catalysts for CH₄ reforming with CO₂[J]. Chemical Research in Chinese Universities, 2009, 30(4): 746-751.)
2. [2]
  [2] 徐慧根, 姜恩勇, 盛京, 徐廷献, 李振花. 等离子体技术与应用[M]. 北京: 化学工业出版社, 2006. (XU Hui-gen, JIANG En-yong, SHENG Jing, XU Ting-xian, LI Zhen-hua. Plasma technology and application[M]. Beijing: Chemical Industry Press, 2006.)
3. [3]
  [3] CHU P K, CHEN J Y, WANG L P, HUANG N. Plasma-surface modification of biomaterials[J]. Mater Sci Eng R, 2003, 36(5/6): 143-206.
4. [4]
  [4] 于开录, 刘昌俊, 夏清, 邹吉军. 低温等离子体技术在催化剂领域的应用[J]. 化学进展, 2002, 4(6): 456-461. (YU Kai-lu, LIU Chang-jun, XIA Qing, ZOU Ji-jun. Applications of low temperature plasma in catalysis [J]. Progress in Chemistry, 2002, 14(6): 456-461.)
5. [5]
  [5] 邹吉军. 等离子体处理制备高效催化剂的基础研究[D]. 天津:天津大学, 2005. (ZOU Ji-jun. On the preparation of highly efficient catalysts using cold plasma treatment[D]. Tianjin: Tianjin University, 2005.)
6. [6]
  [6] SHI P, LIU C-J. Characterization of silica supported nickel catalyst for methanation with improved activity by room temperature plasma treatment[J]. Catal Lett, 2009, 133(1/2): 112-118.
7. [7]
  [7] GUO X Y, SUN Y L, YU Y, ZHU X, LIU C J. Carbon formation and steam reforming of methane on silica supported nickel catalysts[J]. Catal Commun, 2012, 19: 61- 65.
8. [8]
  [8] LIU C J, YE J Y, JIANG J J, PAN Y X. Progresses in the preparation of coke resistant Ni-based catalyst for steam and CO₂ reforming of methane[J]. Chem Cat Chem, 2011, 3(3): 529- 541.
9. [9]
  [9] KHODAKOV A Y, CHU W, FONGARLAND P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels[J]. Chem Inform, 2007, 107(5): 1692-1744.
10. [10]
  [10] ZHANG Y, CHU W, CAO W M, LUO C R, WEN X G, ZHOU K L. A plasma-activated Ni/α-Al₂O₃catalyst for the conversion of CH₄ to syngas[J]. Plasma Chem Plasma P, 2000, 20(1): 137-144.
11. [11]
  [11] CHEN M H, CHU W, DAI X Y. New palladium catalysts prepared by glow discharge plasma for the selective hydrogenation of acetylene[J]. Catal Today, 2004, 89(1/2): 201-204.
12. [12]
  [12] LIU C J, YU K L, ZHANG Y P, ZHU X L, HE F, ELIASSON B. Characterization of plasma treated Pd/HZSM-5 catalyst for methane combustion[J]. Appl Catal B, 2004, 47(2): 95-100.
13. [13]
  [13] 徐慧远, 储伟, 慈志敏. 辉光放电等离子体对合成甲醇用铜基催化剂的改性作用[J]. 物理化学学报, 2007, 23(7): 1042-1046. (XU Hui-yuan, CHU Wei, CI Zhi-min. Effect of glow discharge plasma on copper-based catalysts for methanol synthesis[J]. Acta Phys-Chim Sin, 2007, 23(7): 1042-1046.)
14. [14]
  [14] 徐慧远, 储伟, 士丽敏, 张辉, 周俊. 射频等离子体技术制备合成低碳醇用铜钴基催化剂[J]. 物理化学学报, 2008, 24(6): 1085-1089. (XU Hui-yuan, CHU Wei, SHI Li-min, ZHANG Hui, ZHOU Jun. Preparation of copper-cobalt catalyst by glow discharge plasma for lower alcohols synthesis[J]. Acta Phys-Chim Sin, 2008, 24(6): 1085-1089.)
15. [15]
  [15] 张月萍, 祝新利, 潘云翔, 刘昌俊. 等离子体处理制备对甲烷重整Ni基催化剂抗积炭性能的改进[J]. 催化学报, 2008, 19(10):1058-1066. (ZHANG Yue-ping, ZHU Xin-li, PAN Yun-xiang, LIU Chang-jun. Improvement of coke resistance performance of Ni-based catalysts in methane reforming via glow discharge plasma treatment[J]. Chinese Journal of Catalysis, 2008, 19(10): 1058-1066.)
16. [16]
  [16] DADASHOVA E A, YAGODOVSKAYA T V, LUNIN V V, KISELEV V V, SHPIRO E S, BEILIN L A. The regeneration of the Fe₂O₃/ZSM-5 catalyst for Fischer-Tropsch synthesis in oxygen glow discharge[J]. Kinet Catal, 1993, 34(4): 670-673.
17. [17]
  [17] 李代红, 习敏, 陶旭梅, 石新雨, 戴晓雁, 印永祥. 常压等离子体还原的Ni/γ-Al₂O₃催化剂的程序升温脱附研究[J]. 催化学报, 2008, 29(3): 287-291. (LI Dai-hong, XI Min, TAO Xu-mei, SHI Xin-yu, DAI Xiao-yan, YIN Yong-xiang. TPD studies on Ni/γ-Al₂O₃ catalysts reduced by atmosphere plasma[J]. Chinese Journal of Catalysis, 2008, 29(3): 287-291.)
18. [18]
  [18] ZOU J-J, ZHANG Y-P, LIU C-J, LI Y, ELIASSON B. Starch-enhanced synthesis of oxygenates from methane and carbon dioxide using dielectric-barrier discharges[J]. Plasma Chem Plasma P, 2003, 23(1): 69-82.
19. [19]
  [19] 郭芳, 储伟, 徐慧远, 张涛. 采用等离子体强化制备CO₂甲烷化用镍基催化剂[J]. 催化学报, 2007, 28(5): 429-434. (GUO Fang, CHU Wei, XU Hui-yuan, ZHANG Tao. Glow discharge plasma-enhanced preparation of nickel-based catalyst for CO₂ methanation [J]. Chinese Journal of Catalysis, 2007, 28(5): 429-434.)
20. [20]
  [20] 徐慧远, 储伟, 士丽敏, 张辉, 邓思玉. 射频等离子体对合成低碳醇用CuCoAl催化剂的改性作用[J]. 燃料化学学报, 2009, 37(2): 212-216. (XU Hui-yuan, CHU Wei, SHI Li-min, ZHANG Hui, DENG Si-yu. Effect of glow discharge plasma on copper-cobalt-aluminum catalysts for higher alcohol synthesis[J]. Journal of Fuel Chemistry and Technology, 2009, 37(2): 212-216. )
21. [21]
  [21] XAVIER K O, SREEKALA R, RASHID K K A, YUSUFF K K M, SEN B. Doping effects of cerium oxide on Ni/ Al₂O₃ catalysts for methanation[J]. Catal Today, 1999, 49(1/3): 17- 21.
22. [22]
  [22] TAO X M, BAI M G, LI X, LONG H L, SHANG S Y, YIN Y X, DAI X Y. CH₄-CO₂ reforming by plasma-challenges and opportunities[J]. Prog Energ Combust, 2011, 37(2): 113-124.
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . Recent advances in synergistic catalytic valorization of CO₂ and hydrocarbons by heterogeneous catalysis. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-. doi: 10.1016/j.actphy.2025.100073
4. [4]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
8. [8]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
9. [9]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
10. [10]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
11. [11]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
12. [12]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
16. [16]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
17. [17]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Co/Mn/Mo掺杂加速NiSe₂重构以提高其电催化尿素氧化性能. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-. doi: 10.1016/j.actphy.2025.100083
18. [18]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
19. [19]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
20. [20]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(562)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of glow discharge plasma treatment on the performance of Ni/SiO2 catalyst in CO2 methanation

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of glow discharge plasma treatment on the performance of Ni/SiO₂ catalyst in CO₂ methanation