Citation: HUANG Xiao-ming, ZHANG Qing, WANG Tie-jun, MA Long-long, ZHANG Qi, ZHANG Xing-hua, YU Yu-xiao, ZUO Hua-liang, LIU Jian-guo, YANG Yong. Catalytic performance of Raney Ni in the hydrogenation of di-furfural-acetone for producing long-chain alkane precursors[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(1): 79-84. shu

Catalytic performance of Raney Ni in the hydrogenation of di-furfural-acetone for producing long-chain alkane precursors

HUANG Xiao-ming ^1,2 ,
ZHANG Qing ¹ ,
WANG Tie-jun ^1,, ,
MA Long-long ¹ ,
ZHANG Qi ¹ ,
ZHANG Xing-hua ^1,2 ,
YU Yu-xiao ^1,2 ,
ZUO Hua-liang ^1,2 ,
LIU Jian-guo ^1,2 ,
YANG Yong ^1,2

1.
1. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: WANG Tie-jun,
Received Date: 29 May 2012
Available Online: 5 August 2012
Fund Project: 国家高技术研究发展计划(863计划, 2012AA101806) (863计划, 2012AA101806) 国家自然科学基金(51161140331) (51161140331) 国家重点基础研究发展规划(973计划, 2012CB215304)。 (973计划, 2012CB215304)

The hydrogenation of di-furfural-acetone for producing long-chain alkane precursors was carried out over Raney Ni catalyst; the effects of reaction temperature, pressure and time on the product distribution were investigated. The results indicated that Raney Ni exhibits excellent catalytic performance at low temperature. The hydrogenation can be enhanced by increasing temperature and pressure; at 50℃, 2.5 MPa and after 2 h reaction, the di-furfural-acetone is completely converted with 80.8% of the selectivity to the saturated hydrogenated products. However, excessive high temperature may be harmful to the hydrogenation. It was found that the hydrogenation activity towards three double bonds in di-furfural-acetone follows the order of ethylenic bond > furan ring double bond > C=O. Various solvents (water, methanol, tetrahydrofuran and cyclohexane) are also different in their effects on the catalytic performance; Raney Ni exhibits much higher hydrogenation activity in methanol than in other solvents.
- di-furfural-acetone,
- Raney Ni,
- hydrogenation,
- long-chain alkane
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