Advanced Search

Citation: SHEN Bo-xiong, CHEN Jian-hong, YAO Yan, HU Guo-li. Effects of alkali metals on catalyst of MnOx-CeO2/ZrO2-PILC in the low-temperature selective catalytic reduction[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(12): 1487-1491. shu

Effects of alkali metals on catalyst of MnOx-CeO2/ZrO2-PILC in the low-temperature selective catalytic reduction

  • 1.

    College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China

  • Corresponding author: SHEN Bo-xiong, 
  • Received Date: 8 February 2012
    Available Online: 28 May 2012

    Fund Project: 国家自然科学基金(51176077,50976050) (51176077,50976050) 天津市自然科学基金(12JCZDJC29300) (12JCZDJC29300) 环保公益性行业科研专项经费(201109004)。 (201109004)

  • The poisoning effects of alkali metals on low-temperature selective catalytic reduction (SCR) catalyst MnOx-CeO2/ZrO2-PILC were invested by the method of impregnation in the laboratory. It was indicated that the addition of Ca/Mg would decrease the activities of the catalyst, and the poisoning effects were contacted with the amount and acidity of the doped-alkali metal. X-ray diffraction (XRD), H2-temperature programmed reduction (H2-TPR), N2 adsorption-desorption and temperature-programmed desorption of NH3 (NH3-TPD) were used to characterize the properties of the fresh and alkali earth doped catalysts. According to the results, the doped-alkali metals would inhibit the reduction properties, induce the loss in surface area and surface acidity.
  • 加载中
    1. [1]

      [1] 张先龙, 吴雪平, 黄张根, 刘振宇. 燃煤烟气中碱金属化合物对V2O5/AC催化剂低温脱硝的影响[J]. 燃料化学学报,2009, 37(4): 496-500. (ZHANG Xian-long, WU Xue-ping,HUANG Zhang-gen, LIU Zhen-yu. Effect of potassium compounds on the catalytic activity of V2O5 /AC for SCR of NO by NH3 at low temperatures:NH3 adsorption and oxidation[J]. Journal of Fuel Chemistry and Technology, 2009, 37(4): 496-500.)

    2. [2]

      [2] CHEN L, LI J, GE M. The poisoning effect of alkali metals doping over nano V2O5–WO3/TiO2 catalysts on selective catalytic reduction of NOx by NH3[J]. Chem Eng J, 2011, 170(2/3): 531-537.

    3. [3]

      [3] 郭凤, 余剑, 朱剑虹, 刘云义, 许光文. Mn-Fe-Ce/TiO2低温NH3选择性催化还原NO[J]. 过程工程学报, 2009, 9(6): 1192-1197. (GUO Feng, YU Jian, ZHU Jian-hong, LIU Yun-yi, XU Guang-wen. Low-temperature selective catalytic reduction of NO with NH3 over Mn-Fe-Ce/TiO2[J]. The Chinese Journal of Process Engineering, 2009, 9(6): 1192-1197.)

    4. [4]

      [4] SHEN B, LIU T, ZHAO N, YANG X, DENG L. Iron-doped Mn-Ce/TiO2 catalyst for low temperature selective catalytic reduction of NO with NH3[J]. J Environ Sci, 2010, 22(9): 1447-1454.

    5. [5]

      [5] 熊丽仙, 沈伯雄, 杨晓燕, 邓黎丹, 赵宁. 纳米负载型V2O5-WO3/TiO2催化剂碱及碱土金属中毒[J]. 环境化学, 2010, 29(4): 690-695. (XIONG Li-xian, SHEN Bo-xiong, YANG Xiao-yan, DENG Li-dan, ZHAO Ning. Deactivation of V2O5-WO3/TiO2 nona catalysts by alkali and alkaline earth metals[J]. Environmental Chemistry,2010,29(4):690-695.)

    6. [6]

      [6] TANG F, XU B, SHI H,QIU J, FAN Y. The poisoning effect of Na+ and Ca2+ ions doped on the V2O5/TiO2 catalysts for selective catalytic reduction of NO by NH3[J]. Appl Catal B, 2010, 94(1/2): 71–76.

    7. [7]

      [7] 沈伯雄, 邓黎丹, 马娟, 左琛, 郝晓翠. Mn-CeOx/钛基层柱黏土( Ti-PILCs)低温选择性催化还原催化剂的钙中毒研究[J]. 环境污染与防治, 2011, 33(3): 1-5,10. (SHEN Bo-xiong, DENG Li-dan, MA Juan,ZUO Chen, HAO Xiao-cui. Calcium deact ivation of Mn-CeOx/Ti-PILCs low-temperature SCR catalyst[J]. Environmental Pollution & Control, 2011, 33(3): 1-5.)

    8. [8]

      [8] SHEN B, LIU T, YANG X, ZHAO N. The catalysts of MNOx/CeO2-ZrO2 for low-temperature selective catalytic reduction of NOx with NH3[J]. Environ Eng Sci, 2011, 28(4): 291-298.

    9. [9]

      [9] KUSTOVSTOV A L, KUSTOVA M Y, FEHRMANNA R, SIMONSEN P. Vanadia on sulphated-ZrO2, a promising catalyst for NO abatement with ammonia in alkali containing ue gases[J]. Appl Catal B, 2005, 58(1/2): 97-104.

    10. [10]

      [10] KLIMCZAK M, KERN P, HEINZELMANN T, LUCAS M, CLAUS P. High-throughput study of the effects of inorganic additives and poisons on NH3-SCR catalysts: Part II Fe-zeolite catalysts[J]. Appl Catal B, 2010, 95(1/2): 48-56.

    11. [11]

      [11] LONG R Q, YANG R T. The promoting role of rare earth oxides on Fe-exchanged TiO2-pillared clay for selective catalytic reduction of nitric oxide by ammonia[J]. Appl Catal B,2000, 27(2):87-95.

    12. [12]

      [12] CHMIELARZ L, KUSTROWSKI P, ZBROJA M, ASOCHA W, DZIEMBAJ R. Selective reduction of NO with NH3 over pillared clays modified with transition metals[J]. Catal Today, 2004, 90(1/2): 43-49.

    13. [13]

      [13] EINVALL J,ALBERTAZZI S,HULTEBERG C,MALIK A, BASILE F, LARSSON A, BRANDIN J, SANATI M.Investigation of reforming catalyst deactivation by exposure to fly ash from biomass gasification in laboratory scale[J]. Energy Fuels 2007, 21(5), 2481-2488.

    14. [14]

      [14] 沈伯雄, 熊丽仙, 刘亭, 王静, 田晓娟. 纳米负载型 V2O5-WO3/TiO2催化剂碱中毒及再生研究[J]. 燃料化学学报,2010, 38(4): 85-90. (SHEN Bo-xiong, XIONG Li-xian, LIU Ting, WANG Jing, TIAN Xiao-juan.Alkali deactivation and regeneration of nano V2O5-WO3/TiO2 catalysts[J]. Journal of Fuel Chemistry and Technology, 2010, 38(4): 85-90.)

    15. [15]

      [15] TANG X, LI Y, HUANG X, XU Y, ZHU H, WANG J, SHEN W.MNOx-CeO2 mixed oxide catalysts for complete oxidation of formaldehyde: Effect of preparation method and calcination temperature[J]. Appl Catal B, 2006, 62(3/4): 265-273.

    16. [16]

      [16] CHOI E-Y, NAM I-S, KIM Y G. TPD study of mordenite-type zeolites for selective catalytic reduction of NO by NH3[J]. J Catal, 1996, 161(2): 597-604.

    17. [17]

      [17] LISI L, LASORELLA G, MALLOGGI S, RUSSO G. Single and combined deactivating effect of alkali metals and HCl on commercial SCR catalysts[J]. Appl Catal B, 2004, 50(4): 251-25.

  • 加载中
    1. [1]

      Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO2 Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028

    2. [2]

      Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO2 by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420

    3. [3]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    4. [4]

      Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019

    5. [5]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    6. [6]

      . 

      CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化

      . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

    7. [7]

      Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    8. [8]

      Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005

    9. [9]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    10. [10]

      Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040

    11. [11]

      Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li+ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005

    12. [12]

      Lijun Yue ,  Siya Liu ,  Peng Liu . 不同晶相纳米MnO2的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005

    13. [13]

      Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    14. [14]

      Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023

    15. [15]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    16. [16]

      Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

    17. [17]

      Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037

    18. [18]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    19. [19]

      Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

    20. [20]

      Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(424)
  • HTML views(28)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return